Electrode coated with a film obtained from an aqueous solution comprising a water-soluble binder, production method thereof and uses of same

Patent metadata

Field	Value
Publication number	US-10923704-B2
Application number	US-201715611284-A
Country	US
Kind code	B2
Filing date	Jun 1, 2017
Priority date	Nov 13, 2002
Publication date	Feb 16, 2021
Grant date	Feb 16, 2021

Abstract

A method of preparing an electrochemical electrode which is partially or totally covered with a film that is obtained by spreading an aqueous solution comprising a water-soluble binder over the electrode and subsequently drying same. The production cost of the electrodes thus obtained is reduced and the surface porosity thereof is associated with desirable resistance values.

First claim

The invention claimed is:

1. An electrode consisting of a support coated at least in part with a film containing an active material comprising LiFePO 4 coated with graphite and/or carbon,
said electrode being obtained by
preparing the active material by mechano-fusion or hybridization, and
spreading on a support an aqueous solution comprising the active material, at least one water soluble binder and at least one water soluble thickening agent,
wherein the at least one water soluble binder is non-fluorinated.

2. The electrode according to claim 1 , wherein the electrode is a cathode, and wherein the electrode support is at least in part stainless, aluminum, copper, carbon, metal-plastic or a mixture of at least two of these materials.

3. The electrode according to claim 1 , wherein the electrode is an anode, and wherein the electrode support is at least in part copper, metal-plastic, or a mixture of at least two thereof.

4. The electrode according to claim 1 , having at least one of the following properties:
storage stability, higher than 1 year, in the presence of a moisture content higher than 50% and in the presence of temperatures higher than 20° C.;
a film thickness, when the latter is graphite based, of between 10 and 100 μm;
a film thickness, when the latter is iron and/or phosphate based, of between 20 and 200 μm;
electrochemical performances that compare to those of corresponding electrodes obtained with the same active material but by using an organic solvent solution; and
an electrode film with particles of rubber directly attached to the electrode support.

5. The electrode according to claim 4 , wherein a porosity of the film that coats one or more of the electrodes, measured according to the method of thickness measurement, is between 10 and 90%.

6. The electrode according to claim 5 , wherein the porosity is between 30 and 40%.

7. An electrochemical system comprising at least one electrode according to claim 1 , and a separator of a gel, solid or liquid electrolyte.

8. The electrochemical system according to claim 7 , wherein the electrolyte comprises at least one salt and at least one solvent, wherein said at least one salt is selected from the group consisting of LiPF 6 , LiBF 4 , LIBOB, LiTFSI, LIFSI and mixtures thereof.

9. The electrochemical system according to claim 7 , further comprising at least one pair of a cathode and an anode each being at least partially coated with active material,
wherein the cathode is an electrode according to claim 1 , and
wherein the active material of the anode is selected from the group consisting of powders of graphite, SN alloys, Si alloys, Li 4 Ti 5 O 12 , WO 2 and mixtures thereof.

10. The electrochemical system according to claim 9 , wherein the anode comprises a powder of graphite present as particles having an ellipsoidal graphite nucleus coated with prismatic shaped graphite particles.

11. The electrochemical system according to claim 7 , wherein the separator has a porosity of about 30 to 50%.

12. The electrochemical system according to claim 11 , wherein the separator consists of polypropylene, polyethylene, polyoxyethylene, polyoxypropylene or mixtures thereof.

13. An electric vehicle battery comprising the electrochemical system according to claim 7 .

14. An electrochemical system comprising an electrode consisting of a support coated at least in part with a film containing an active material comprising LiFePO 4 coated with graphite and/or carbon,
said electrode being obtained by
preparing the active material by mechano-fusion or hybridization, and
spreading on the support an aqueous solution comprising the active material, at least one water soluble binder and at least one water soluble thickening agent,
wherein the at least one water soluble binder is non-fluorinated.

15. The electrical system according to claim 14 , comprising an electrolyte gel.

16. The electrical system according to claim 15 , further comprising an all liquid battery, wherein the electrolyte comprises at least one salt and at least one solvent.

17. The electrical system according to claim 16 , wherein a molar concentration of the at least one salt, in the electrolyte, is lower than or equal to 1 and a molar concentration of the solvent is higher than or equal to 1.

18. The electrical system according to claim 16 , wherein the salt is selected from the group consisting of imides, LiPF6, LiBF4, LiBOB, LiTFSI, LiFSI and mixtures thereof.

19. The electrical system according to claim 16 , wherein retained solvents have an elevated boiling point.

20. The electrical system according to claim 19 , wherein the solvent has a boiling point higher than 100° C.

21. The electrical system according to claim 20 , wherein the solvent is selected from the group consisting of gamma-butyrolactone (γBL), tetraethylsulfamide (TESA), modified tetraethylsulfamide, and mixtures thereof.

22. The electrical system according to claim 16 , wherein EC and PC solvents are used for formation of a passivation film in the case of carbon based anodes, and PC solvent for low temperature applications.

23. The electrical system according to claim 22 , wherein the electrolyte for the all gel battery is obtained from a precursor made of a) a polymer+b) a liquid electrolyte.

24. The electrical system according to claim 23 , wherein the a) content varies from 1 to 99%; and the b) content varies from 1 to 99%, and the a and b contents agree with the relation (a)+(b)=100%, the % being given in weight.

25. The electrical system according to claim 23 , wherein the composition of the precursor is about 5% of a 4 branch polyether, and about 95% of an electrolyte of composition comprising 1.5 M LiTFSI, 1 M ethylene carbonate, 1 M propylene carbonate, 1 M tetraethylsulfamide (TESA), 2 M gamma-butyrolactone (γBL).

26. The electrochemical system according to claim 25 , wherein the concentration in lithium salt is higher than or equal to 1 M (1 molar) for the gels.

Assignees

• Hydro Quebec

Inventors

• Zaghib Karim
• Armand Michel
• Guerfi Abdelbast
• Perrier Michel
• Dupuis Elisabeth
• Charest Patrick

Classifications

• H01M50/42

  Acrylic resins · CPC title

• H01M50/417

  Polyolefins · CPC title

• H01M50/426

  Fluorocarbon polymers · CPC title

• H01M50/491

  Porosity · CPC title

• H01M50/406

  Moulding; Embossing; Cutting · CPC title