Method for producing an anode for a lithium metal secondary battery including a MXene thin film

Patent metadata

Field	Value
Publication number	US-10923725-B2
Application number	US-201916285680-A
Country	US
Kind code	B2
Filing date	Feb 26, 2019
Priority date	Feb 26, 2018
Publication date	Feb 16, 2021
Grant date	Feb 16, 2021

Abstract

A method for producing an anode for a lithium metal secondary battery includes coating a thin film comprised of Nb 2 C, Ti 2 C or Ti 3 C 2 on a substrate; providing a lithium metal electrode; and laminating the thin film to a surface of the lithium metal electrode. Coating is accomplished by providing a dispersion of a powder comprising Nb 2 C, Ti 2 C or Ti 3 C 2 ; and coating the dispersion on the substrate by Langmuir-Blodgett scooping (LBS). The method may further include, prior to providing the dispersion, obtaining the powder by etching a MAX phase structure represented by Formula 1, Formula 2 or Formula 3 below:

Nb 2 AC  (1);

Ti 2 AC  (2); and

Ti 3 AC 2   (3),
where A is a metal selected from among Group IIIA elements, Group IVA elements, Cd, and combinations thereof. The method may further include, after laminating the thin film, removing the substrate from the thin film.

First claim

What is claimed is:

1. A method for producing an anode for a lithium metal secondary battery, comprising:
coating a thin film comprised of Nb 2 C, Ti 2 C or Ti 3 C 2 on a substrate;
providing a lithium metal electrode; and
laminating the thin film to a surface of the lithium metal electrode.

2. The method according to claim 1 , wherein coating is accomplished by providing a dispersion of a powder comprising Nb 2 C, Ti 2 C or Ti 3 C 2 ; and coating the dispersion on the substrate by Langmuir-Blodgett scooping (LBS).

3. The method according to claim 2 , further comprising, prior to providing the dispersion, obtaining the powder by etching a MAX phase structure represented by Formula 1, Formula 2 or Formula 3 below:
Nb 2 AC  (1);

Ti 2 AC  (2); and

Ti 3 AC 2   (3),

where A is a metal selected from the group consisting of Group IIIA elements, Group IVA elements, Cd, and combinations thereof.

4. The method according to claim 3 , wherein the MAX phase structure represented by Formula 1 is Nb 2 AlC and the etching is performed by mixing the Nb 2 AlC with hydrofluoric acid to provide a mixture in amounts so that a weight ratio of the Nb 2 AlC to hydrogen fluoride ranges from 1:3.5 to 1:6.0 and allowing the mixture to react for from 2 to 9 days.

5. The method according to claim 3 , wherein the MAX phase structure represented by Formula 2 is Ti 2 AlC and the etching is performed by mixing the Ti 2 AlC with hydrofluoric acid to provide a mixture in amounts so that a weight ratio of the Ti 2 AlC to hydrogen fluoride ranges from 1:0.5 to 1:1.5 and allowing the mixture to react for from 12 to 36 hours.

6. The method according to claim 3 , wherein the MAX phase structure represented by Formula 3 is Ti 3 AlC 2 and the etching is performed by mixing the Ti 3 AlC 2 with hydrofluoric acid to provide a mixture in amounts so that a weight ratio of the Ti 3 AlC 2 to hydrogen fluoride ranges from 1:3.5 to 1:6.0 and allowing the mixture to react for 2-5 days.

7. The method according to claim 1 , wherein laminating the thin film is accomplished by rolling.

8. The method according to claim 7 , wherein laminating the thin film by rolling is accomplished by pressing the lithium metal against the thin film to provide a sandwich structure and passing the sandwich structure through a rolling mill.

9. The method according to claim 1 , further comprising, after laminating the thin film, removing the substrate from the thin film.

10. The method according to claim 1 , wherein laminating takes place in an inert atmosphere comprised of inert gasses.

11. The method according to claim 1 , wherein laminating takes place in a dry atmosphere having a relative humidity ranging from 0% to 1%.

Assignees

• Korea Inst Sci & Tech

Inventors

• Cho Won Il
• Kim Mun Sek
• Ryu Ji Hyun
• Lee Seung Hun

Classifications

• H01M2220/10

  Batteries in stationary systems, e.g. emergency power source in plant · CPC title

• H01M12/08

  composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type · CPC title

• H01M10/052 Primary

  Li-accumulators · CPC title

• H01M4/1395

  of electrodes based on metals, Si or alloys · CPC title

• H01M4/134 Primary

  Electrodes based on metals, Si or alloys · CPC title