Solid-state lithium-ion conductor and methods of manufacture thereof
US-11876225-B2 · Jan 16, 2024 · US
US10916357B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10916357-B2 |
| Application number | US-201114235748-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 29, 2011 |
| Priority date | Jul 29, 2011 |
| Publication date | Feb 9, 2021 |
| Grant date | Feb 9, 2021 |
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An object of the present invention is to provide an aluminum alloy foil for an electrode current collector and a manufacturing method thereof, the foil having a high strength and high strength after a drying process after the application of the active material while keeping a high electrical conductivity. Disclosed is a method for manufacturing an aluminum alloy foil for electrode current collector, including: forming by continuous casting an aluminum alloy sheet containing 0.03 to 1.0% of Fe, 0.01 to 0.2% of Si, 0.0001 to 0.2% of Cu, with the rest being Al and unavoidable impurities, performing cold rolling to the aluminum alloy sheet at a cold rolling reduction of 80% or lower, and performing heat treatment at 550 to 620° C. for 1 to 15 hours.
Opening claim text (preview).
The invention claimed is: 1. A positive electrode, comprising: an electrode current collector comprising an aluminum foil consisting of 0.03 to 1.0 mass % (hereinafter referred to as %) of Fe, 0.01 to 0.2% of Si, 0.0001 to 0.2% of Cu, Al, and unavoidable impurities, and lithium containing metal oxide provided on the electrode current collector, wherein an electrical conductivity of the aluminum alloy foil is 57% IACS or higher, and a particle number of an intermetallic compounds having a maximum diameter length of 0.1 to 1.0 μm or longer is 1.0×10 4 particles/mm 2 or more; and tensile strength of an original sheet after final cold rolling is preferably 180 MPa or higher, 0.2% yield strength thereof is preferably 160 MPa or higher, and tensile strength is 170 MPa or higher, and 0.2% yield strength is 150 MPa or higher even when heat treatment at 120° C. for 24 hours, at 140° C. for 3 hours, or at 160° C. for 15 minutes is performed. 2. A method for manufacturing the positive electrode of claim 1 , comprising the step of: applying lithium containing metal oxide onto an aluminum alloy foil, wherein the aluminum alloy foil is obtained by the method comprising the steps of: continuous casting an aluminum alloy sheet consisting of 0.03 to 1.0% of Fe, 0.01 to 0.2% of Si, 0.0001 to 0.2% of Cu, Al, and unavoidable impurities, performing cold rolling to the aluminum alloy sheet at a cold rolling reduction of 80% or lower, and performing heat treatment at 550 to 620° C. for 1 to 15 hours.
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