Method for producing rare-earth magnets, and rare-earth-compound application device

Patent metadata

Field	Value
Publication number	US-10916372-B2
Application number	US-201615569888-A
Country	US
Kind code	B2
Filing date	Apr 18, 2016
Priority date	Apr 28, 2015
Publication date	Feb 9, 2021
Grant date	Feb 9, 2021

Abstract

When a slurry 41 obtained by dispersing a rare-earth-compound powder in a solvent is applied to sintered magnet bodies 1 , and dried to remove the solvent in the slurry and cause the surfaces of the sintered magnet bodies to be coated with the powder, and the sintered magnet bodies coated with the powder are heat treated to cause the rare-earth element to be absorbed by the sintered magnet bodies, the sintered magnet bodies having had the slurry applied thereto are dried by being irradiated with near infrared radiation having a wavelength of 0.8-5 μm, to remove the solvent in the slurry, and cause the surfaces of the sintered magnet bodies to be coated with the powder. As a result, the rare-earth-compound powder can be uniformly and efficiently applied to the surfaces of the sintered magnet bodies.

First claim

The invention claimed is:

1. A method for producing a rare-earth sintered magnet, the method comprising: holding a plurality of sintered magnet bodies by a rotatable jig, the sintered magnet bodies composed of a R1-Fe—B composition (R1 is at least one selected from rare-earth elements including Y and Sc), wherein a bottom part of the rotatable jig is formed of a net formed of metallic wires which are coated with fluororesin:
immersing the sintered magnet bodies held by the rotatable jig in a slurry obtained by dispersing a powder containing at least one selected from an oxide, a fluoride, an oxyfluoride, a hydroxide or a hydride of R2 (R2 is at least one selected from rare-earth elements including Y and Sc) in a solvent so that each of the sintered magnet bodies is coated with the slurry;
drawing up the slurry-coated sintered magnet bodies held by the rotatable jig from the slurry to allow the slurry to drain from the net of the bottom of the rotatable jig and rotating the slurry-coated sintered magnet bodies together with the jig to remove surplus slurry present on a surface of each of the sintered magnet bodies by a centrifugal force, wherein
the sintered magnet bodies held by the rotatable jig are disposed around a rotational axis of the rotatable jig and are inclined such that no part of any of outer surfaces constituting shapes of the sintered magnet bodes is orthogonal to the direction of the centrifugal force acting on each of the sintered magnet bodies;
drying the slurry to remove the solvent in the slurry and coat a surface of the sintered magnet bodies with the powder; and
heat treating the sintered magnet bodies coated with the powder to cause the R2 to be absorbed into the sintered magnet bodies,
wherein in the step of drying, the sintered magnet bodies coated with the slurry held by the rotating jig is dried by irradiation with near infrared radiation of a wavelength of 0.8 to 5 um, while rotating the rotatable jig, to remove the solvent in the slurry while exhausting the solvent evaporated by irradiation with the near infrared radiation from the surroundings of the sintered magnet bodies to the outside of the drying area.

2. The method for producing the rare-earth sintered magnet according to claim 1 , wherein the application process of immersing the sintered magnet bodies in the slurry, removing the surplus slurry and drying the slurry-coated sintered magnet bodies is repeated multiple times.

3. The method for producing the rare-earth sintered magnet according to claim 1 , wherein the jig is rotated normally and reversely at a low speed of 5 to 20 rpm in a state in which the sintered magnet bodies are immersed in the slurry, thereby to apply the slurry to the sintered magnet bodies.

4. The method for producing the rare-earth sintered magnet according to claim 1 , wherein the jig is drawn up from the slurry and rotated normally and reversely at a high speed of 170 to 550 rpm, thereby to remove the surplus slurry present on the surfaces of the sintered magnet bodies.

5. The method for producing the rare-earth sintered magnet according to claim 1 , wherein the application of the slurry is conducted by disposing the sintered magnet bodies around a rotational axis of the jig, and holding the sintered magnet bodies in an inclined state such that no part of any of outer surfaces constituting shapes of the sintered magnet bodies is orthogonal to a direction of the centrifugal force acting on each of the sintered magnet bodes.

6. The method for producing the rare-earth sintered magnet according to claim 5 , wherein the sintered magnet bodies are in a shape of a tetragonal plate or a tetragonal block, and each of the sintered magnet bodies is held by the jig in a state in which the sintered magnet body is erect with its thickness direction set horizontal and with its length direction or width direction inclined at an angle of more than 0° and less than 45° from the direction of the centrifugal force.

7. The method for producing the rare-earth sintered magnet according to claim 1 , wherein the sintered magnet bodies coated with the powder are heat treated in vacuum or an inert gas at temperature of up to sintering temperature of the sintered magnet bodies.

8. The method for producing the rare-earth sintered magnet according to claim 1 , wherein after the heat treatment, the sintered magnet bodies coated with the powder are subjected further to an ageing treatment at a temperature lower than temperature of the heat treating the sintered magnet bodies.

9. The method for producing the rare-earth magnet according to claim 1 , wherein the jig is rotated at a speed of 5 to 20 rpm during the step of drying.

Assignees

• Shinetsu Chemical Co

Inventors

• Kuribayashi Yukihiro
• Kamiya Shogo
• Maegawa Harukazu
• Tanaka Shintaro

Classifications

• H01F1/0577 Primary

  sintered · CPC title

• B05C3/09

  for treating separate articles · CPC title

• B05D2258/00

  Small objects (e.g. screws) · CPC title

• B05C9/14

  the auxiliary operation involving heating {or cooling} · CPC title

• B05D1/18

  performed by dipping · CPC title