Method and intermediate for the production of highly refined or microfibrillated cellulose

Patent metadata

Field	Value
Publication number	US-10900169-B2
Application number	US-201314421708-A
Country	US
Kind code	B2
Filing date	Aug 16, 2013
Priority date	Aug 20, 2012
Publication date	Jan 26, 2021
Grant date	Jan 26, 2021

Abstract

A method for the production of highly refined or microfibrillated cellulose (MFC), comprising the steps of treating cellulosic fibres to remove at least a major part of the primary wall of the fibres, drying the treated fibres, rewetting the treated fibres, and disintegrating the wetted fibres by mechanical means to obtain the final product. Dried cellulosic pulp is produced as an intermediate product of the method, having an average fibre length of at least 0.4 mm, while less than 50% of the primary wall material of natural untreated fibres is left in the intermediate product. Instead of transporting large amounts of dilute MFC dispersion the invention enables transport of the dry intermediate product to the MFC end user, who would complete the process by turning the intermediate product to final MFC by use of standard disintegrating devices.

First claim

The invention claimed is:

1. A method for the production of a highly refined cellulose product or a microfibrillated cellulose product, the method comprising the steps of:
(a) treating cellulosic fibres having a primary wall material at a first location by mechanical refining, oxidation using peroxide or ozone and/or enzymatically to provide treated fibres having at least 50% of the primary wall material removed;
(b) evaporation drying the treated fibres by use of an evaporation drying machine for pulp to obtain a dried cellulosic pulp intermediate product having a water content of less than 20 wt-%, a Shoppler-Riegler (SR) drainage resistance in the range of 20SR to 35SR, and a wet zero-span tensile strength less than 60 Nm/g;
(c) transporting the dried cellulosic pulp intermediate product at step (b) in the form of two or more stacked sheets to a different second location;
(d) rewetting at least one sheet of the dried cellulosic pulp intermediate product at the different second location to provide wetted fibres; and
(e) disintegrating the wetted fibres by mechanical means to obtain the highly refined cellulose product or the microfibrillatd cellulose product, the highly refined cellulose product having a diameter up to 500 nm and a fibre length of at least 500 μm, and the microfibrillated cellulose product having a diameter of about 5 to 100 nm and a fibre length of about 100 nm to 10 μm.

2. The method of claim 1 , wherein at step (a) the primary wall material of the cellulosic fibres is removed by mechanical refining.

3. The method of claim 1 , wherein at step (a) the primary wall material of the cellulosic fibres is removed by oxidation using peroxide or ozone.

4. The method of claim 1 , wherein at step (a) the primary wall material of cellulosic fibres is removed enzymatically by the use of a cellulase enzyme.

5. The method of claim 1 , wherein the primary wall material of cellulosic fibres is removed by mechanical defibrillation combined with oxidation using peroxide or ozone and/or enzymatic treatment.

6. The method of claim 1 , wherein at step (a) cellulosic fibres are treated enzymatically or by oxidation to remove at least 50% of the primary wall material to provide the treated fibres having an average fibre length of at least 0.4 mm.

7. The method of claim 6 wherein at step (a) the primary wall material is removed by mechanical refining.

8. The method of claim 6 , wherein the primary wall material is removed by mechanical defibrillation combined with oxidation using peroxide or ozone and/or enzymatic treatment.

9. The method of claim 1 , wherein the dried cellulosic pulp intermediate product has a BET surface of more than 40 m 2 /g.

10. The method of claim 1 , wherein the cellulosic fibres are selected from the group consisting of hardwood fibres, softwood fibres, and agricultural fibres.

11. The method of claim 1 , wherein the mechanical means of disintegrating the wetted fibres of step (e) comprises a homogenizer.

12. A method for the production of a highly refined cellulose product or a microfibrillated cellulose product, the method comprising the steps of:
(a) treating cellulosic fibres having a primary wall material at a first location by mechanical refining, oxidation using peroxide or ozone and/or enzymatically to provide treated fibres having at least 50% of the primary wall material removed;
(b) evaporation drying the treated fibres by use of an evaporation drying machine for pulp to obtain a dried cellulosic pulp intermediate product having a water content of less than 20 wt-% a Shoppler-Riegler (SR) drainage resistance in the range of 20SR to 35SR, an average fibre length of at least 0.4 mm, and a wet zero-span tensile strength less than 60 Nm/g;
(c) transporting the dried cellulosic pulp intermediate product at step (b) in the form of two or more stacked sheets to a different second location;
(d) rewetting at least one sheet of the dried cellulosic pulp intermediate product at the different second location to provide wetted fibres; and
(e) disintegrating the wetted fibres by mechanical means to obtain the highly refined cellulose product or the microfibrillatd cellulose product, the highly refined cellulose product having a diameter up to 500 nm and a fibre length of at least 500 μm, and the microfibrillated cellulose product having a diameter of about 5 to 100 nm and a fibre length of about 100 nm to 10 μm.

13. The method of claim 12 , wherein the wet zero-span tensile strength of the dried cellulosic pulp intermediate product of step (b) is less than 40 Nm/g.

14. The method of claim 12 , wherein the dried cellulosic pulp intermediate product of step (b) has a BET surface of more than 40 m 2 /g.

15. The method of claim 12 , wherein the dried cellulosic pulp intermediate product of step (b) is in the form of stacked sheets, ready for transport to a different location.

16. The method of claim 12 , wherein the average fibre length of the dried cellulosic pulp intermediate product of step (b) is more than 70% of the average fibre length of the untreated cellulosic fibres.

17. The method of claim 12 , wherein a content of fines with a fibre length less than 10 μm of the dried cellulosic pulp intermediate product of step (b) is at most 5 wt-%.

18. The method of claim 12 , wherein the dried cellulosic pulp intermediate product of step (b) has a water content of less than 15 wt-%.

Assignees

• Stora Enso Oyj

Inventors

• Heiskanen Isto
• Land Hensdal Cecilia
• Axrup Lars
• Saxell Heidi

Classifications

• D21H11/18 Primary

  Highly hydrated, swollen or fibrillatable fibres · CPC title

• D21C9/005

  organic compounds · CPC title

• C08L1/02 Primary

  Cellulose; Modified cellulose · CPC title

• D21C9/007 Primary

  by mechanical or physical means · CPC title

• D21C5/005

  Treatment of cellulose-containing material with microorganisms or enzymes · CPC title