Dispersant for resin collectors, material for resin collectors, and resin collector

Patent metadata

Field	Value
Publication number	US-10916779-B2
Application number	US-201816135622-A
Country	US
Kind code	B2
Filing date	Sep 19, 2018
Priority date	Jul 8, 2013
Publication date	Feb 9, 2021
Grant date	Feb 9, 2021

Abstract

An object of the present invention is to provide a dispersant for a resin current collector which can uniformly disperse a conductive filler to attain sufficient charge and discharge characteristics without impairing the output power per unit weight of a battery. The present invention provides a dispersant for a resin current collector comprising a polymer having a resin-philic block (A1) and a conductive filler-philic block (A2).

First claim

The invention claimed is:

1. A resin current collector for lithium secondary batteries comprising a material, the material comprising a dispersant (A), a resin (B), and a conductive filler (C),
the dispersant (A) comprising a polymer having a resin-philic block (A1) and a conductive filler-philic block (A2),
wherein the polymer having a resin-philic block (A1) and a conductive filler-philic block (A2) is a polymer wherein the resin-philic block (A1) is a polymer block composed of an olefin (a1) having 2 to 30 carbon atoms as an essential constituent monomer, and a functional group contained in the conductive filler-philic block (A2) is at least one selected from the group consisting of a cyano group, a hydroxyl group, an amino group, an amide group, and an imide group, wherein a total concentration of a cyano group, a hydroxyl group, an amino group, an amide group, and an imide group in the dispersant (A) is 1 to 40% by weight based on a weight of the dispersant (A),
wherein the conductive filler (C) comprises metal particles or carbon particles,
when the conductive filler (C) comprises metal particles, the dispersant (A) is contained in an amount of 1 to 20% by weight, the resin (B) is contained in an amount of 20 to 27% by weight, and the conductive filler (C) is contained in an amount of 71 to 79% by weight, based on a weight of the material, and
when the conductive filler (C) comprises carbon particles, the dispersant (A) is contained in an amount of 1 to 20% by weight, the resin (B) is contained in an amount of 20 to 85% by weight, and the conductive filler (C) is contained in an amount of 10 to 79% by weight, based on a weight of the material, and
wherein a weight ratio {(A1)/(A2)} of the resin-philic block (A1) to the conductive filler-philic block (A2) is 50/50 to 99/1.

2. The resin current collector according to claim 1 ,
wherein the resin current collector has a thickness of 5 to 200 μm.

3. The resin current collector according to claim 1 ,
wherein the dispersant (A) has a weight average molecular weight of 10,000 to 100,000.

4. The resin current collector according to claim 1 ,
wherein the conductive filler-philic block (A2) is a polymer block composed of an ethylenically unsaturated monomer (a2) as an essential constituent monomer, the ethylenically unsaturated monomer (a2) having at least one functional group selected from the group consisting of a cyano group, a hydroxyl group, an amino group, an amide group, and an imide group.

5. The resin current collector according to claim 4 ,
wherein the ethylenically unsaturated monomer (a2) is contained in monomers forming the conductive filler-philic block (A2) in a proportion of 50 to 100% by weight based on a weight of the conductive filler-philic block (A2).

6. The resin current collector according to claim 1 ,
wherein the conductive filler-philic block (A2) is a polymer block composed of an ethylenically unsaturated monomer (a2) as an essential constituent monomer, the ethylenically unsaturated monomer (a2) having at least one functional group selected from the group consisting of a cyano group, a hydroxyl group, an amino group, an amide group, and an imide group, and
wherein the dispersant (A) is a polymer wherein a polymer (A″1) is added into the ethylenically unsaturated monomer (a2), wherein the polymer (A″1) has an unsaturated group and is a thermally degraded polymer of the olefin (a1).

7. The resin current collector according to claim 1 ,
wherein the resin (B) is polyethylene (PE), polypropylene (PP), polymethylpentene (PMP), polycycloolefin (PCO), polyethylene terephthalate (PET), polyether nitrile (PEN), polytetrafluoroethylene (PTFE), styrene butadiene rubber (SBR), polyacrylonitrile (PAN), poly(methyl acrylate) (PMA), poly(methyl methacrylate) (PMMA), polyvinylidene difluoride (PVdF), an epoxy resin, a silicone resin, or a mixture thereof.

