Utilization of pollutants from internal combustion engines

Patent metadata

Field	Value
Publication number	US-10919769-B2
Application number	US-201816637618-A
Country	US
Kind code	B2
Filing date	Dec 3, 2018
Priority date	Jan 18, 2018
Publication date	Feb 16, 2021
Grant date	Feb 16, 2021

Abstract

Nitrogen oxides formed in combustion engines are recycled such that the nitrogen oxides can be utilized for producing liquid or solid chemicals. The nitrogen oxides are recycled by a method including an adsorber material adsorbing nitrogen oxides from an exhaust-gas stream of the combustion engine, removing the adsorber material laden with nitrogen oxides, desorbing the adsorbed nitrogen oxides from the adsorber material, and converting the nitrogen oxides desorbed from the adsorber material into liquid or solid nitrogen-containing compounds.

First claim

The invention claimed is:

1. A system for recycling nitrogen oxides formed in a combustion engine, the system comprising:
an adsorber unit having an adsorber material including at least one zeolite configured to adsorb nitrogen oxides from an exhaust-gas stream of the combustion engine, the adsorber unit being configured as an exchangeable cartridge or such that adsorber material laden with nitrogen oxides is removable from the adsorber unit so that another adsorber material, unladen with nitrogen oxides, can be accommodated in the adsorber unit, in a non-destructive manner;
a desorption module, detached from the combustion engine and provided outside of the exhaust-gas stream, configured to desorb, from the adsorber material, nitrogen oxides that have been adsorbed by the adsorber material; and
a reaction unit, detached from the combustion engine and provided outside of the exhaust-gas stream, configured to convert the nitrogen oxides desorbed by the desorption module into liquid or solid nitrogen-containing compounds.

2. The system according to claim 1 , wherein
the adsorber unit is configured such that adsorber material laden with nitrogen oxides is removable from the adsorber unit, and
the adsorber unit is configured as a reclosable container from which the adsorber material is removable after opening of the reclosable container.

3. The system according to claim 1 , wherein
the desorption module is configured to heat the adsorber unit, or feed hot water vapor, hot gas or a liquid solvent to the adsorber unit, and thereby desorb nitrogen oxides from the adsorber unit, or
the desorption module is configured to heat the adsorber material laden with nitrogen oxides, or to treat the adsorber material with hot water vapor, hot gas or a liquid solvent, and thereby desorb nitrogen oxides from the adsorber material.

4. The system according to claim 1 , wherein the reaction unit includes a reactor to convert nitrogen oxides to form nitric acid.

5. The system according to claim 4 , wherein the reaction unit includes another reactor to convert the nitric acid with ammonia to form ammonium nitrate.

6. A system, for recycling nitrogen oxides formed in a combustion engine, the system comprising:
an adsorber unit having an adsorber material including at least one zeolite configured to adsorb nitrogen oxides from an exhaust-gas stream of the combustion engine;
a desorption module, detached from the combustion engine and provided outside of the exhaust-gas stream, configured to desorb, from the adsorber material, nitrogen oxides that have been adsorbed by the adsorber material; and
a reaction unit, detached from the combustion engine and provided outside of the exhaust-gas stream, configured to convert the nitrogen oxides desorbed by the desorption module into liquid or solid nitrogen-containing compounds, the reaction unit including a reactor to convert nitrogen oxides to form nitric acid.

7. The system according to claim 6 , wherein the reaction unit includes another reactor to convert the nitric acid with ammonia to form ammonium nitrate.

8. The system according to claim 6 , wherein
the desorption module is configured to heat the adsorber unit, or feed hot water vapor, hot gas or a liquid solvent to the adsorber unit, and thereby desorb nitrogen oxides from the adsorber unit, or
the desorption module is configured to heat the adsorber material laden with nitrogen oxides, or to treat the adsorber material with hot water vapor, hot gas or a liquid solvent, and thereby desorb nitrogen oxides from the adsorber material.

