Polarizing film, method for producing same, optical film, and image display device

Patent metadata

Field	Value
Publication number	US-10901129-B2
Application number	US-201716094303-A
Country	US
Kind code	B2
Filing date	Mar 6, 2017
Priority date	Apr 20, 2016
Publication date	Jan 26, 2021
Grant date	Jan 26, 2021

Abstract

A polarizing film, wherein transparent protective films are laid, respectively, on/over both surfaces of a polarizer to interpose an adhesive layer (a) and an adhesive layer (b), respectively, between both the surfaces and the transparent protective films. The adhesive layer (a) has a glass transition temperature of −60° C. or higher and lower than 40° C. The adhesive layer (b) has a glass transition temperature of 40° C. or higher. The adhesive layer (a) is a layer formed in the form of a cured product layer yielded by radiating an active energy ray to an active-energy-ray-curable adhesive composition (a). The active-energy-ray-curable adhesive composition (a) comprises at least one or more radical polymerizable compounds, and when a total amount of the radical polymerizable compound(s) is defined as 100% by weight, one or more alkyl (meth)acrylates (A) (each) having 10 to 20 carbon atoms are comprised in a proportion of 15% or more by weight.

First claim

The invention claimed is:

1. A polarizing film, comprising:
a polarizer,
a first transparent protective film laid on/over a first surface of the polarizer to interpose an adhesive layer (a) between the first surface and the first transparent protective film, and films;
a second transparent protective film laid on/over a second surface of the polarizer to interpose an adhesive layer (b) between the second surface and the second transparent protective film;
wherein the adhesive layer (a) on/over the first surface has a glass transition temperature of −60° C. or higher and lower than 40° C.;
wherein the adhesive layer (b) on/over the second ether surface has a glass transition temperature of 40° C. or higher and 300° C. or lower;
wherein a difference in the glass transition temperature of the adhesive layer (a) and the glass transition temperature of the adhesive layer (b) is 60° C. or more;
wherein the adhesive layer (a) is a layer formed in the form of a cured product layer yielded by radiating an active energy ray to an active-energy-ray-curable adhesive composition (a); and
wherein the active-energy-ray-curable adhesive composition (a) comprises at least one or more radical polymerizable compounds, and when a total amount of the radical polymerizable compound(s) is defined as 100% by weight, one or more alkyl (meth)acrylates (A) each having 10 to 20 carbon atoms are comprised in a proportion of 15% or more by weight.

2. The polarizing film according to claim 1 , wherein the active-energy-ray-curable adhesive composition (a) comprises, as the alkyl (meth)acrylate(s) (A), an alkyl (meth)acrylate (A1) having 10 to 14 carbon atoms, and an alkyl (meth)acrylate (A2) having 15 to 20 carbon atoms.

3. The polarizing film according to claim 2 , wherein in the active-energy-ray-curable adhesive composition (a), a ratio by weight of the component (A1) to the component (A2) (A1/A2) is from 1.0/9.0 to 4.0/6.0.

4. The polarizing film according to claim 1 , comprising the following in an amount of 3% or more by weight at the time of defining the total amount of the radical polymerizable compound(s) as 100% by weight: one or more nitrogen-containing monomers (B) selected from the group consisting of (meth)acrylamide derivatives, amino-group-containing monomers, and nitrogen-containing and heterocycle-containing vinyl monomers.

5. The polarizing film according to claim 1 , wherein the active-energy-ray-curable adhesive composition (a) further comprises a polyfunctional radical polymerizable compound.

6. The polarizing film according to claim 5 , wherein in the active-energy-ray-curable adhesive composition (a), the polyfunctional radical polymerizable compound is an alkylene di(meth)acrylate having 7 to 12 carbon atoms.

7. The polarizing film according to claim 1 , wherein the active-energy-ray-curable adhesive composition (a) further comprises an acrylic oligomer obtained by polymerizing a (meth)acrylic monomer.

