Mixtures containing plastic and organic fibres

Patent metadata

Field	Value
Publication number	US-10920079-B2
Application number	US-201615768354-A
Country	US
Kind code	B2
Filing date	Oct 25, 2016
Priority date	Oct 30, 2015
Publication date	Feb 16, 2021
Grant date	Feb 16, 2021

Abstract

Polysiloxane/polymer copolymers are used in conjunction with conventional polymer binders for production of wood fiber composites, and improve processing characteristics as well as end product properties.

First claim

The invention claimed is:

1. A thermoplastic, extrudable mixture comprising:
(A) at least one amorphous siloxane-organo copolymer having 10 to 3000 siloxane units per siloxane segment and at least one organo segment having at least one group selected from ester groups, amide groups, urethane groups, urea groups and thiourea groups,
(B) organic fibers, and
(C) optionally substituted polyolefins, wherein component (B) organic fibers are wood fibers.

2. A thermoplastic, extrudable mixture comprising:
(A) at least one amorphous siloxane-organo copolymer having 10 to 3000 siloxane units per siloxane segment and at least one organo segment having at least one group selected from ester groups, amide groups, urethane groups, urea groups and thiourea groups,
(B) organic fibers, and
(C) optionally substituted polyolefins, wherein component (B) organic fibers are wood fibers, and wherein the content of diorganylsiloxy units in component (A) is between 80% and 99% by weight.

3. A mixture comprising:
(A) at least one amorphous siloxane-organo copolymer having 10 to 3000 siloxane units per siloxane segment and at least one organo segment having at least one group selected from ester groups, amide groups, urethane groups, urea groups and thiourea groups,
(B) organic fibers, and
(C) optionally substituted polyolefins, and optionally one or more of components (D) through (I)
(D) inorganic fibers,
(E) flame retardants,
(F) biocides,
(G) pigments,
(H) UV absorbers, and
(I) HALS stabilizers, and no further components.

4. A mixture comprising:
(A) at least one amorphous siloxane-organo copolymer having 10 to 3000 siloxane units per siloxane segment and at least one organo segment having at least one group selected from ester groups, amide groups, urethane groups, urea groups and thiourea groups,
(B) organic fibers, and
(C) optionally substituted polyolefins, wherein component (A) comprises components of the formula (1)

wherein
R are identical or different and are monovalent, SiC-bonded, optionally fluorine- or chlorine-substituted hydrocarbon radicals having 1 to 20 carbon atoms, X are identical or different and are alkylene radicals having 1 to 20 carbon atoms in which nonadjacent methylene units are optionally replaced by —O— groups, A are identical or different and are oxygen, sulfur, or an amino group —NR′—, Z are identical or different and are oxygen, or an amino group —NR′—, R′ are identical or different and are hydrogen or an alkyl radical having 1 to 10 carbon atoms, Y are identical or different and are divalent, optionally fluorine- or chlorine-substituted hydrocarbon radicals having 1 to 20 carbon atoms, D are identical or different and are divalent, optionally fluorine-, chlorine- or C 1 -C 6 -alkyl-ester-substituted hydrocarbon radicals in which nonadjacent methylene units are optionally replaced by —O—, —COO—, —OCO— or —OCOO— groups, B are identical or different and are hydrogen or a functional or nonfunctional organic or organosilicon radical, n each is identical or different and is a number from 10 to 3000, a is a number of at least 1,
b is 0 or a number from 1 to 100,
c is 0 or a number from 1 to 100,
d is a number of at least 1 and e is 0 or 1.

5. The mixture of claim 4 , wherein the content of diorganylsiloxy units in component (A) is between 80% and 99% by weight.

6. The mixture of claim 4 , wherein the proportion of silicone copolymer(s) (A) in the mixture is between 100 ppmw and 10,000 ppmw based on the total weight of the mixture.

7. The mixture of claim 4 , wherein component (B) organic fibers are wood fibers.

8. The mixture of claim 4 , wherein the proportion of the organic fibers (B) in the mixture is between 30% and 90% by weight based on the total weight of the mixture.

9. The mixture of claim 4 , wherein component (C) comprises at least one polymer selected from the group consisting of chlorine-substituted polyolefins, alkyl-substituted polyolefins, alkyl-carboxylate-substituted polyolefins, nitrile-substituted polyolefins, and phenyl-substituted polyolefins.

10. The mixture of claim 4 , wherein the proportion of the optionally substituted polyolefins (C) in the mixture is 10% to 70% by weight based on the total weight of the mixture.

11. The mixture of claim 4 , wherein the proportion of silicone copolymer(s) (A) in the mixture is between 250 ppmw and 6,000 ppmw based on the total weight of the mixture.

12. The mixture of claim 4 , wherein the proportion of silicone copolymer(s) (A) in the mixture is between 500 ppmw and 4,000 ppmw based on the total weight of the mixture.

13. A molded article produced by extrusion of a mixture of claim 4 .

14. A process for producing a mixture of claim 4 , comprising mixing the components (A), (B) and (C) and also optionally further components in any desired sequence.

15. The process of claim 14 , wherein component (A) is employed as a premixture with a portion of the optionally substituted polyolefins (C) and optionally one or more of the components
(D) inorganic fibers,
(E) flame retardants,
(F) biocides,
(G) pigments,
(H) UV absorbers, and
(I) HALS stabilizers.

Assignees

• Wacker Chemie Ag

Inventors

• Schaefer Oliver
• Randel Peter

Classifications

• C08G18/61

  Polysiloxanes · CPC title

• C08G77/458

  containing polyurethane sequences · CPC title

• C08L97/02 Primary

  Lignocellulosic material, e.g. wood, straw or bagasse {(manufacture of articles made from lignocellulosic material by dry processes B27N)} · CPC title

• C08L83/10 Primary

  Block- or graft-copolymers containing polysiloxane sequences (obtained by polymerising a compound having a carbon-to-carbon double bond on to a polysiloxane C08L51/08, C08L53/00) · CPC title

• C08L23/26

  modified by chemical after-treatment (saponified copolymers C08L23/0861; unsaturated acid salts C08L23/0876) · CPC title