Use of semi-aromatic copolyamide for transporting refrigerant fluid

Patent metadata

Field	Value
Publication number	US-10914409-B2
Application number	US-201916276160-A
Country	US
Kind code	B2
Filing date	Feb 14, 2019
Priority date	Feb 18, 2013
Publication date	Feb 9, 2021
Grant date	Feb 9, 2021

Abstract

Provided is a method for heating or cooling a liquid or a body by means of a vapor compression circuit containing a heat transfer fluid. The vapor compression circuit element includes at least one layer that includes copolyamide of formula X/10.T/Y, where the structural variables are described herein.

First claim

The invention claimed is:

1. A method for heating or cooling a liquid or a body by means of a vapor compression circuit comprising a heat transfer fluid, comprising in succession in the vapor compression circuit:
evaporating the heat transfer fluid;
compressing the heat transfer fluid;
condensing the heat fluid; and
expanding the heat transfer fluid,

wherein
the vapor compression circuit also comprises at least one vapor compression circuit element;
the at least one vapor compression circuit element comprises a composition comprising at least one layer consisting of 30 to 99% by mass of least one copolyamide comprising units of formula X, 10.T and Y;
X represents alternatively the residues of an aliphatic amino acid comprising from 8 to 18 carbon atoms, or a lactam, or the unit X 1 .X 2 which represents the residues resulting from the condensation of an aliphatic diamine comprising from 6 to 18 carbon atoms and a (cyclo)aliphatic dicarboxylic acid comprising from 6 to 18 carbon atoms;
10.T represents the residues from the condensation of a decane diamine and terephthalic acid;
Y represents the residues from the condensation of an aliphatic diamine comprising from 9 to 14 carbon atoms and an aromatic dicarboxylic acid, Y being different from the unit 10.T;
the molar proportion of units 10.T in the copolyamide are greater than 0%;
the molar proportion of the units Y relative to the total of units 10.T and Y is from 0% to 30%; and
the proportion of units X is from 0.4 to 0.8 mol per mole of semi-aromatic units 10.T and Y.

2. The method of claim 1 , wherein the copolyamide is a copolyamide of formula X/10.T.

3. The method of claim 1 , wherein X represents either the residues of an aliphatic amino acid comprising from 10 to 12 carbon atoms or the unit X 1 .X 2 which represents the residues resulting from the condensation of an aliphatic diamine comprising from 6 to 12 carbon atoms and an aliphatic diacid comprising from 6 to 12 carbon atoms.

4. The method of claim 1 , wherein Y represents a unit 10.I, 9.T, 12.T, or 14.T.

5. The method of claim 1 , wherein the copolyamide is selected from the group consisting of copolyamides of formulae 11/10.T, 12/10.T, 6.10/10.T, 6.12/10.T, 10.6/10.T, 10.10/10.T, 10.12/10.T, 12.12/10.T, and 10.14/10.T.

6. The method of claim 1 , wherein the proportion of units X in the copolyamide is from 0.5 to 0.7 mol per mole of semi-aromatic units 10.T and Y.

7. The method of claim 1 , wherein the composition optionally further comprises at least one of:
one or more functionalized or non-functionalized polyolefins;
one or more plasticizers; or
one or more additives selected from the group consisting of conversion aids, fillers, heat stabilizers, UV stabilizers, nucleating agents, dyes, pigments, mold release agents, flame retardants, surfactants, fluorescent whiteners, antioxidants, and mixtures thereof.

8. The method of claim 1 , wherein the copolyamide is PA 11/10.T.

9. The method of claim 1 , wherein the composition further comprises a functionalized polyolefin.

10. The method of claim 9 , wherein the composition comprises 10% to 40% by weight of the functionalized polyolefin.

11. The method of claim 9 , wherein the functionalized polyolefin is an alpha-olefin polymer comprising a reactive unit.

12. The method of claim 11 , wherein the reactive unit is a carboxylic acid function, anhydride function, or an epoxy function.

13. The method of claim 1 , wherein the vapor compression circuit element is in contact with the heat transfer fluid.

14. The method of claim 13 , wherein the heat transfer fluid is admixed with a lubricant.

15. The method of claim 1 , wherein the vapor compression circuit is integrated into a device selected from the group consisting of mobile and stationary air conditioning devices, refrigeration devices, freezing devices, Rankine-cycle and heat-pump heating devices.

16. The method of claim 1 , wherein the vapor compression circuit element is a connection element or a pipe.

17. The method of claim 1 , wherein the layer is disposed on an inner surface of the vapor compression circuit element.

18. A method of claim 1 , wherein the vapor compression circuit element is a multilayer tube comprising in succession:
an inner layer comprising (i) the composition which comprises at least one layer consisting of 30 to 99% by mass of least one copolyamide comprising units of formula X, 10.T and Y and (ii) an elastomeric material; and
an outer layer comprising a composition which comprises an elastomeric material.

19. The method of claim 18 , wherein the multiplayer tube further comprises at least one of:
a first intermediate layer comprising a composition which comprises an elastomeric material; or
a second intermediate layer comprising a reinforcing textile.

20. The method of claim 1 , wherein the vapor compression circuit element is an extruded article.

21. The method of claim 1 , which is a method of heating, air conditioning, refrigerating, or freezing.

22. The method of claim 1 , wherein the heat transfer fluid is a compound selected from the group consisting of hydrocarbons, hydrofluorocarbons, ethers, hydrofluoroethers, and fluoroolefins.

23. The method of claim 1 , wherein the heat transfer fluid is a compound selected from the group consisting of hydrofluorocarbons, hydrofluoroethers, and fluoroolefins.

24. The method of claim 1 , wherein the heat transfer fluid comprises 2,3,3,3-tetrafluoropropene.

25. The method of claim 1 , wherein the heat transfer fluid is mixed with a lubricant.

26. The method of claim 1 , wherein the vapor compression circuit is integrated into a motor vehicle air conditioning device.

27. The method of claim 1 , wherein the vapor compression circuit comprises at least one evaporator, a compressor, a condenser, and an expander, and also lines for transporting heat transfer fluid between those components.

28. The method of claim 27 , wherein the evaporator and the condenser comprise a heat exchanger permitting an exchange of heat between a heat transfer fluid, which circulates within the vapor compression circuit, and another fluid or body.

Assignees

• Arkema France

Inventors

• Blondel Philippe
• Brule Benoît
• Gamache Eric
• Meurice Pierrat Estelle

Classifications

• B29C49/0005

  characterised by the material · CPC title

• B32B27/308 Primary

  comprising acrylic (co)polymers · CPC title

• F16L11/085 Primary

  comprising one or more braided layers (in combination with layers of a helically wound core or wire F16L11/088) · CPC title

• C09K2205/122

  Halogenated hydrocarbons · CPC title

• B29C48/022

  characterised by the choice of material · CPC title