Iron based media

Patent metadata

Field	Value
Publication number	US-10913665-B2
Application number	US-201715726800-A
Country	US
Kind code	B2
Filing date	Oct 6, 2017
Priority date	Oct 6, 2016
Publication date	Feb 9, 2021
Grant date	Feb 9, 2021

Abstract

A filtering medium for removing the content of contaminants in fluids, wherein said filtering medium includes an acid-washed iron-based powder, wherein the acid-washed iron-based powder is formed by washing an iron-based powder in HCl, wherein the BET surface area of the acid-washed iron-based powder is at least 1.2 m2/g, wherein the acid-washed iron-based powder has a Fe content of at least 90% by weight. And, a method for reducing the content of contaminants in fluids including the steps of: a) providing the filtering medium, b) bringing one or more contaminated fluid(s) in contact with the filtering medium to reduce the content of contaminants in said one or more fluid(s), c) optionally removing the filtering medium from the one or more fluid(s) with a reduced content of contaminants.

First claim

The invention claimed is:

1. A filtering medium for reducing the content of contaminants in fluids,
wherein said filtering medium comprises an acid-washed iron-based powder,
wherein the iron-based powder is a hydrogen-reduced powder,
wherein the acid-washed iron-based powder is formed by washing an iron-based powder in hydrochloric acid, drying the iron-based powder, and then cooling the iron-based powder under a protective atmosphere,
wherein the Brunauer-Emmett-Teller (BET) surface area of the acid-washed iron-based powder is 3 to 10 m 2 /g;
wherein the acid-washed iron-based powder has an iron (Fe) content of at least 90% by weight,
wherein the acid-washed iron-based powder has a pH specific Eh (PSE) of less than −0.05 V.

2. The filtering medium of claim 1 , wherein the protective atmosphere is a nitrogen atmosphere.

3. The filtering medium of claim 1 , wherein the average particle size (D50) of the acid-washed iron-based powder is 20 to 10,000 μm.

4. The filtering medium of claim 1 , wherein the average particle size (D50) of the acid-washed iron-based powder is 200 to 590 μm.

5. The filtering medium of claim 1 , wherein the average particle size (D50) of the acid-washed iron-based powder is less than 200 μm.

6. The filtering medium of claim 1 , wherein the apparent density of the acid-washed iron-based powder is 0.5 to 5 g/cm3.

7. The filtering medium of claim 1 , wherein the acid-washed iron-based powder has a localized chlorine concentration on the surface of at least 3% by X Energy Dispersive X-ray (EDX) spectral analysis.

8. A filtering medium for reducing the content of contaminants in fluids,
wherein said filtering medium comprises an acid-washed iron-based powder,
wherein the iron-based powder is a hydrogen-reduced iron powder,
wherein the acid-washed iron-based powder has a localized chlorine concentration on the surface of at least 3% by Energy Dispersive X-ray (EDX) spectral analysis,
wherein the Brunauer-Emmett-Teller (BET) surface area of the iron-based powder is 3-10 m 2 /g,
wherein the acid-washed iron-based powder has an iron (Fe) content of at least 90% by weight,
wherein the acid-washed iron-based powder has a pH specific Eh of (PSE) less than −0.05 V.

9. The filtering medium of claim 8 , wherein the average particle size (D50) of the iron-based powder is 20 to 10,000 μm.

10. The filtering medium of claim 1 , wherein the average particle size (D50) of the acid-washed iron-based powder is 200 to 590 μm.

11. The filtering medium of claim 1 , wherein the average particle size (D50) of the acid-washed iron-based powder is less than 200 μm.

12. The filtering medium of claim 1 , wherein the apparent density of the acid-washed iron-based powder is 0.5 to 5 g/cm 3 .

13. The filtering medium of claim 8 , wherein the iron-based powder having has an average particle size (D50) between 40 and 590 μm.

14. The filtering medium of claim 8 , wherein the acid-washed iron-based powder is formed by washing an iron-based powder in hydrochloric acid.

15. The filtering medium of claim 14 , wherein the acid washing comprises hydrochloric acid washing, drying, and cooling process in a protective atmosphere.

16. A method for reducing the content of contaminants in fluids comprising the steps of:
a) providing a filtering medium according to claim 1 ,
b) bringing one or more contaminated fluid(s) in contact with the filtering medium to reduce the content of contaminants in said one or more fluid(s),
c) optionally removing the filtering medium from the one or more fluid(s) with a reduced content of contaminants.

17. The method according to claim 16 , wherein in step b) one or more contaminated fluid(s) is/are allowed to pass through the filtering medium in an up or downflow direction.

18. The method according to claim 16 , wherein said fluid(s) is/are contaminated by at least one of chlorinated volatile organic compounds (VOC), radionuclides, and heavy metals.

19. The method according to claim 18 , wherein the chlorinated VOC is chosen from the group consisting of trichloroethylene (TCE), tetrachloroethylene (PCE), and their daughter products.

20. A method for producing a filtering medium, wherein the filtering medium is according to claim 1 , the method comprising the steps of:
hydrochloric acid washing
drying and cooling process, optionally in a protective nitrogen atmosphere.

Assignees

• Hoeganaes Ab Publ

Inventors

• Chang Hyunshik
• Tandukar Madan
• Endler Paul

Classifications

• C02F1/705

  Reduction by metals · CPC title

• C02F1/66

  by neutralisation; pH adjustment (for degassing C02F1/20; using ion-exchange C02F1/42; for flocculation or precipitation of suspended impurities C02F1/52; for removing dissolved compounds C02F1/58) · CPC title

• C02F1/281 Primary

  using inorganic sorbents · CPC title

• B22F9/22

  using gaseous reductors · CPC title

• B09C1/08

  chemically · CPC title