Fixed bed radial flow reactor for light paraffin conversion

Patent metadata

Field	Value
Publication number	US-10913042-B2
Application number	US-201816214846-A
Country	US
Kind code	B2
Filing date	Dec 10, 2018
Priority date	Feb 16, 2017
Publication date	Feb 9, 2021
Grant date	Feb 9, 2021

Abstract

Systems and methods are provided for conversion of light paraffinic gases to form liquid products in a process performed in a fixed bed radial-flow reactor. The light paraffins can correspond to C3+ paraffins. Examples of liquid products that can be formed include C6-C12 aromatics, such as benzene, toluene, and xylene. The fixed bed radial-flow reactor can allow for improved control over the reaction conditions for paraffin conversion in spite of the fixed bed nature of the reactor. This can allow the process to operate with improved efficiency while reducing or minimizing the complexity of operation relative to non-fixed bed reactor systems.

First claim

The invention claimed is:

1. A method for processing a paraffin-containing feed, comprising:
exposing a feed comprising about 30 vol % to about 70 vol % of C 3 -C 4 paraffins to one or more fixed beds of a conversion catalyst to form a conversion effluent comprising C 6 -C 12 aromatics, the one or more fixed beds of the conversion catalyst comprising fixed beds in one or more radial flow reactors, a combined pressure drop across the one or more fixed beds being less than about 100 kPag, the one or more radial flow reactors comprising:
an outer annular volume defined by an interior of a reactor wall and an exterior of a gas-permeable wall, the interior of the reactor wall defining an outer annular radius R 1 ;
a central volume defined by the interior of a central column and a column cap, the interior of the central column defining a column radius R 3 ; and
an inner annular volume defined by an interior of the gas-permeable wall, an exterior of the central column, an inner annular top, and an inner annular bottom, the interior of the gas-permeable wall defining an inner annular radius R 2 , the inner annular volume comprising a catalyst bed, the inner annular volume being in direct fluid communication with the outer annular volume through the gas-permeable wall, the inner annular volume being in direct fluid communication with the central volume through the central column,
wherein the conversion catalyst comprises catalyst particles comprising an equivalent particle diameter d P,e ,
wherein the outer annular radius R 1 , inner annular radius R 2 , and the equivalent particle diameter d P,e satisfy the relationship
C*d P,e ≤R 1− R 2≤ D*d P,e

where C is at least 30 and D is 300 or less, and
wherein the inner annular radius R 2 , the column radius R 3 , and the equivalent particle diameter d P,e satisfy the relationship
A*d P,e ≤R 2− R 3≤ B*d P,e

where A is at least 100 and B is 600 or less.

2. The method of claim 1 , wherein the feed is exposed to the conversion catalyst at a temperature of about 450° C. to about 650° C., a pressure in the one or more fixed catalyst beds comprising at least about 200 kPa-a, and a WHSV of about 0.1 hr −1 to about 4.0 hr −1 .

3. The method of claim 1 , the method further comprising heating at least a portion of the feed after exposure of the feed to a first catalyst bed of the one or more catalyst beds and prior to exposure of the feed to a second catalyst bed of the one or more catalyst beds.

4. The method of claim 1 , wherein a temperature drop across a first catalyst bed of the one or more catalyst beds is about 125° C. or less.

5. The method of claim 1 , further comprising:
separating C 3 -C 4 paraffins from a natural gas feedstock to form at least a fraction comprising C 3 -C 4 paraffins;
mixing at least a portion of the fraction separated C 3 -C 4 paraffins with a gas comprising methane, ethane, or a combination thereof to form an enriched feedstock,
wherein exposing the feed comprising about 30 vol % to about 70 vol % of C 3 -C 4 paraffins to one or more fixed beds of conversion catalyst comprises exposing at least a portion of the enriched feedstock to the one or more fixed beds of conversion catalyst.

6. The method of claim 5 , wherein the gas comprising methane, ethane, or a combination thereof comprises a portion of the natural gas feedstock, a fraction separated from the natural gas feedstock, or a combination thereof.

7. The method of claim 1 , further comprising separating the conversion effluent to form a fraction comprising C 6 -C 12 aromatics or C 6 -C 9 aromatics, and combining at least a portion of the fraction comprising C 6 -C 12 aromatics with a hydrocarbon liquid.

8. The method of claim 1 , wherein A is at least 300, or wherein B is 400 or less, or a combination thereof, or wherein C is at least 50, or wherein D is less than 150, or a combination of any two or more thereof, or a combination of all thereof.

9. The method of claim 1 , wherein the equivalent particle diameter is about 0.2 cm to about 4.0 cm.

10. The method of claim 1 , wherein the catalyst particles comprise ZSM-5, ZSM-11, ZSM-12, ZSM-22, ZSM-23, ZSM-35, ZSM-48, MCM-22, MCM-49, or a combination thereof.

11. The method of claim 1 , wherein the catalyst particles comprise 0.1 wt % to 5.0 wt % of a metal from Groups 3-13 of the periodic table relative to a weight of the catalyst particles.

12. The method of claim 11 , wherein the metal comprises Ga, In, or a combination thereof.

Assignees

• Exxonmobil Res & Eng Co

Inventors

• Behkish Arsam
• Maher David W
• Keusenkothen Paul F
• Valencia Jaime A

Classifications

• C07C2529/40

  of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 · CPC title

• C07C2/76

  by condensation of hydrocarbons with partial elimination of hydrogen · CPC title

• B01J2219/00038

  Processes in parallel · CPC title

• B01J2208/02

  with stationary particles · CPC title

• B01J2208/00884

  Means for supporting the bed of particles, e.g. grids, bars, perforated plates · CPC title