Cleaning device for gas flows from isocyanate production

Patent metadata

Field	Value
Publication number	US-10919845-B2
Application number	US-201816499357-A
Country	US
Kind code	B2
Filing date	Mar 29, 2018
Priority date	Apr 3, 2017
Publication date	Feb 16, 2021
Grant date	Feb 16, 2021

Abstract

The invention relates to a cleaning device for separating an organic isocyanate produced by the reaction of an organic amine with a stoichiometric excess of phosgene in the gas phase from the gaseous raw product obtained in the reaction, said device comprising a first separating body comprising at least one raw product supply line for a gaseous raw product flow containing at least the isocyanate, hydrogen chloride and non-reacted phosgene, a first liquid supply line for a liquid flow containing at least one quench liquid, and a first liquid discharge line for a liquid flow containing at least part of the quench liquid and part of the isocyanate, a first gas line for transporting a gas flow containing at least hydrogen chloride, evaporated quench liquid and phosgene leading away from the first separating body. The invention is characterized in that at least one addition body for directly introducing at least one cooling fluid for an at least partial condensation and/or absorption of the gas flow that can be guided via the first gas line is associated with the first gas line.

First claim

The invention claimed is:

1. A cleaning apparatus for separating an organic isocyanate prepared by reacting an organic amine with a stoichiometric excess of phosgene in the gas phase from the gaseous crude product obtained in the reaction, comprising a first separating unit having at least
a crude product inlet for a gaseous crude product stream containing at least the isocyanate, hydrogen chloride and unconverted phosgene,
a first liquid inlet for a liquid stream containing at least a quench liquid and
a first liquid outlet for a liquid stream containing at least some of the quench liquid and at least some of the isocyanate,

wherein a first gas conduit for conveying a gas stream containing at least hydrogen chloride, evaporated quench liquid and phosgene departs from the first separation unit, and
wherein at least one addition unit for direct introduction of at least one cooling fluid for an at least partial condensation and/or absorption of the gas stream conductible through the first gas conduit is assigned to the first gas conduit.

2. The cleaning apparatus as claimed in claim 1 , wherein at least one of the first removal unit and the first gas conduit is set up such that the gas stream conductible through the first gas conduit is deflected at least once before it reaches the addition unit.

3. The cleaning apparatus as claimed in claim 1 , wherein the addition unit consists of one or more nozzles for direct introduction of the cooling fluid in concurrent or counter current, or consists of multiple nozzles positioned in the conduit shell of the first gas conduit, at uniform intervals along the circumference of the first gas conduit.

4. The cleaning apparatus as claimed in claim 1 , wherein the addition unit has at least one orifice for generation of a fluid curtain over the entire cross section of the first gas conduit, positioned in a horizontal pipeline section in the upper region of the conduit shell of the first gas conduit, such that the gas flow crosses the lamellae or jets of the fluid curtain.

5. The cleaning apparatus as claimed in claim 1 , wherein the addition unit (has a cooling fluid inlet for conveying the cooling fluid.

6. The cleaning apparatus as claimed in claim 1 , wherein the first gas conduit leads to a second removal unit.

7. The cleaning apparatus as claimed in claim 6 , wherein a second liquid conduit for at least partial recycling of a liquid stream as quench liquid departs from the second separation unit and leads to the first separation unit.

8. The cleaning apparatus as claimed in claim 7 , wherein two closed-loop control devices (and for control of the liquid flow rates conductible through the second liquid conduit to the first separation unit and through the cooling fluid inlet to the addition unit are additionally assigned to the second liquid conduit and to the cooling fluid inlet.

Assignees

• Covestro Deutschland Ag

Inventors

• Kobylka Manfred
• Merkel Michael
• Duerig Dominik
• Seidel Bernhard

Classifications

• B01F23/2132

  using nozzles · CPC title

• C07C263/10 Primary

  by reaction of amines with carbonyl halides, e.g. with phosgene · CPC title

• B01D53/1487

  Removing organic compounds · CPC title

• B01D5/0087

  Recirculating of the cooling medium · CPC title

• Y02P20/151

  Reduction of greenhouse gas [GHG] emissions, e.g. CO2 · CPC title