Process and apparatus for producing uranium or a rare earth element

Patent metadata

Field	Value
Publication number	US-10894999-B2
Application number	US-201615762743-A
Country	US
Kind code	B2
Filing date	Jun 30, 2016
Priority date	Sep 29, 2015
Publication date	Jan 19, 2021
Grant date	Jan 19, 2021

Abstract

In a process for producing uranium and/or at least one rare earth element selected from the group consisting of cerium, dysprosium, erbium, europium, gadolinium, holmium, lanthanum, lutetium, neodymium, praseodymium, promethium, samarium, scandium, terbium, thulium, ytterbium and yttrium out of an ore, the ore is mixed with sulphuric acid with a concentration of at least 95 wt.-% to a mixture, wherein the mixture is granulated to pellets. The pellets are fed into at least one fluidized bed fluidized by a fluidizing gas for a thermal treatment at temperatures between 200 and 1000° C. The at least one fluidized bed is developed such that it at least partly surrounds a gas supply tube for a gas or a gas mixture fed into the reactor and the gas or gas mixture is used as a heat transfer medium.

First claim

The invention claimed is:

1. Process for producing uranium (U) and/or at least one rare earth element selected from the group consisting of cerium (Ce), dysprosium (Dy), erbium (Er), europium (Eu), gadolinium (Gd), holmium (Ho), lanthanum (La), lutetium (Lu), neodymium (Nd), praseodymium (Pr), promethium (Pm), samarium (Sm), scandium (Sc), terbium (Tb), thulium (Tm), ytterbium (Yb) and yttrium (Y) out of an ore, the process comprising:
mixing the ore with sulphuric acid having a concentration of at least 95 wt.-% to form a mixture,
granulating the mixture into pellets, and
feeding the pellets sequentially into a first fluidized bed, a second fluidized bed, and a third fluidized bed, in the stated order,
wherein the first, second, and third fluidized beds are connected in series and each is fluidized by a separate fluidizing gas,
wherein each of the first, second and third fluidized beds at least partly surrounds a gas supply tube for feeding a gas or a gas mixture,
wherein the gas or gas mixture is used as a heat transfer medium in the first, second and third fluidized bed,
wherein off-gas of a low temperature heating in the second fluidized bed performed at temperatures between 200 and 350° C. is used as the gas or the gas mixture in the first fluidized bed for a preheating performed at temperatures between 150 and 250° C., and off-gas of a high temperature heating in the third fluidized bed performed at temperatures between 500 and 800° C. is used as the gas or the gas mixture in the second fluidized bed for the low temperature heating,
wherein the pellets have an average diameter between 100 and 500 μm and/or 10 wt.-% of the pellets have a diameter of more than 1 mm, and
wherein the residence time in the preheating is between 1 s and 5 minutes, the residence time in the low temperature heating is between 5 and 20 minutes, and the residence time in the high temperature heating is between 5 and 20 minutes.

2. Process according to claim 1 , wherein an off-gas of the preheating is fed into a gas cleaning stage.

Assignees

• Outotec Finland Oy

Inventors

• Wrobel Maciej
• Güntner Jochen
• Charitos Alexandros
• Hammerschmidt Jörg

Classifications

• C22B1/2406

  pelletizing · CPC title

• C22B59/00

  Obtaining rare earth metals · CPC title

• C22B5/14

  fluidised material · CPC title

• C22B60/0208 Primary

  preliminary treatment of ores or scrap · CPC title

• C22B60/0213

  by dry processes · CPC title