MnZn ferrite and its production method

Patent metadata

Field	Value
Publication number	US-10919809-B2
Application number	US-201716087224-A
Country	US
Kind code	B2
Filing date	Mar 24, 2017
Priority date	Mar 25, 2016
Publication date	Feb 16, 2021
Grant date	Feb 16, 2021

Abstract

A method for producing MnZn ferrite comprising Fe, Mn and Zn as main components, and Ca, Si and Co, and at least one selected from the group consisting of Ta, Nb and Zr as sub-components, comprising a step of molding a raw material powder for the MnZn ferrite to obtain a green body, and a step of sintering the green body; the sintering step comprising a temperature-elevating step, a high-temperature-keeping step, and a cooling step; the cooling step including a slow cooling step of cooling in a temperature range of 1100° C. to 1250° C. at a cooling speed of 0° C./hour to 20° C./hour for 1 hours to 20 hours, and a cooling speed before and after the slow cooling step being higher than 20° C./hour; the MnZn ferrite having a volume resistivity of 8.5 Ω·m or more at room temperature, an average crystal grain size of 7 μm to 15 μm, and core loss of 420 kW/m 3 or less between 23° C. and 140° C. at a frequency of 100 kHz and an exciting magnetic flux density of 200 mT.

First claim

What is claimed is:

1. A method for producing MnZn ferrite comprising Fe, Mn and Zn as main components, and Ca, Si and Co, and at least one selected from the group consisting of Ta, Nb and Zr as sub-components, comprising
a step of molding a raw material powder for said MnZn ferrite to obtain a green body, and
a step of sintering said green body;
said sintering step comprising a temperature-elevating step, a high-temperature-keeping step, and a cooling step;
said cooling step including a slow cooling step of cooling in a temperature range of 1100° C. to 1250° C. at a cooling speed of 0° C./hour to 20° C./hour for 1 hours to 20 hours, and
a cooling speed before and after said slow cooling step being higher than 20° C./hour;
said MnZn ferrite having a volume resistivity of 8.5 Ω·m or more at room temperature, an average crystal grain size of 7 μm to 15 μm and core loss of 420 kW/m 3 or less between 23° C. and 140° C. at a frequency of 100 kHz and an exciting magnetic flux density of 200 mT.

2. The method for producing MnZn ferrite according to claim 1 , wherein said high-temperature-keeping step is conducted at a keeping temperature of higher than 1250° C. and 1350° C. or lower in an atmosphere having an oxygen concentration of more than 0.2% by volume and 10% by volume or less.

3. The method for producing MnZn ferrite according to claim 2 , wherein the concentration of oxygen in said cooling step is controlled so that the relationship between the concentration of oxygen P [O 2 ] (volume fraction) and temperature T (° C.) satisfies a formula:
log(P [O 2 ])=a−b/(T+273), wherein a is a constant of 6.4 to 11.5, and b is a constant of 10000 to 18000.

4. The method for producing MnZn ferrite according to claim 1 , wherein the MnZn ferrite comprises Fe, Mn and Zn as main components, and Si, Ca and Co, and at least one selected from the group consisting of Ta, Nb and Zr as sub-components,
said main components comprising 53-54% by mol of Fe (calculated as Fe 2 O 3 ), and 8.2-10.2% by mol of Zn (calculated as ZnO), the balance being Mn calculated as MnO, and
said sub-components comprising more than 0.001 parts by mass and 0.015 parts by mass or less of Si (calculated as SiO 2 ), more than 0.1 parts by mass and 0.35 parts by mass or less of Ca (calculated as CaCO 3 ), 0.4 parts by mass or less (not including 0) of Co (calculated as Co 3 O 4 ), 0.1 parts by mass or less (including 0) of Ta (calculated as Ta 2 O 5 ), 0.1 parts by mass or less (including 0) of Zr (calculated as ZrO 2 ), and 0.05 parts by mass or less (including 0) of Nb (calculated as Nb 2 O 5 ), the total amount of Ta 2 O 5 , ZrO 2 and Nb 2 O 5 being 0.1 parts by mass or less (not including 0), per 100 parts by mass in total of said main components (calculated as said oxides).

5. MnZn ferrite comprising 53-54% by mol of Fe (calculated as Fe 2 O 3 ), and 8.2-10.2% by mol of Zn (calculated as ZnO), the balance being Mn (calculated as MnO), as main components, and
more than 0.001 parts by mass and 0.015 parts by mass or less of Si (calculated as SiO 2 ), more than 0.1 parts by mass and 0.35 parts by mass or less of Ca (calculated as CaCO 3 ), 0.4 parts by mass or less (not including 0) of Co (calculated as Co 3 O 4 ), 0.1 parts by mass or less (including 0) of Ta (calculated as Ta 2 O 5 ), 0.1 parts by mass or less (including 0) of Zr (calculated as ZrO 2 ), and 0.05 parts by mass or less (including 0) of Nb (calculated as Nb 2 O 5 ), the total amount of Ta 2 O 5 , ZrO 2 and Nb 2 O 5 being 0.1 parts by mass or less (not including 0), as sub-components, per 100 parts by mass in total of said main components (calculated as said oxides),
said MnZn ferrite having a volume resistivity of 8.5 Ω·m or more at room temperature, an average crystal grain size of 7 μm to 15 μm, core loss of 420 kW/m 3 or less between 23 ° C. and 140 ° C. at a frequency of 100 kHz and an exciting magnetic flux density of 200 mT, and initial permeability μi of 2800 or more at a frequency of 100 kHz and at 20° C.

6. The MnZn ferrite according to claim 5 , wherein said sub-components comprises more than 0.003 parts by mass and 0.012 parts by mass or less of Si (calculated as SiO 2 ), more than 0.1 parts by mass and 0.35 parts by mass or less of Ca (calculated as CaCO 3 ), and 0.2 parts by mass or more and 0.4 parts by mass or less of Co (calculated as Co 3 O 4 ), and
said sub-components further comprises at least one selected from the group consisting of 0.015 parts by mass or more and 0.1 parts by mass or less of Ta (calculated as Ta 2 O 5 ), 0.03 parts by mass or more and 0.1 parts by mass or less of Zr (calculated as ZrO 2 ), and 0.02 parts by mass or more and 0.05 parts by mass or less of Nb (calculated as Nb 2 O 5 ), the total amount of Ta 2 O 5 , ZrO 2 and Nb 2 O 5 being 0.1 parts by mass or less (not including 0), per 100 parts by mass in total of said main components (calculated as said oxides),
said MnZn ferrite having core loss of 400 kW/m 3 or less at 23° C. at a frequency of 100 kHz and an exciting magnetic flux density of 200 mT.

Assignees

• Hitachi Metals Ltd

Inventors

• Miyoshi Yasuharu
• Koyuhara Norikazu
• Tada Tomoyuki

Classifications

• H01F1/34

  non-metallic substances, e.g. ferrites · CPC title

• H01F41/02

  for manufacturing cores, coils, or magnets (H01F41/14 takes precedence; for dynamo-electric machines H02K15/00) · CPC title

• C04B2235/6562

  Heating rate · CPC title

• C04B2235/3275

  Cobalt oxides, cobaltates or cobaltites or oxide forming salts thereof, e.g. bismuth cobaltate, zinc cobaltite · CPC title

• C04B2235/6565

  Cooling rate · CPC title