Oxidation control for improved flue gas desulfurization performance

Patent metadata

Field	Value
Publication number	US-10919016-B2
Application number	US-201715433230-A
Country	US
Kind code	B2
Filing date	Feb 15, 2017
Priority date	Feb 15, 2017
Publication date	Feb 16, 2021
Grant date	Feb 16, 2021

Abstract

A system and method of using the system for controlling oxidation of sulfites to reduce total nitrite and nitrate levels in a slurry is disclosed. The system includes a tank having an inlet for receiving a slurry produced in a wet flue gas desulfurization process. The tank also includes an inlet for receiving a gas. The inlet for receiving the gas is operable to disperse at least a portion of the gas received in the tank through at least a portion of the slurry received in the tank. A sensor is configured to measure a sulfite concentration of the slurry received in the tank to obtain a sulfite concentration measurement. In some embodiments, the sensor is a sulfite analyzer. In other embodiments, the sensor is a virtual analyzer. The system also includes a controller. Software executing on the controller generates an electronic signal affecting an adjustment of a flow rate of gas into the slurry in the tank based at least in part on the sulfite concentration/sulfite concentration measurement.

First claim

The invention claimed is:

1. A system for controlling oxidation of sulfites to reduce total nitrite and nitrate levels in a slurry, comprising:
a tank for receiving a slurry and having an inlet for receiving a gas, the inlet for receiving the gas configured for dispersal of at least a portion of the gas through at least a portion of the slurry in the tank;
a sensor configured to measure a sulfite concentration S 1 of the slurry in the tank to obtain a sulfite concentration measurement;
a controller configured to adjust a flow rate of the gas into the slurry in the tank in dependence upon the sulfite concentration S 1 /sulfite concentration measurement to adjust oxidation of the sulfite contained in the slurry to less than 100%, effective to reduce nitrite and nitrate levels in the slurry.

2. The system of claim 1 , wherein the controller is configured to adjust the flow rate of the gas into the slurry based on a predetermined sulfite concentration of the slurry.

3. The system of claim 1 , wherein the gas is an oxygen-containing gas.

4. The system of claim 1 , further comprising:
a spray tower configured to provide for wet flue gas desulfurization of a flue gas provided to the spray tower;
wherein the slurry in the tank is produced via the wet flue gas desulfurization of the flue gas.

5. The system of claim 1 , wherein the sensor comprises a sulfite analyzer.

6. The system of claim 1 , wherein the sensor comprises a virtual analyzer.

7. The system of claim 4 , wherein the tank is in a structure separate from the spray tower structure in which the slurry is produced; and
wherein the tank and the spray tower are fluidly interconnected via a conduit.

8. The system of claim 1 , further comprising:
a spray tower in fluid communication with the tank;
a supply of alkaline slurry;
at least one conduit providing for fluid communication with the slurry in the tank;
a plurality of nozzles configured to disperse the alkaline slurry from the supply and/or the slurry from the tank into an interior of the spray tower.

9. The system of claim 8 , wherein:
the controller is configured to adjust a supply rate and/or supply ratio of alkaline slurry and/or slurry from the tank to the plurality of nozzles in dependence upon the sulfite concentration S 1 /sulfite concentration measurement.

10. The system of claim 8 , wherein:
the plurality of nozzles are arranged in at least a first nozzle array and a second nozzle array;
wherein the first nozzle array is located above the second nozzle array; and
wherein the controller is configured to adjust a supply of the alkaline slurry and/or slurry from the tank to the first nozzle array and/or the second nozzle array in dependence upon the sulfite concentration S 1 /sulfite concentration measurement.

11. A method of controlling oxidation of sulfites to reduce total nitrite and nitrate levels in a slurry comprising the steps of:
receiving a slurry in a tank, the slurry comprising one or more sulfites;
supplying a flow of a gas at a flow rate into the slurry in the tank;
measuring with a sensor a sulfite concentration of the slurry in the tank to obtain a sulfite concentration measurement; and
adjusting the flow rate of the gas into the slurry based on the sulfite concentration/sulfite concentration measurement to adjust oxidation of the sulfite contained in the slurry to less than 100%, effective to reduce total nitrite and nitrate levels in the slurry.

12. The method of claim 11 , wherein adjusting the flow rate of the gas is further based on a predetermined sulfite concentration of the slurry.

13. The method of claim 11 , wherein the sensor comprises a sulfite analyzer used for measuring sulfite concentration.

14. The method of claim 11 , wherein oxidation is less than 100%, and total nitrite and nitrate levels in the slurry are reduced by 50% or greater as compared to total nitrite and nitrate levels in the slurry at 100% oxidation.

15. The method of claim 11 , wherein the slurry comprises about 5 ppm to about 80 ppm of sulfite.

16. The method of claim 11 , further comprising adjusting alkaline slurry supply based on the sulfite concentration/sulfite concentration measurement to adjust oxidation of the sulfite contained in the slurry to less than 100%, effective to reduce total nitrite and nitrate levels in the slurry.

17. The method of claim 11 , wherein the gas is an oxygen-containing gas.

18. The method of claim 11 , wherein the sensor comprises a virtual analyzer.

Assignees

• General Electric Technology Gmbh

Inventors

• Gansley Raymond Raulfs

Classifications

• B01D53/80 Primary

  Semi-solid phase processes, i.e. by using slurries · CPC title

• B01D53/78

  with gas-liquid contact · CPC title

• B01D53/48

  Sulfur compounds · CPC title

• B01D53/30

  Controlling by gas-analysis apparatus (regulating non electrical variables in general G05D) · CPC title

• B01D47/063

  with two or more jets impinging against each other · CPC title