Porous microsphere and method for preparing the same

Patent metadata

Field	Value
Publication number	US-10913045-B2
Application number	US-201816129791-A
Country	US
Kind code	B2
Filing date	Sep 12, 2018
Priority date	Jun 7, 2018
Publication date	Feb 9, 2021
Grant date	Feb 9, 2021

Abstract

A porous microsphere and a method for preparing the same includes the following steps. A copolymer having a vinylbenzyl chloride unit and a vinylbenzyl alcohol unit is dissolved in an organic solvent, and inorganic particles are dispersed in the organic solvent to form a mixed suspension. An aqueous solution containing a surfactant is provided. The mixed suspension is emulsified in the aqueous solution to form an emulsion. The emulsion is heated to evaporate the organic solvent to obtain inorganic-composite porous microspheres suspended in water. The copolymer in the formed porous microspheres can be further carbonized or removed to produce inorganic-based porous microspheres containing carbon or not containing carbon.

First claim

What is claimed is:

1. A method for preparing a porous microsphere, comprising:
dissolving a copolymer in an organic solvent and dispersing inorganic particles in the organic solvent to form a mixed suspension;
providing an aqueous solution containing a surfactant;
emulsifying the mixed suspension in the aqueous solution to obtain an emulsion; and
heating the emulsion to remove the organic solvent from the emulsion and obtain inorganic-composite porous microspheres,
wherein a number-average molecular weight of the copolymer is less than 120,000 g/mol and the copolymer has a chemical structure shown in formula (1) or (2) below:

in formula (1),
m>0, 8%≤p≤80%, y≥0, and z≥0,
X is selected from chlorine, bromine and iodine, and
R is selected from hydrogen, chlorine, bromine, —C n H 2n+1 , —CH 2 NH 2 , —CH 2 C(═O)OC i H 2i+1 , —CH 2 OC(═O)C n H 2n+1 , —NH 2 , —N(C i H 2i+1 )C(═O)C n H 2n+1 , —C(═O)OC i H 2i+1 , —OC(═O)C n H 2n+1 , —SO 3 M (M is selected from hydrogen, sodium, potassium and NH 4 ) and Si(OC n H 2n+1 ) 3 , R′ is selected from hydrogen, carboxyl and —C n H 2n+1 , and R″ is selected from hydrogen, —C(═O)OC j H 2j+1 , —OC(═O)C k H 2k+1 , —C≡N, —Si(OC n H 2n+1 ) 3 , —NH 2 , —N(C i H 2i+1 )C(═O)C n H 2n+1 , pyrrolidonyl and pyridinyl, wherein n=1 to 4, i=0 to 4, j=1 to 12, and k=1 to 17;

in formula (2),
m>0, 8%≤p≤80%, t>0, u≥0, and z≥0,
X is selected from chlorine, bromine and iodine, and
R is selected from hydrogen, chlorine, bromine, —C n H 2n+1 , —CH 2 NH 2 , —CH 2 C(═O)OC i H 2i+1 , —CH 2 OC(═O)C n H 2n+1 , —NH 2 , —N(C i H 2i+1 )C(═O)C n H 2n+1 , —C(═O)OC i H 2i+1 , —OC(═O)C n H 2n+1 , —SO 3 M (M is selected from hydrogen, sodium, potassium and NH 4 ) and Si(OC n H 2n+1 ) 3 , R′ is selected from hydrogen, carboxyl and —C n H 2n+1 , R″ is selected from hydrogen, —C(═O)OC j H 2j+1 , —OC(═O)C k H 2k+1 , —C≡N, —Si(OC n H 2n+1 ) 3 , —NH 2 , —N(C i H 2i+1 )C(═O)C n H 2n+1 , pyrrolidonyl and pyridinyl, and R′″ is —C n H 2n+1 , wherein n=1 to 4, i=0 to 4, j=1 to 12, and k=1 to 17.

2. The method of claim 1 , further comprising: immersing the obtained inorganic-composite porous microspheres in the organic solvent, and/or adjusting a relative amount of the inorganic powder, the surfactant and the solvent to adjust a pore size of the inorganic-composite porous microspheres.

3. The method of claim 2 , wherein the inorganic particles comprise at least one kind of particles selected from the group consisting of titanium dioxide particles, silicon dioxide particles, magnetic substance particles, hydroxyapatite particles, heat-resistant substance particles, noble metal particles, and electrode active substance particles.

4. The method for preparing the porous microsphere of claim 2 , further comprising: carbonizing the copolymer or removing the copolymer.

5. The method of claim 1 , wherein the inorganic particles comprise at least one kind of particles selected from the group consisting of titanium dioxide particles, silicon dioxide particles, magnetic substance particles, hydroxyapatite particles, heat-resistant substance particles, noble metal particles, and electrode active substance particles.

6. The method for preparing the porous microsphere of claim 1 , further comprising: carbonizing the copolymer or removing the copolymer.

Assignees

• Univ Nat Taipei Technology

Inventors

• Li Chia-Chen
• Jhang Jia-Hao

Classifications

• B01J13/125 Primary

  by evaporation of the solvent (apparatus therefor B01J13/043) · CPC title

• C08K7/18 Primary

  inorganic · CPC title

• Y02E10/549

  Organic PV cells · CPC title

• C08K3/22

  of metals · CPC title

• C08K2003/2241

  Titanium dioxide · CPC title