3D polymer nanofiber membrane composed of 1D individual polymer nanofibers which are quasi-aligned and cross-laminated like grid structure with functions of controlling pore distribution and size, and manufacturing method thereof

Patent metadata

Field	Value
Publication number	US-10913032-B2
Application number	US-201715648807-A
Country	US
Kind code	B2
Filing date	Jul 13, 2017
Priority date	Jul 15, 2016
Publication date	Feb 9, 2021
Grant date	Feb 9, 2021

Abstract

Disclosed is a 1D nanofibers quasi-aligned, grid structure cross-laminated, and pore distribution and size controlled 3D polymer nanofiber membrane, and manufacturing method thereof. A 3D polymer nanofiber membrane controlled in pore size and porosity is formed by employing an electrospinning pattern forming apparatus that includes double insulating blocks quasi-aligns nanofibers in a specific direction by transforming an electric field and includes a current collector rotatable in 90°. Additionally, the 3D polymer nanofiber membrane may be used for air filters, separator, water filters, cell culture membranes, and so on by allowing various properties thereto through a functional surface coating.

First claim

What is claimed is:

1. A polymer nanofiber membrane comprising:
quasi-aligned and cross-laminated individual polymer nanofibers in a grid structure with controlled pore distribution and size, the grid structure having a first direction orthogonal to a second direction, a first portion of the individual polymer nanofibers being generally oriented in the first direction wherein 1) at least 80% of the first portion of the individual polymer nanofibers are oriented within 10° of the first direction, and 2) the first portion of individual polymer nanofibers includes individual polymer nanofibers that are not parallel to the first direction.

2. The polymer nanofiber membrane of claim 1 , wherein the diameter of the individual polymer nanofibers is from 50 nm to 5 μm.

3. The polymer nanofiber membrane of claim 1 , wherein the lamination thicknesses of the individual polymer nanofibers is from 5 to 200 μm.

4. The polymer nanofiber membrane of claim 1 , a second portion of the individual polymer nanofibers being generally oriented in the second direction wherein 1) at least 80% of the second portion of the individual polymer nanofibers are oriented within 10° of the second direction, and 2) the second portion of individual polymer nanofibers including individual polymer nanofibers that are not parallel to the second direction.

5. The polymer nanofiber membrane of claim 1 , wherein the pores have an average diameter from 10 nm to 10 μm.

6. The polymer nanofiber membrane of claim 1 , wherein the porosity of the polymer nanofiber membrane is from 50 to 90%.

7. The polymer nanofiber membrane of claim 1 , wherein the area of the polymer nanofiber membrane is from 1 cm 2 to 1 m 2 .

8. The polymer nanofiber membrane of to claim 1 and forming at least one of an air filter, a separator, a water filter, and a cell culture filter.

9. A polymer nanofiber membrane comprising individual polymer nanofibers that are cross-laminated in a grid structure having a first direction orthogonal to a second direction, a first portion of the individual polymer nanofibers being generally oriented in the first direction wherein 1) at least 80% of the first portion of the individual polymer nanofibers are oriented within 10° of the first direction, and 2) the first portion of individual polymer nanofibers includes individual polymer nanofibers that are not parallel to the first direction, the polymer nanofiber membrane being manufactured by an electrospinning pattern forming apparatus comprising a high voltage generator, a conductive current collector, a polymer solution injection nozzle connected to a metering pump, and a plurality of insulating blocks.

10. The polymer nanofiber membrane of claim 9 , wherein the high voltage generator is configured to apply a voltage between 1 kV and 30 kV, and
wherein the metering pump is configured to discharge a polymer solution at a rate between 5 μl/minute and 200 μl/minute.

11. The polymer nanofiber membrane of claim 9 , wherein the plurality of insulating blocks comprise one or a mixture with two or more among a Styrofoam material, a Teflon material, a wooden material, a plastic material, a glass material, a quartz material, a silicon oxide material, and a metallic material, and has a relative permittivity equal to or lower than 50.

12. The polymer nanofiber membrane of claim 9 , wherein the plurality of insulating blocks each have a width and a length from 3 to 8 cm and a height from 2 to 5 cm, and an interval between two of the plurality of insulating blocks has a distance from 1 to 6 cm.

13. The polymer nanofiber membrane of claim 9 , wherein an interval between top surfaces of the plurality of insulating blocks and a tip of the injection nozzle is from 2 to 5 cm, and an interval between bottom surfaces of the double insulating blocks and the conductive current collector is ranged from 2 to 5 cm.

14. The polymer nanofiber membrane of claim 9 , wherein, in the electrospinning pattern forming apparatus, the nanofibers are discharged and aligned in one direction by the plurality of insulating blocks, and a grid-structured membrane is formed by movement and rotation of the conductive current collector relative to the plurality of insulating blocks.

15. A polymer nanofiber membrane comprising individual polymer nanofibers that are cross-laminated in a grid structure, the grid structure having a first direction orthogonal to a second direction, wherein at least a portion of the individual polymer nanofibers are generally oriented in the first direction and are not parallel to the first direction, the polymer nanofiber membrane being prepared by a process comprising:
discharging and electrospinning the individual polymer nanofibers into a space adjacent to a plurality of insulating blocks;
collecting the discharged individual polymer nanofibers at a conductive current collector to form a first layer of the individual polymer nanofibers in the first direction; and
collecting the discharged individual polymer nanofibers at the conductive current collector to form a second layer of the individual polymer nanofibers in the second direction.

16. The polymer nanofiber membrane of claim 15 , wherein at least 80% of the individual polymer nanofibers in the first direction are oriented within 10° of the first direction.

17. The polymer nanofiber membrane of claim 15 , wherein the process by which the membrane is prepared further comprises rotating the conductive current collector relative to the plurality of insulating blocks prior to collecting the discharged polymer nanofibers at the conductive current collector to form the second layer.

18. The polymer nanofiber membrane of claim 15 , wherein discharging and electrospinning the individual polymer nanofibers includes discharging a solution comprising a polymer, the solution being 5-15% polymer by weight.

19. The polymer nanofiber membrane of claim 15 , wherein the polymer nanofiber membrane has a nanofiber lamination thickness between 5 and 200 μm.

20. The polymer nanofiber membrane of claim 15 , wherein discharging and electrospinning the individual polymer nanofibers includes discharging a polymer solution through at least one injection nozzle connected to a terminal of a high voltage generator.

21. The polymer nanofiber membrane of claim 15 , wherein the process further comprises, during collection of the discharged individual polymer nanofibers, controlling a moving speed of the conductive current collector at a speed between 1 mm/s and 50 mm/s and controlling a moving distance of the conductive current collector between 1 cm and 20 cm.

22. The polymer nanofiber membrane of claim 15 , wherein the process further comprises coating a surface of the polymer nanofiber membrane with a layer of at least one of a polymer, a ceramic material, a metal, and a metal oxide, the layer providing at least one of hydrophilicity, hydrophobicity, oxidation resistivity, thermal resistivity, and chemical resistivity to the polymer nanofiber membrane.

Assignees

• Korea Advanced Inst Sci & Tech

Inventors

• Kim Il-Doo
• Kim Chanhoon
• Cho Su Ho
• Hwang Won Tae

Classifications

• B01D67/00042 Primary

  by deposition of fibres, nanofibres or nanofibrils · CPC title

• B01D71/262

  Polypropylene · CPC title

• B01D71/5211

  Polyethylene glycol or polyethyleneoxide · CPC title

• B01D71/261

  Polyethylene · CPC title

• B01D71/421

  Polyacrylonitrile · CPC title