Method for preparing functionalized carbon materials

Patent metadata

Field	Value
Publication number	US-10913657-B2
Application number	US-201916246120-A
Country	US
Kind code	B2
Filing date	Jan 11, 2019
Priority date	Aug 12, 2016
Publication date	Feb 9, 2021
Grant date	Feb 9, 2021

Abstract

The present invention belongs to the field of new materials technology and discloses a green method for preparing functionalized carbon materials. The present invention can use potassium ferrate(VI) as an oxidant and mechanical milling as a reaction technique for oxidizing carbon materials in a preparation of functionalized carbon materials having oxygen-containing functional groups. Compared with the prior art, the present invention provides a method that combines an environmentally friendly oxidant with an environmentally friendly reaction process. The oxidant potassium ferrate(VI) is a green oxidant without producing any toxic byproducts. The reaction process is solvent-free, facilitated by milling the solid mixture of carbon materials and the oxidant. Thus, the present invention provides an environmentally friendly method for preparing oxidatively functionalized carbon materials, which is of promotion value.

First claim

What is claimed is:

1. A method for preparing a functionalized carbon material, comprising milling a carbon material and potassium ferrate(VI) to oxidize the carbon material to produce an oxidized carbon material,
wherein the carbon material includes carbon nanotubes,
the carbon nanotubes include one or more selected from the group consisting of multiwalled carbon nanotubes, double-walled carbon nanotubes, and single-walled carbon nanotubes,
the functionalized carbon material has oxygen-containing groups on a surface thereof,
oxidation between the carbon material and potassium ferrate(VI) does not need any solvent, and
the mass ratio of the carbon material to potassium ferrate(VI) is 1:5-50.

2. The method according to claim 1 , wherein the method further includes performing a post treatment of the oxidized carbon material.

3. The method according to claim 1 , wherein the milling is a manual milling or a machine milling, the manual milling is performed with a manual milling or grinding or dispersing device, and the machine milling is performed with a machine milling or grinding or dispersing device.

4. The method according to claim 3 , wherein the manual milling or grinding or dispersing device includes at least one selected from the group consisting of a mortar and a pestle, and the machine milling or grinding or dispersing device includes planetary ball mill machine, vibration ball mill machine, stirring dispersing machine, or grinder.

Assignees

• Univ Shanghai Jiaotong

Inventors

• Li Tao
• Zhang Zhaoyang
• Zhou Ying

Classifications

• C01B32/156

  After-treatment · CPC title

• C01B32/00

  Carbon; Compounds thereof (C01B21/00, C01B23/00 take precedence; percarbonates C01B15/10; carbon black C09C1/48) · CPC title

• C01B32/194

  After-treatment · CPC title

• C01P2004/133

  Multiwall nanotubes · CPC title

• C01B2202/02

  Single-walled nanotubes · CPC title