Cathode for metal-air battery including spaces for accommodating metal oxides formed during discharge of metal-air battery and metal-air battery including the same

Patent metadata

Field	Value
Publication number	US-10916762-B2
Application number	US-201715795841-A
Country	US
Kind code	B2
Filing date	Oct 27, 2017
Priority date	Nov 1, 2016
Publication date	Feb 9, 2021
Grant date	Feb 9, 2021

Abstract

Provided is a metal-air battery including a cathode having a space which may be filled with a metal oxide formed during a discharge of the metal-air battery and thus having improved energy density and lifespan. The cathode for the metal-air battery includes a plurality of cathode materials, a plurality of electrolyte films disposed on surfaces of the plurality of cathode materials, and a plurality of spaces which are not occupied by the plurality of cathode materials and the plurality of electrolyte films. A volume of the plurality of spaces may be greater than or equal to a maximum space of a metal oxide formed during a discharge of the metal-air battery.

First claim

What is claimed is:

1. A cathode for a metal-air battery, the cathode comprising:
a plurality of cathode materials regularly arranged therein; and
a plurality of electrolyte films disposed on surfaces of the plurality of cathode materials,
wherein a plurality of spaces, which is not occupied by the plurality of cathode materials and the plurality of electrolyte films, is defined by the plurality of electrolyte films between the plurality of cathode materials,
wherein each of the plurality of spaces is disposed between two surfaces facing each other of two adjacent electrolyte films of the plurality of electrolyte films, and
wherein the plurality of spaces and the plurality of cathode materials are alternately disposed.

2. The cathode of claim 1 , wherein the plurality of electrolyte films are formed of an organic material.

3. The cathode of claim 1 , wherein a volume of each of the plurality of spaces is equal to or less than 120% of a predetermined volume.

4. The cathode of claim 1 , wherein the plurality of cathode materials are spaced apart from each other.

5. The cathode of claim 1 , wherein each of the plurality of spaces is directly surrounded by the two surfaces facing each other of the two adjacent electrolyte films of the plurality of electrolyte films.

6. The cathode of claim 1 , wherein
a width of each of the plurality of spaces is defined as a distance between electrolyte films facing each other between two adjacent cathode materials, and
the width of each of the plurality of spaces is greater than about 20 nm.

7. The cathode of claim 6 , wherein
each of the plurality of cathode materials has a thickness of about 10 nm or less, and
each of the plurality of electrolyte films has a thickness of about 10 nm or less.

8. The cathode of claim 1 , wherein the plurality of cathode materials each have a flat panel shape, and are arranged in parallel to each other.

9. The cathode of claim 8 , wherein each of the plurality of cathode materials comprises:
a first surface and a second surface which are opposite to each other; and
a third surface and a fourth surface which are opposite to each other and extend between the first surface and the second surface,
wherein each of areas of the third surface and the fourth surface is smaller than each of areas of the first surface and the second surface,
wherein the plurality of cathode materials are arranged in a way such that the first and second surfaces of two adjacent cathode materials face each other.

10. The cathode of claim 9 , wherein the plurality of electrolyte films are disposed at least on the first and second surfaces of each of the plurality of cathode materials.

11. A metal-air battery comprising:
a cathode comprising a plurality of cathode materials regularly arranged therein and a plurality of electrolyte films disposed on surfaces of the plurality of cathode materials;
an anode metal layer configured to supply metal ions to the plurality of cathode materials of the cathode; and
a gas diffusion layer configured to supply oxygen to the plurality of cathode materials,
wherein a space, which is not occupied by the plurality of cathode materials and the plurality of electrolyte films, is defined by the plurality of electrolyte films between the plurality of cathode materials, and
wherein a volume of the space is greater than or equal to a maximum volume of a metal oxide formed between each of the plurality of cathode materials and a corresponding one of the plurality of electrolyte films during a discharge of the metal-air battery.

12. The metal-air battery of claim 11 , wherein each of the plurality of electrolyte films of the cathode comprises:
a first electrolyte portion disposed on a top surface of the anode metal layer; and
a second electrolyte portion extending from the first electrolyte portion to a surface of one of the plurality of cathode materials.

13. The metal-air battery of claim 12 , wherein the plurality of cathode materials are arranged in a way such that each of a first end portions thereof is in contact with a corresponding one of the first electrolyte portions and second end portions thereof are in contact with the gas diffusion layer.

14. The metal-air battery of claim 12 , further comprising a third electrolyte portion which transmits metal ions and blocks moisture and oxygen,
wherein the third electrolyte portion is disposed between the first electrolyte portion and the anode metal layer.

Assignees

• Samsung Electronics Co Ltd

Inventors

• Lee Heungchan
• Im Dongmin
• Lee Hyunpyo

Classifications

• H01M2004/8689

  Positive electrodes · CPC title

• H01M12/08 Primary

  composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type · CPC title

• H01M4/96 Primary

  Carbon-based electrodes · CPC title

• H01M4/8626 Primary

  characterised by the form · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title