Powder metal material for wear and temperature resistance applications

Patent metadata

Field	Value
Publication number	US-10926334-B2
Application number	US-202016773369-A
Country	US
Kind code	B2
Filing date	Jan 27, 2020
Priority date	Apr 8, 2008
Publication date	Feb 23, 2021
Grant date	Feb 23, 2021

Abstract

A powder metal composition for high wear and temperature applications is made by atomizing a melted iron based alloy including 3.0 to 7.0 wt. % carbon; 10.0 to 25.0 wt. % chromium; 1.0 to 5.0 wt. % tungsten; 3.5 to 7.0 wt. % vanadium; 1.0 to 5.0 wt. % molybdenum; not greater than 0.5 wt. % oxygen; and at least 40.0 wt. % iron. The high carbon content reduces the solubility of oxygen in the melt and thus lowers the oxygen content to a level below which would cause the carbide-forming elements to oxidize during atomization. The powder metal composition includes metal carbides in an amount of at least 15 vol. %. The microhardness of the powder metal composition increases with increasing amounts of carbon and is typically about 800 to 1,500 Hv50.

First claim

What is claimed is:

1. A powder metal material, comprising:
a plurality of particles, the particles including 3.0 to 7.0 wt. % carbon, 10.0 to 25.0 wt. % chromium, 1.0 to 5.0 wt. % tungsten, 3.5 to 7.0 wt. % vanadium, 1.0 to 5.0 wt. % molybdenum, not greater than 0.5 wt. % oxygen, and at least 40.0 wt. % iron, based on the total weight of the particles;
the particles being atomized; and
the particles including metal carbides in an amount of at least 15 vol. %, based on the total volume of the particles.

2. The powder metal material according to claim 1 , wherein the metal carbides are present in an amount of 40.0 to 60.0 vol. %, based on the total volume of the particles.

3. The powder metal material according to claim 2 , wherein the metal carbides are present in an amount of 47.0 to 52.0 vol. %, based on the total volume of the particles.

4. The powder metal material according to claim 1 , wherein the metal carbides include at least one of M 8 C 7 , M 7 C 3 , MC, M 6 C, M 23 C 6 , and M 3 C, wherein M is at least one metal atom, such as Fe, Cr, V, Mo, and/or W, and C is carbon.

5. The powder metal material according to claim 4 , wherein the metal carbides are selected from the group consisting of: M 8 C 7 , M 7 C 3 , M 6 C.

6. The powder metal material according to claim 5 , wherein the M 8 C 7 is (V 63 Fe 37 ) 8 C 7 , the M 7 C 3 is selected from the group consisting of: (Cr 34 Fe 66 ) 7 C 3 , Cr 35 Fe 35 C 3 , and Cr 4 Fe 3 C 3 ; and the M 6 C is selected from the group consisting of: Mo 3 Fe 3 C, Mo 2 Fe 4 C, W 3 Fe 3 C, and W 2 Fe 4 C.

7. The powder metal material of claim 1 , wherein the particles include austenite and/or martensite.

8. The powder metal material of claim 1 , wherein the metal carbides include vanadium-rich carbides in an amount of about 5.0 to 10.0 vol. % and chromium-rich carbides in an amount of about 40.0 to 45.0 vol. %, based on the total volume of the particles.

9. The powder metal material of claim 1 , wherein the particles include 3.5 to 4.0 wt. % carbon, 11.0 to 15.0 wt. % chromium, 1.5 to 3.5 wt. % tungsten, 4.0 to 6.5 wt. % vanadium, 1.0 to 3.0 wt. % molybdenum, not greater than 0.3 wt. % oxygen, and 50.0 to 81.5 wt % iron, based on the total weight of the particles.

10. The powder metal material of claim 9 , wherein the particles consist essentially of 3.8 wt. % carbon, 13.0 wt. % chromium, 2.5 wt. % tungsten, 6.0 wt. % vanadium, 1.5 wt. % molybdenum, 0.2 wt. % oxygen, 70.0 to 80.0 wt. % iron, and impurities in an amount not greater than 2.0 wt. %, based on the total weight of the particles.

11. The powder metal material of claim 1 , wherein the particles have a microhardness of greater than 1000 Hv 50 .

12. The powder metal material of claim 1 , wherein the metal carbides have a diameter of about 1 to 2 μm.

13. A article comprising:
a plurality of particles, the particles including 3.0 to 7.0 wt. % carbon, 10.0 to 25.0 wt. % chromium, 1.0 to 5.0 wt. % tungsten, 3.5 to 7.0 wt. % vanadium, 1.0 to 5.0 wt. % molybdenum, not greater than 0.5 wt. % oxygen, and at least 40.0 wt. % iron, based on the total weight of the particles;
the particles being atomized and sintered; and
the particles including metal carbides in an amount of at least 15 vol. %, based on the total volume of the particles.

14. The article of claim 13 , wherein the metal carbides are present in an amount of 40.0 to 60.0 vol. %, based on the total volume of the particles.

15. The article according to claim 13 , wherein the metal carbides include at least one of M 8 C 7 , M 7 C 3 , MC, M 6 C, M 23 C 6 , and M 3 C, wherein M is at least one metal atom, such as Fe, Cr, V, Mo, and/or W, and C is carbon.

16. The article of claim 15 , wherein the metal carbides are selected from the group consisting of: M 8 C 7 , M 7 C 3 , M 6 C; wherein the M 8 C 7 is (V 63 Fe 37 ) 8 C 7 ; the M 7 C 3 is selected from the group consisting of: (Cr 34 Fe 66 ) 7 C 3 , Cr 35 Fe 35 C 3 , and Cr 4 Fe 3 C 3 ; and the M 6 C is selected from the group consisting of: Mo 3 Fe 3 C, Mo 2 Fe 4 C, W 3 Fe 3 C, and W 2 Fe 4 C.

17. The article of claim 13 , wherein the particles include austenite and/or martensite.

18. The article of claim 13 , wherein the metal carbides include vanadium-rich carbides in an amount of about 5.0 to 10.0 vol. % and chromium-rich carbides in an amount of about 40.0 to 45.0 vol. %, based on the total volume of the particles.

19. The article of claim 13 , wherein the particles include 3.5 to 4.0 wt. % carbon, 11.0 to 15.0 wt. % chromium, 1.5 to 3.5 wt. % tungsten, 4.0 to 6.5 wt. % vanadium, 1.0 to 3.0 wt. % molybdenum, not greater than 0.3 wt. % oxygen, and 50.0 to 81.5 wt % iron, based on the total weight of the particles.

20. The article of claim 13 , wherein the particles have a microhardness of greater than 1000 Hv 50 .

Assignees

• Tenneco Inc
• Corp De Lecole Polytechnique De Montreal

Inventors

• Beaulieu Philippe
• Christopherson Jr Denis B
• Farthing Leslie John
• Schoenwetter Todd
• L'Espérance Gilles

Classifications

• B22F1/00

  Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties · CPC title

• C22C33/0285

  with Cr, Co, or Ni having a minimum content higher than 5% · CPC title

• B22F3/1017

  Multiple heating or additional steps (B22F3/101 takes precedence) · CPC title

• B22F9/082 Primary

  atomising using a fluid (using centrifugal force B22F9/10) · CPC title

• B22F3/12

  Both compacting and sintering (by forging B22F3/17) · CPC title