8. The polarizing film according to claim 1 , wherein the active-energy-ray-curable adhesive composition (a) comprises a radical polymerizable compound having a hydroxyl group.

9. The polarizing film according to claim 1 , wherein the active-energy-ray-curable adhesive composition (a) further comprises a silane coupling agent.

10. The polarizing film according to claim 9 , wherein in the active-energy-ray-curable adhesive composition (a), the silane coupling agent is a silane coupling agent having no radical polymerizable functional group.

11. The polarizing film according to claim 1 , wherein the active-energy-ray-curable adhesive composition (a) comprises a radical polymerizable compound having an active methylene group, and a radical polymerization initiator having hydrogen-withdrawing effect.

12. The polarizing film according to claim 11 , wherein in the active-energy-ray-curable adhesive composition (a), the active methylene group is an acetoacetyl group.

13. The polarizing film according to claim 11 , wherein in the active-energy-ray-curable adhesive composition (a), the radical polymerizable compound having the active methylene group is acetoacethoxyalkyl (meth)acrylate.

14. The polarizing film according to claim 11 , wherein in the active-energy-ray-curable adhesive composition (a), the radical polymerization initiator is a thioxanthone based radical polymerization initiator.

15. A method for producing the polarizing film recited in claim 1 , comprising:
a first painting step of painting an adhesive composition (b) for forming the adhesive layer (b) to at least the second surface of the polarizer and the second transparent protective film,
a first bonding step of bonding the polarizer and the second transparent protective film to each other,
a first adhering step of causing the polarizer and the second transparent protective film to adhere to each other through the adhesive layer (b) yielded by curing the adhesive composition (b),
a second painting step of painting an active-energy-ray-curable adhesive composition (a) for forming the adhesive layer (a) to at least the first surface of the polarizer and the first transparent protective film,
a second bonding step of bonding the polarizer and the first transparent protective film to each other, and
a second adhering step of radiating the active energy ray to the resultant workpiece to cure the active-energy-ray-curable adhesive composition (a) to yield the adhesive layer (a), and causing the polarizer and the first transparent protective film to adhere to each other through the yielded adhesive layer (a).

16. The method for producing the polarizing film according to claim 15 , wherein the active energy ray shows a ratio of 100:0 to 100:50, this ratio being a ratio between an integrated illuminance of rays in a wavelength range from 380 to 440 nm and an integrated illuminance of rays in a wavelength range from 250 to 370 nm.

17. A method for producing the polarizing film recited in claim 1 , comprising:
a painting step of painting an active-energy-ray-curable adhesive composition (b) for forming the adhesive layer (b) to at least the second surface of the polarizer and the second transparent protective film,
another painting step of painting an active-energy-ray-curable adhesive composition (a) for forming the adhesive layer (a) to at least the first surface of the polarizer and the first transparent protective film,
a bonding step of bonding the polarizer to the first and second transparent protective films, and
an adhering step of radiating the active energy ray to the resultant workpiece to cure the active-energy-ray-curable adhesive compositions (a) and (b) to yield the adhesive layer (a) and the adhesive layer (b), and causing the first and second transparent protective films to adhere to the polarizer through the yielded adhesive layer (a) and the yielded adhesive layer (b), respectively.

18. An optical film, comprising at least one polarizing film as recited in claim 1 .

19. An image display device, comprising a polarizing film as recited in claim 1 .

Assignees

• Nitto Denko Corp

Inventors

• Okamoto Masayuki
• Mita Satoshi
• Konno Yoshimi
• Jiang Taiyan
• Ikeda Tetsuro

Classifications

• B29D11/00644 Primary

  polarizing · CPC title

• G02B5/3025 Primary

  Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state (G02B5/3008, G02B5/3016 take precedence) · CPC title

• C09J4/00

  Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond {; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16} · CPC title

• G02F1/1335

  Structural association of cells with optical devices, e.g. polarisers or reflectors · CPC title

• G02B5/30 Primary

  Polarising elements (light-modulating devices with active elements G02F1/00) · CPC title