Multimodal polyethylene screw cap

Patent metadata

Field	Value
Publication number	US-10913041-B2
Application number	US-201716332066-A
Country	US
Kind code	B2
Filing date	Sep 8, 2017
Priority date	Sep 12, 2016
Publication date	Feb 9, 2021
Grant date	Feb 9, 2021

Abstract

The present invention relates to a multimodal polyethylene composition comprising: (A) 35 to 65 parts by weight, preferably 45 to 65 parts by weight, most preferred 50 to 60 parts by weight, of the low molecular weight polyethylene having a weight average molecular weight (Mw) of 20,000 to 90,000 g/mol; (B) 5 to 40 parts by weight, preferably 5 to 30 parts by weight, most preferred 5 to 20 parts by weight, of the first high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000 g/mol or the first ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000 g/mol; and (C) 20 to 60 parts by weight, preferably 25 to 60 parts by weight, most preferred 35 to 55 parts by weight, of the second high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000 g/mol or the second ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000 g/mol, wherein the molecular weight distribution of the multimodal polyethylene composition is from 10 to 25, preferably 10 to 20, determined by Gel Permeation Chromatography; the isothermal crystallization half-time of the multimodal polyethylene composition at a temperature of 123° C. is 7 min or less, preferably 6 min or less, preferably 2-6 min, according to Differential Scanning Calorimetry; and a spiral flow length at a temperature of 220° C. is at least 200 mm, preferably 250-400 mm and a screw cap comprising the same.

First claim

The invention claimed is:

1. A multimodal polyethylene composition comprising;
(A) 35 to 65 parts by weight of a low molecular weight polyethylene having a weight average molecular weight (Mw) of 20,000 to 90,000 g/mol;
(B) 5 to 40 parts by weight of a first high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000 g/mol or a first ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000 g/mol; and
(C) 20 to 60 parts by weight of a second high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000 g/mol or a second ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000 g/mol,
wherein the molecular weight distribution of the multimodal polyethylene composition is from 10 to 25, determined by Gel Permeation Chromatography;
the isothermal crystallization half-time of the multimodal polyethylene composition at a temperature of 123° C. is 7 min or less, according to Differential Scanning Calorimetry;
a spiral flow length at a temperature of 220° C. is at least 200 mm, and
wherein (A), (B), and (C) each have a different weight average molecular weight.

2. The multimodal polyethylene composition according to claim 1 , wherein the molecular weight distribution is from 15 to 25.

3. The multimodal polyethylene composition according to claim 1 , wherein the spiral flow length at a temperature of 220° C. is from 250 to 370 mm.

4. The multimodal polyethylene composition according to claim 1 , wherein the multimodal polyethylene composition has an average molecular weight from 80,000 to 250,000 g/mol, measured by Gel Permeation Chromatography.

5. The multimodal polyethylene composition according to claim 1 , wherein the multimodal polyethylene composition has a number average molecular weight from 5,000 to 30,000 g/mol, measured by Gel Permeation Chromatography.

6. The multimodal polyethylene composition according to claim 1 , wherein the multimodal polyethylene composition has a Z average molecular weight from 700,000 to 2,500,000 g/mol, measured by Gel Permeation Chromatography.

7. The multimodal polyethylene composition according to claim 1 , wherein the multimodal polyethylene composition has a density 0.950 to 0.965 g/cm3, according to ASTM D 1505 and/or MI 2 from 0.1 to 20 g/10 min, according to ASTM D 1238.

8. Screw cap comprising the multimodal polyethylene composition according to claim 1 .

9. Screw cap according to claim 8 obtainable by injection molding or compression molding.

10. The multimodal polyethylene composition of claim 1 , comprising 45 to 65 parts by weight of the low molecular weight polyethylene.

11. The multimodal polyethylene composition of claim 1 , comprising 5 to 30 parts by weight of the first high molecular weight polyethylene.

12. The multimodal polyethylene composition of claim 1 , comprising 25 to 60 parts by weight of the second high molecular weight polyethylene.

13. The multimodal polyethylene composition of claim 1 , wherein the molecular weight distribution of the multimodal polyethylene composition is from 10 to 20, determined by Gel Permeation Chromatography.

14. The multimodal polyethylene composition of claim 1 , wherein the molecular weight distribution of the multimodal polyethylene composition is from 10 to 20, determined by Gel Permeation Chromatography.

15. The multimodal polyethylene composition of claim 1 , wherein the isothermal crystallization half-time at a temperature of 123° C. is 6 min or less.

16. The multimodal polyethylene composition of claim 1 , wherein the spiral flow length at a temperature of 220° C. is 250-400 mm.

17. The multimodal polyethylene composition of claim 4 , wherein the average molecular weight is from 80,000 to 200,000 g/mol, measured by Gel Permeation Chromatography.

18. The multimodal polyethylene composition of claim 5 , wherein the number average molecular weight is from 5,000 to 20,000 g/mol, measured by Gel Permeation Chromatography.

19. The multimodal polyethylene composition of claim 6 , wherein the Z average molecular weight is from 700,000 to 2,000,000 g/mol, measured by Gel Permeation Chromatography.

20. The multimodal polyethylene composition of claim 7 , wherein the density is 0.953 to 0.960 g/cm3 according to ASTM D 1505 and/or MI 2 is from 0.3 to 17 g/10 min, according to ASTM D 1238.

Assignees

• Thai Polyethylene Co Ltd
• Scg Chemicals Co Ltd

Inventors

• Traisilanun Saranya
• Cheevasrirungruang Watcharee
• Klomkamol Warachad

Classifications

• C08L23/06 Primary

  Polyethylene · CPC title

• C08L23/04

  Homopolymers or copolymers of ethene · CPC title

• C08F2/00 Primary

  Processes of polymerisation · CPC title

• B65D41/04

  Threaded or like caps or cap-like covers secured by rotation · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title