Method of making a copper oxide-titanium dioxide nanocatalyst

Patent metadata

Field	Value
Publication number	US-10898880-B2
Application number	US-201716083477-A
Country	US
Kind code	B2
Filing date	Mar 9, 2017
Priority date	Mar 9, 2016
Publication date	Jan 26, 2021
Grant date	Jan 26, 2021

Abstract

A method of making a copper oxide-titanium dioxide nanocatalyst for performing the catalytic oxidation of carbon monoxide is provided. The copper oxide-titanium dioxide nanocatalyst is in the form of copper oxide (CuO) nanoparticles supported on mesoporous titanium dioxide (TiO2) nanotubes. The copper oxide-titanium dioxide nanocatalyst is prepared by adding an aqueous solution of Cu(NO3)2.3H2O to an aqueous suspension of titanium dioxide nanotubes. Deposition precipitation at constant alkaline pH is used to form the copper oxide nanoparticles supported on mesoporous titanium dioxide nanotubes. Aqueous sodium carbonate is used to adjust the pH. The solid matter (copper oxide deposited on titanium dioxide nanotubes) is separated from the suspension, washed, dried and calcined, yielding the copper oxide-titanium dioxide nanocatalyst. Carbon monoxide may then flow over a fixed-bed reactor loaded with the copper oxide-titanium dioxide nanocatalyst at a temperature between 80° C. and 200° C.

First claim

We claim:

1. A method of making a copper oxide-titanium dioxide nanocatalyst, comprising the steps of:
sonicating a suspension of titanium dioxide (TiO 2 ) nanotubes in deionized water;
adding an aqueous solution of Cu(NO 3 ) 2 .3H 2 O to form a mixture;
stirring the mixture;
adding an aqueous solution of Na 2 CO 3 to the mixture dropwise until a pH of 9 is obtained;
separating solid matter from the suspension by centrifuge;
washing and drying the solid matter; and
calcining the solid matter to obtain the copper oxide-titanium dioxide nanocatalyst.

2. The method of making a copper oxide-titanium dioxide nanocatalyst as recited in claim 1 , wherein the step of sonicating the suspension of TiO 2 nanotubes in the deionized water comprises sonicating the suspension of TiO 2 nanotubes in the deionized water for a period of 10 minutes.

3. The method of making a copper oxide-titanium dioxide nanocatalyst as recited in claim 1 , wherein the step of stirring the mixture comprises stirring the mixture at room temperature for two hours.

4. The method of making a copper oxide-titanium dioxide nanocatalyst as recited in claim 1 , wherein the step of adding the aqueous solution of Na 2 CO 3 to the mixture comprises adding a 0.2 mol/L aqueous solution of Na 2 CO 3 to the mixture.

5. The method of making a copper oxide-titanium dioxide nanocatalyst as recited in claim 1 , wherein the step of calcining the solid matter comprises calcining the solid matter at a temperature of 400° C. for two hours in air at a temperature ramp rate of 2° C./minute.

6. The method of making a copper oxide-titanium dioxide nanocatalyst as recited in claim 1 , further comprising the steps of:
adding TiO 2 anatase powder to an aqueous solution of NaOH to form an alkaline TiO 2 anatase mixture;
stirring the alkaline TiO 2 anatase mixture;
heating the alkaline TiO 2 anatase mixture;
filtering to obtain a first filtrate from the heated alkaline TiO 2 anatase mixture;
adding an aqueous solution of HCl to the first filtrate until a pH of 6 is obtained to yield a TiO 2 -bearing product;
filtering to obtain a second filtrate from the TiO 2 -bearing product;
heating the second filtrate at a temperature of 80° C.; and
calcining the second filtrate at a temperature of 450° C. for two hours at a temperature ramp rate of 2° C./minute to yield the TiO 2 nanotubes.

7. The method of making a copper oxide-titanium dioxide nanocatalyst as recited in claim 6 , wherein the aqueous solution of NaOH comprises an aqueous solution of 10 M NaOH.

8. The method of making a copper oxide-titanium dioxide nanocatalyst as recited in claim 6 , wherein the step of stirring the alkaline TiO 2 anatase mixture comprises stirring the alkaline TiO 2 anatase mixture for 30 minutes.

9. The method of making a copper oxide-titanium dioxide nanocatalyst as recited in claim 8 , wherein the step of heating the alkaline TiO 2 anatase mixture comprises heating the alkaline TiO 2 anatase mixture at a temperature of 140° C. for 48 hours.

Assignees

• Univ Qatar

Inventors

• Zedan Abdallah F
• Alqaradawi Siham Y

Classifications

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J35/45

  Nanoparticles · CPC title

• B01J2235/15

  X-ray diffraction · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/70

  characterised by their crystalline properties, e.g. semi-crystalline (catalysts comprising carbon B01J21/18; molecular sieves B01J29/00) · CPC title