Process using ion exchange resins for the treatment of wastewater emanating from purified terephthalic acid production

Patent metadata

Field	Value
Publication number	US-10919787-B2
Application number	US-201615774612-A
Country	US
Kind code	B2
Filing date	Nov 8, 2016
Priority date	Nov 13, 2015
Publication date	Feb 16, 2021
Grant date	Feb 16, 2021

Abstract

A method for recovering water from purified terephthalic acid production wastewater includes: producing purified terephthalic acid comprising purified terephthalic acid feedstock and wastewater comprising impurities; separating the purified terephthalic acid feedstock from the wastewater comprising impurities; transferring the wastewater to a tank; adjusting the p H of the wastewater with a basic solution; adjusting the temperature of the wastewater; passing the wastewater to a column; contacting the wastewater with an ion exchange resin to remove the impurities; and recovering the water depleted of impurities.

First claim

What is claimed is:

1. A method for recovering water from purified terephthalic acid (PTA) production wastewater, comprising:
separating purified terephthalic acid from the PTA production wastewater to provide separated wastewater comprising an impurity selected from para-toluic acid, trimellitic acid, terephthalic acid, ortho-phthalic acid, benzoic acid, acetic acid, 4-carboxybenzaldehyde, or a combination comprising at least one of the foregoing;
transferring the separated wastewater to a tank;
adjusting the pH of the separated wastewater to a pH of 4 to 10 with a basic solution;
adjusting the temperature of the separated wastewater;
passing the separated wastewater to a column;
contacting the separated wastewater with an ion exchange resin to remove the impurity from the separated wastewater;
tuning contacting of the separated wastewater with the ion exchange resin by varying hydraulic parameters or selection of the ion exchange resin to
separate aromatic carboxylic acids from aliphatic carboxylic acids; and/or
separate aromatic or aliphatic monoacids from di/tri acids containing an aromatic moiety; and

recovering water depleted of the impurity.

2. The method of claim 1 , wherein the pH of the separated wastewater is adjusted to a pH of 5 to 9 with the basic solution.

3. The method of claim 1 , wherein the basic solution is selected from sodium hydroxide, potassium hydroxide, or a combination comprising at least one of the foregoing.

4. The method of claim 1 , wherein the separated wastewater is contacted with the ion exchange resin at a separated wastewater temperature of 10° C. to 60° C.

5. The method of claim 1 , wherein the separated wastewater is a first-stage filtrate emanating from PTA production.

6. A method for recovering water from purified terephthalic acid (PTA) production wastewater, comprising:
separating purified terephthalic acid from the PTA production wastewater to provide separated wastewater comprising an impurity selected from para-toluic acid, trimellitic acid, terephthalic acid, ortho-phthalic acid, benzoic acid, acetic acid, 4-carboxybenzaldehyde, or a combination comprising at least one of the foregoing;
transferring the separated wastewater to a tank;
adjusting the pH of the separated wastewater to a pH of 5 to 9 with a basic solution;
adjusting the temperature of the separated wastewater to 30 to 45° C.;
passing the separated wastewater to a column;
contacting the separated wastewater with an ion exchange resin to remove the impurity from the separated wastewater;
tuning contacting of the separated wastewater with the ion exchange resin by varying hydraulic parameters or selection of the ion exchange resin to
separate aromatic carboxylic acids from aliphatic carboxylic acids; and/or
separate aromatic or aliphatic monoacids from di/tri acids containing an aromatic moiety; and

recovering water depleted of the impurity.

7. The method of claim 1 , further comprising regenerating the ion exchange resin with the basic solution, wherein the basic solution is selected from sodium hydroxide, sodium carbonate, ammonia, potassium hydroxide, potassium carbonate, or a combination comprising at least one of the foregoing.

8. The method of claim 1 , wherein the ion exchange resin comprises a matrix comprising polystyrene, aliphatic polyamine, mixed polyalkylene amine, styrene divinyl benzene copolymers, resins containing amine functional groups, resins containing amine derivatives, or combination comprising at least one of the foregoing.

