Systems and methods for power production using a carbon dioxide working fluid

Patent metadata

Field	Value
Publication number	US-10914232-B2
Application number	US-201916289804-A
Country	US
Kind code	B2
Filing date	Mar 1, 2019
Priority date	Mar 2, 2018
Publication date	Feb 9, 2021
Grant date	Feb 9, 2021

Abstract

The present disclosure relates to systems and methods for power production utilizing a recirculating working fluid. In particular, a portion of the recirculating working fluid can be separated from the main stream of recirculating working fluid as a bypass stream that can be compressed for adding heat to the system.

First claim

The invention claimed is:

1. A method of power production comprising:
combusting fuel with an oxidant stream in a combustor in the presence of a recycle CO 2 stream at a pressure of 100 bar to 500 bar to form a combustion stream;
expanding the combustion stream to a lower pressure in a turbine to produce power and form a turbine exhaust stream;
cooling the turbine exhaust stream in a heat exchanger having a plurality of sections operating at different temperature ranges;
purifying the turbine exhaust to form a substantially pure CO 2 stream;
separating the substantially pure CO 2 stream into a first portion and a second portion;
pumping the first portion and the second portion of the substantially pure CO 2 stream to an increased pressure;
independently passing the first portion and the second portion of the substantially pure CO 2 stream through the heat exchanger to increase a temperature thereof;
passing the first portion of the substantially pure CO 2 stream to the combustor as the recycle CO 2 stream; and
passing the second portion of the substantially pure CO 2 stream to the combustor;
wherein the second portion of the substantially pure CO 2 stream bypasses at least one section of the plurality of sections of the heat exchanger by:
withdrawing the second portion of the substantially pure CO 2 stream upstream from the at least one section of the plurality of sections of the heat exchanger;
processing the second portion of the substantially pure CO 2 stream in a compressor so as to increase a pressure and a temperature of the second portion of the substantially pure CO 2 stream and thus form a bypass portion of the substantially pure CO 2 stream; and
entering the bypass portion of the substantially pure CO 2 stream into the heat exchanger downstream from the at least one section of the plurality of sections of the heat exchanger.

2. The method of claim 1 , wherein the substantially pure CO 2 stream is processed through a multi-stage compressor prior to separating into the first portion and the second portion.

3. The method of claim 1 , wherein the heat exchanger comprises at least a first section, a second section, and a third section each operating at successively lower temperature ranges.

4. The method of claim 3 , wherein the second portion of the substantially pure CO 2 stream bypasses the second section of the heat exchanger and is heated in the first section and the third section of the heat exchanger.

5. The method of claim 1 , wherein the bypass portion of the substantially pure CO 2 stream enters into the heat exchanger by being combined with the first portion of the substantially pure CO 2 stream downstream from the at least one section of the plurality of sections of the heat exchanger.

6. The method of claim 1 , wherein first portion of the substantially pure CO 2 stream is divided to form a third portion of the substantially pure CO 2 stream, and wherein the third portion of the substantially pure CO 2 stream is combined with an oxygen stream to form the oxidant stream.

7. The method of claim 1 , wherein the second portion of the substantially pure CO 2 stream is combined with an oxygen stream before the second portion of the substantially pure CO 2 stream bypasses the at least one section of the plurality of sections of the heat exchanger such that the bypass portion of the substantially pure CO 2 stream exits the heat exchanger as the oxidant stream.

8. The method of claim 7 , wherein after the second portion of the substantially pure CO 2 stream is combined with the oxygen stream but before the second portion of the substantially pure CO 2 stream is passed through the heat exchanger, the second portion of the substantially pure CO 2 stream including the combined oxygen stream is heated in a heat exchanger.

9. The method of claim 1 , wherein one or more of the following conditions is met:
the combustion stream is at a temperature of 700° C. to 1,600° C.;
the turbine exhaust stream is at a pressure of 1 bar to 50 bar;
said purifying comprises separating water from the turbine exhaust stream;
prior to said pumping, the substantially pure CO 2 stream is compressed in a multi-stage compressor to a pressure of 65 bar to 90 bar;
the first portion of the substantially pure CO 2 stream is pumped to a pressure of 100 bar to 500 bar;
the second portion of the substantially pure CO 2 stream is pumped to a pressure of 80 bar to 140 bar;
processing the second portion of the substantially pure CO 2 stream in the compressor comprises increasing the pressure to 200 bar to 500 bar.

10. The method of claim 9 , further comprising mixing an oxygen stream from an air separation plant with one of the first portion and the second portion of the substantially pure CO 2 stream to form the oxidant stream.

11. The method of claim 1 , wherein a quantity of the second portion of the substantially pure CO 2 stream that bypasses the at least one section of the plurality of sections of the heat exchanger is sufficient to give a positive minimum temperature difference in the at least one section of the heat exchanger of 2° C. to 20° C.

12. The method of claim 1 , wherein the second portion of the substantially pure CO 2 stream that is upstream from the at least one section of the plurality of sections of the heat exchanger and the bypass portion of the substantially pure CO 2 stream entered into the heat exchanger downstream from the at least one section of the plurality of sections of the heat exchanger have respective temperatures that are configured to provide a positive minimum temperature difference in the at least one section of the heat exchanger of 2° C. to 20° C..

13. The method of claim 1 , wherein the compressor processing the second portion of the substantially pure CO 2 stream has an inlet pressure of 65 bar to 260 bar.

14. A power production system comprising:
a combustor configured to receive a plurality of streams and having an outlet;
a turbine having an inlet in fluid connection with the outlet of the combustor and having an outlet;
a generator configured for production of electrical power and in a power-generating connection with the turbine;
a heat exchanger comprising a first section, a second section, and a last section each section having a plurality of inlets and outlets, each section being configured for operation at different temperature ranges, wherein the first section has an inlet and an outlet in fluid connection with the turbine;
a separator in fluid connection with an outlet from the last section of the heat exchanger and having an outlet for output of a substantially pure CO 2 stream;
a divider configured for dividing the substantially pure CO 2 stream into a first portion and a second portion;
a first pump configured to receive the first portion of the substantially pure CO 2 stream and increase a pressure thereof, the first pump having an outlet in fluid connection with a first inlet of the last section of the heat exchanger;
a second pump configured to receive the second portion of the substantially pure CO 2 stream and increase a pressure thereof, the second pump having an outlet in fluid connection with a second inlet of the last section of the heat exchanger;
a bypass compressor having an inlet in fluid connection with an outlet of the last section of the heat exchanger, the inlet being configured to receive the second portion of the substantially pure CO 2 stream, and having an outlet in fluid connection with an inlet on the first section of the heat exchanger, such that the second portion of the substantially pure CO 2 stream is configured

Assignees

• 8 Rivers Capital Llc

Inventors

• Allam Rodney John

Classifications

• F01K25/103 Primary

  Carbon dioxide (F01K25/065 takes precedence) · CPC title

• F01K23/10

  with exhaust fluid of one cycle heating the fluid in another cycle (F01K17/025 takes precedence) · CPC title

• B01D2257/80

  Water · CPC title

• B01D2257/504

  Carbon dioxide · CPC title

• F02C3/34 Primary

  with recycling of part of the working fluid, i.e. semi-closed cycles with combustion products in the closed part of the cycle · CPC title