8. The resin current collector according to claim 1 ,
wherein the conductive filler (C) has an average particle size of 0.01 to 10 μm.

9. The a resin current collector according to claim 1 ,
wherein the conductive filler (C) is nickel, aluminum, stainless steel, carbon, silver, copper, titanium, or a mixture thereof.

10. A resin current collector for lithium secondary batteries comprising a material, the material comprising a dispersant (A), a resin (B), and a conductive filler (C),
the dispersant (A) comprising a polymer having a resin-philic block (A1) and a conductive filler-philic block (A2),
wherein the polymer having a resin-philic block (A1) and a conductive filler-philic block (A2) is a polymer wherein the resin-philic block (A1) is a polymer block composed of an olefin (a1) having 2 to 30 carbon atoms as an essential constituent monomer, and a functional group contained in the conductive filler-philic block (A2) is at least one selected from the group consisting of a cyano group, a hydroxyl group, an amino group, an amide group, and an imide group, wherein a total concentration of a cyano group, a hydroxyl group, an amino group, an amide group, and an imide group in the dispersant (A) is 1 to 40% by weight based on a weight of the dispersant (A), and
wherein the conductive filler (C) comprises metal particles or carbon particles,
when the conductive filler (C) comprises metal particles, the dispersant (A) is contained in an amount of 1 to 20% by weight, the resin (B) is contained in an amount of 20 to 27% by weight, and the conductive filler (C) is contained in an amount of 71 to 79% by weight, based on a weight of the material, and
when the conductive filler (C) comprises carbon particles, the dispersant (A) is contained in an amount of 1 to 20% by weight, the resin (B) is contained in an amount of 20 to 85% by weight, and the conductive filler (C) is contained in an amount of 10 to 79% by weight, based on a weight of the material, and
wherein an absolute value of a difference between a solubility parameter of the resin (B) and a solubility parameter of the resin-philic block (A1) in the dispersant (A), {solubility parameter of (B)}−{solubility parameter of (A1)}, is 1.0 (cal/cm 3 ) 1/2 or less.

11. A resin current collector for lithium secondary batteries comprising a material, the material comprising a dispersant (A), a resin (B), and a conductive filler (C),
the dispersant (A) comprising a polymer having a resin-philic block (A1) and a conductive filler-philic block (A2),
wherein the polymer having a resin-philic block (A1) and a conductive filler-philic block (A2) is a polymer wherein the resin-philic block (A1) is a polymer block composed of an olefin (a1) having 2 to 30 carbon atoms as an essential constituent monomer, and a functional group contained in the conductive filler-philic block (A2) is at least one selected from the group consisting of a cyano group, a hydroxyl group, an amino group, an amide group, and an imide group, wherein a total concentration of a cyano group, a hydroxyl group, an amino group, an amide group, and an imide group in the dispersant (A) is 1 to 40% by weight based on a weight of the dispersant (A), and
wherein the conductive filler (C) comprises metal particles or carbon particles,
when the conductive filler (C) comprises metal particles, the dispersant (A) is contained in an amount of 1 to 20% by weight, the resin (B) is contained in an amount of 20 to 27% by weight, and the conductive filler (C) is contained in an amount of 71 to 79% by weight, based on a weight of the material, and
when the conductive filler (C) comprises carbon particles, the dispersant (A) is contained in an amount of 1 to 20% by weight, the resin (B) is contained in an amount of 20 to 85% by weight, and the conductive filler (C) is contained in a

Assignees

• Sanyo Chemical Ind Ltd
• Nissan Motor

Inventors

• Fukumoto Hiroshi
• Shindo Yasuhiro
• Watanabe Manabu
• Akama Hiroshi
• Horie Hideaki

Classifications

• C08L51/06

  grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond · CPC title

• C08K3/08

  Metals · CPC title

• C08L23/02

  not modified by chemical after-treatment · CPC title

• C08L67/04

  Polyesters derived from hydroxycarboxylic acids, e.g. lactones (C08L67/06 takes precedence) · CPC title

• C08L23/12

  Polypropene · CPC title