Silver nanoparticle-sulfonated polyester composite powders and methods of making the same
US-2017298232-A1 · Oct 19, 2017 · US
US10913820B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10913820-B2 |
| Application number | US-201916249490-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 16, 2019 |
| Priority date | Jul 30, 2018 |
| Publication date | Feb 9, 2021 |
| Grant date | Feb 9, 2021 |
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A process for producing a cationic dyeable polyester includes the steps of: (a) subjecting a combination of a bis-hydroxy alkyl terephthalate monomer of Formula (1) defined herein and an organic diacid monomer mixture which includes an aromatic dicarboxylic acid monomer and a sulfo group-containing aromatic dicarboxylic acid dyeable monomer to an esterification reaction to form an esterification reaction product; and (b) subjecting the esterification reaction product to a polycondensation reaction.
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What is claimed is: 1. A process for producing a cationic dyeable polyester, comprising the steps of: (a) subjecting a combination of a bis-hydroxy alkyl terephthalate monomer of Formula (1) and an organic diacid monomer mixture, which includes an aromatic dicarboxylic acid monomer and a sulfo group-containing aromatic dicarboxylic acid dyeable monomer, to an esterification reaction to form an esterification reaction product, wherein each R 1 independently represents hydrogen, phenyl, a C 1 -C 6 linear alkyl group, or a C 3 -C 6 branched alkyl group; and (b) subjecting the esterification reaction product to a polycondensation reaction. 2. The process according to claim 1 , wherein each R 1 represents hydrogen. 3. The process according to claim 1 , wherein the sulfo group-containing aromatic dicarboxylic acid dyeable monomer is selected from the group consisting of 2-sulfoterephthalic acid monosodium salt, 5-sulfoisophthalic acid monosodium salt, and a combination thereof. 4. The process according to claim 1 , wherein a molar ratio of the bis-hydroxy alkyl terephthalate monomer to the aromatic dicarboxylic acid monomer is in a range from 1.5:1 to 150:1. 5. The process according to claim 1 , wherein a molar ratio of the bis-hydroxy alkyl terephthalate monomer to the sulfo group-containing aromatic dicarboxylic acid dyeable monomer is in a range from 1.3:1 to 100:1. 6. The process according to claim 1 , wherein the aromatic dicarboxylic acid monomer is selected from the group consisting of terephthalic acid, isophthalic acid, phthalic acid, diphenic acid, 2,6-naphthalic acid, 1,5-naphthalic acid, and combinations thereof. 7. The process according to claim 1 , wherein in step (a), the esterification reaction is implemented at a normal pressure. 8. The process according to claim 1 , wherein in step (b), the polycondensation reaction is implemented in the presence of a transition metal-containing polycondensation catalyst. 9. A cationic dyeable polyester produced by the process according to claim 1 . 10. The cationic dyeable polyester according to claim 9 , having an average aggregate radius of up to 2.3 nm.
Antimony or compounds thereof · CPC title
Dicarboxylic acids and dihydroxy compounds · CPC title
using acid dyes · CPC title
from copolyesters · CPC title
Polyesters · CPC title
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