9. The method of claim 1 , wherein the water depleted of the impurity contains 1 ppm to 100 ppm of the impurity.

10. The method of claim 1 , wherein the water depleted of the impurity contains 0.1 ppm to 10 ppm para-toluic acid, and/or wherein the water depleted of the impurity contains 1 ppm to 10 ppm benzoic acid, and/or wherein the water depleted of the impurity contains 1 ppm to 100 ppm acetic acid.

11. The method of claim 1 , wherein the water depleted of the impurity comprises 30% to 80% less of the impurity after contact with the ion exchange resin.

12. The method of claim 11 , wherein the water depleted of the impurity contains at least 99.5% less of the impurity as compared to the separated wastewater.

13. The method of claim 1 , wherein the separated wastewater is contacted with the ion exchange resin in the column at a pressure of 0.1 MegaPascal to 0.3 MegaPascal.

14. The method of claim 1 , wherein the ion exchange resin separates aromatic carboxylic acids from aliphatic carboxylic acids.

15. The method of claim 1 , wherein the ion exchange resin separates aromatic or aliphatic monoacids from di/tri acids containing an aromatic moiety.

16. The method of claim 15 , wherein the aliphatic acids comprise acetic acid, acrylic acid, propionic acid, or a combination comprising at least one of the foregoing.

17. A method for recovering water from purified terephthalic acid (PTA) production wastewater, comprising:
separating purified terephthalic acid from t PTA production wastewater to provide separated wastewater comprising an impurity selected from para-toluic acid, trimellitic acid, terephthalic acid, orthophthalic acid, benzoic acid, acetic acid, or a combination comprising at least one of the foregoing;
transferring the separated wastewater to a tank;
adjusting the pH of the separated wastewater to a pH of 5 to 9;
adjusting the temperature of the separated wastewater to 25° C. to 50° C.;
passing the separated wastewater to a column;
contacting the separated wastewater with an ion exchange resin to remove the impurity from the separated wastewater;
tuning contacting of the separated wastewater with the ion exchange resin by varying hydraulic parameters or selection of the ion exchange resin to
separate aromatic carboxylic acids from aliphatic carboxylic acids; and/or
separate aromatic or aliphatic monoacids from di/tri acids containing an aromatic moiety;

recovering water depleted of the impurity, which contains at least 99% less of the impurity as compared to the separated wastewater; and
regenerating the ion exchange resin with dilute sodium hydroxide;
wherein the separated wastewater is contacted with the ion exchange resin in the column at a pressure of 0.1 MegaPascal to 0.3 MegaPascal.

18. The method of claim 17 , wherein the water depleted of the impurity contains 1 ppm to 100 ppm of the impurity.

19. The method of claim 17 , wherein the water depleted of the impurity contains at least 99.5% less of the impurity as compared to the separated wastewater.

20. The method of claim 1 , wherein tuning contacting of the separated wastewater with the ion exchange resin to separate aromatic carboxylic acids from aliphatic carboxylic acids; separate aromatic or aliphatic monoacids from di/tri acids containing an aromatic moiety; or a combination comprising at least one of the foregoing comprises varying hydraulic parameters.

Assignees

• Sabic Global Technologies Bv

Inventors

• Van Lier Roy
• Hashmi Syed Azhar
• Chaitanya Vadlamani Prasad Rao
• Mohandas Sandeep P
• Al-Subhi Muhammad Mosleh
• Sangjoo Lee
• Haneef Hasan Mohammed Rashad

Classifications

• B01J47/04

  Mixed-bed processes · CPC title

• B01J49/07

  containing anionic exchangers · CPC title

• C02F2103/38

  Polymers · CPC title

• B01J41/05

  in the strongly basic form · CPC title

• B01J41/07

  in the weakly basic form · CPC title