9. A method for the recycling of nitrogen oxides formed in a combustion engine, the method comprising:
adsorbing, in an adsorber unit having an adsorber material including at least one zeolite, nitrogen oxides from an exhaust-gas stream of the combustion engine, the adsorber unit being configured as an exchangeable cartridge or such that adsorber material laden with nitrogen oxides is removable from the adsorber unit so that another adsorber material, unladen with nitrogen oxides, can be accommodated in the adsorber unit, in a non-destructive manner;
removing the adsorber unit having the adsorber material laden with nitrogen oxides or removing the adsorber material laden with nitrogen oxides from the adsorber unit, to a desorption module, the desorption module being detached from the combustion engine and provided outside of the exhaust-gas stream;
desorbing, by the desorption module, the adsorbed nitrogen oxides from the adsorber material; and
converting, by a reaction unit detached from the combustion engine and provided outside of the exhaust-gas stream, the nitrogen oxides desorbed from the adsorber material into liquid or solid nitrogen-containing compounds.

10. The method according to claim 9 , wherein the liquid or solid nitrogen-containing compounds include nitrates.

11. The method according to claim 10 , wherein the nitrates include ammonium nitrates.

12. The method according to claim 9 , wherein the at least one zeolite includes ZSM-5, zeolite Y, or mordenite.

13. The method according to claim 9 , wherein
the adsorber unit is configured as the exchangeable cartridge,
the adsorber unit is provided in an exhaust tract of the combustion engine, and
the method comprises:
removing the adsorber unit from the exhaust tract; and
providing another adsorber unit, having an adsorber material unladen with nitrogen oxides, in the exhaust tract of the combustion engine.

14. The method according to claim 9 , wherein
the adsorber unit is such that the adsorber material laden with nitrogen oxides is removable from the adsorber unit,
the adsorber material is provided in a container of the adsorber unit, and
the method comprises:
removing the adsorber material laden with nitrogen oxides from the container; and
providing another adsorber material, unladen with nitrogen oxides, in the container.

15. The method according to claim 9 , wherein removing the adsorber unit having the adsorber material laden with nitrogen oxides or removing the adsorber material laden with nitrogen oxides from the adsorber unit, is performed in response to reaching a capacity of the adsorber unit for accommodating nitrogen oxides.

16. The method according to claim 9 , wherein desorbing the adsorbed nitrogen oxides from the adsorber material includes:
treating the adsorber material with at least one of heat, hot vapor, hot gas, and a liquid solvent, and
separating the nitrogen oxides from the adsorber material.

17. The method according to claim 16 , wherein the treating of the adsorber material with the at least one of heat, hot vapor, hot gas, and the liquid solvent, is performed at a temperature of 200° C. or less.

18. The method according to claim 17 , further comprising drying the adsorber material at a temperature of 200° C. or less.

19. The method according to claim 9 , further comprising after removing the adsorber unit having the adsorber material laden with nitrogen oxides or after removing the adsorber material laden with nitrogen oxides from the adsorber unit, storing the adsorber material laden with nitrogen oxides at a collection point together with a plurality of other adsorber materials laden with nitrogen oxides, and
desorbing the adsorbed nitrogen oxides from the adsorber material includes desorbing the adsorbed nitrogen oxides from the adsorber material together with desorbing the adsorbed nitrogen oxides from the plurality of other adsorber materials.

Assignees

• Audi Ag

Inventors

• Müller-Hellwig Simone
• Seifert Hagen
• Heigl Roland
• Krajete Alexander
• Seifert Arne

Classifications

• F01N2570/14

  Nitrogen oxides · CPC title

• F01N2450/30

  Removable or rechangeable blocks or cartridges, e.g. for filters · CPC title

• F01N2370/04

  Zeolitic material · CPC title

• F01N2260/04

  for regeneration or reactivation, e.g. of catalyst · CPC title

• F01N3/0871

  using means for controlling, e.g. purging, the absorbents or adsorbents · CPC title