Lithium-sulfur battery including polymer non-woven fabric between positive electrode and separator

Patent metadata

Field	Value
Publication number	US-10923699-B2
Application number	US-201716304950-A
Country	US
Kind code	B2
Filing date	Jul 6, 2017
Priority date	Sep 9, 2016
Publication date	Feb 16, 2021
Grant date	Feb 16, 2021

Abstract

A lithium-sulfur battery is provided. More specifically, a lithium-sulfur battery including a polymer non-woven fabric containing a liquid electrolyte between a positive electrode including sulfur and a separator is provided. By including a polymer non-woven fabric containing a liquid electrolyte between a positive electrode and a separator, the lithium-sulfur battery according to the present invention is capable of continuously supplying the liquid electrolyte to the positive electrode, and suppressing polysulfide elution. Accordingly, the lithium-sulfur battery has a reduced discharge overvoltage, and exhibits excellent discharge capacity and life time properties.

First claim

The invention claimed is:

1. A lithium-sulfur battery, comprising:
a positive electrode;
a negative electrode;
a separator;
a liquid electrolyte, and
a polymer non-woven fabric provided between the positive electrode and the separator,
wherein a material of the polymer non-woven fabric is one or more selected from the group consisting of polyimide, polyethylene oxide, polyethylene terephthalate, polyvinyl alcohol, polyacrylonitrile and polyurethane,
wherein the polymer non-woven fabric has an average pore diameter of 0.2 μm to less than 0.5 μm, and
wherein the polymer non-woven fabric has tensile strength of 15 MPa to less than 30 MPa.

2. The lithium-sulfur battery of claim 1 , wherein the polymer non-woven fabric has a thickness of 10 μm to 25 μm.

3. The lithium-sulfur battery of claim 1 , wherein the polymer non-woven fabric is formed with a polymer having a weight average molecular weight of 100,000 g/mol to 6,000,000 g/mol.

4. The lithium-sulfur battery of claim 1 , wherein the polymer non-woven fabric is formed with a polymer fiber having a diameter of 100 nm to 400 nm.

5. The lithium-sulfur battery of claim 1 , wherein the polymer non-woven fabric has porosity represented by the following Mathematical Formula 1 of 60% to 80%:
Porosity (%)={1−(density of polymer non-woven fabric/density of raw material polymer)}*100  [Mathematical Formula 1]

6. The lithium-sulfur battery of claim 1 , wherein the polymer non-woven fabric has porosity represented by the following Mathematical Formula 1 of 65% to 75%:
Porosity (%)={1−(density of polymer non-woven fabric/density of raw material polymer)}*100  [Mathematical Formula 1]

7. The lithium-sulfur battery of claim 1 , wherein the polymer non-woven fabric has an amount of liquid electrolyte impregnation of 150% to 350%, wherein liquid electrolyte impregnation is an increased weight of the liquid electrolyte relative to a weight of the polymer non-woven fabric.

8. The lithium-sulfur battery of claim 1 , wherein the positive electrode includes a positive electrode active material layer formed on a current collector, a surface of the positive electrode active material layer is coated with a polymer film including a non-aqueous liquid electrolyte, and voids in the positive electrode active material layer are filled with a polymer material including the non-aqueous liquid electrolyte.

9. The lithium-sulfur battery of claim 8 , wherein the polymer film and the polymer material are formed by polymerizing a composition including at least one or more monomers selected from the group consisting of acrylamide, divinyl benzene, butyl acrylate, hexyl acrylate, trimethylolpropane triacrylate, butanediol diacrylate, butanediol dimethacrylate, diallyl succinate, diallyl malate, diallyl suberate, ethylene glycol diacrylate, ethylene glycol dimethacrylate, ethylene glycol divinyl ether, tritetraethylene dimethyl acrylate (TTEGDA), poly(ethylene glycol) diacrylate (PEGDA), polyethylene glycol dimethacrylate (PEGDMA), poly(ethyleneglycol) divinyl ether and diglycidyl ester, and the non-aqueous liquid electrolyte.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Taek Gyoung
• Yang Doo Kyung
• Park Intae

Classifications

• H01M10/052 Primary

  Li-accumulators · CPC title

• H01M50/417

  Polyolefins · CPC title

• H01M50/494

  Tensile strength · CPC title

• H01M50/454

  comprising a non-fibrous layer and a fibrous layer superimposed on one another · CPC title

• H01M50/42

  Acrylic resins · CPC title