Process for producing fuel using two fermentations

Patent metadata

Field	Value
Publication number	US-10894969-B2
Application number	US-201916244767-A
Country	US
Kind code	B2
Filing date	Jan 10, 2019
Priority date	Jul 22, 2014
Publication date	Jan 19, 2021
Grant date	Jan 19, 2021

Abstract

A process is provided for forming a fuel or a fuel intermediate from two fermentations that includes feeding an aqueous solution comprising a fermentation product from a first bioreactor to a second bioreactor and/or a stage upstream of the second bioreactor, which also produces the fermentation product. The aqueous solution may be added at any stage of the second fermentation and/or processing steps upstream from the second bioreactor that would otherwise require the addition of water. Accordingly, the product yield is increased while fresh/treated water usage is decreased.

First claim

The invention claimed is:

1. A process for producing ethanol comprising:
(i) obtaining methane sourced from biogas, said biogas produced from anaerobic digestion;
(ii) reforming a gas to produce syngas, said gas comprising the methane sourced from biogas;
(iii) converting one or more components of the syngas to ethanol, said converting comprising subjecting a gas substrate comprising the one or more components to a gas fermentation, said one or more components comprising carbon monoxide, carbon dioxide, hydrogen, or a combination thereof;
(iv) using an aqueous stream comprising ethanol produced in (iii) in an ethanol production process that comprises fermenting carbohydrate to ethanol,

wherein step (iv) comprises feeding said aqueous stream to a stage in the ethanol production process such that ethanol produced in (iii) is copresent with carbohydrate during at least part of a step of fermenting said carbohydrate to ethanol.

2. The process according to claim 1 , comprising recovering ethanol produced in (iii) together with ethanol produced by fermenting said carbohydrate to ethanol.

3. The process according to claim 2 , wherein said gas substrate comprises carbon dioxide produced from fermenting said carbohydrate to ethanol.

4. The process according to claim 2 , wherein said ethanol production process is a cellulosic ethanol production process, and wherein said biogas comprises biogas produced from anaerobic digestion of still bottoms produced in said cellulosic ethanol production process.

5. The process according to claim 4 , wherein said gas reformed in step (ii) comprises fossil methane.

6. The process according to claim 4 , comprising:
(a) converting fossil methane to carbon monoxide and hydrogen by reforming;
(b) converting at least a portion of the carbon monoxide produced in (a) by a water-gas shift reaction to carbon dioxide, thereby producing a stream comprising carbon dioxide and hydrogen; and
(c) separating at least a portion of the hydrogen from the stream of step (b) from non-hydrogen components to produce a stream enriched in hydrogen and a stream comprising carbon dioxide;
wherein said gas substrate comprises hydrogen from the stream enriched in hydrogen.

7. The process according to claim 6 , wherein said gas substrate comprises carbon dioxide produced from carbohydrate fermentation in said cellulosic ethanol production process.

8. The process according to claim 7 , wherein said gas substrate comprises hydrogen and carbon dioxide in amounts sufficient to provide a molar ratio of hydrogen to carbon dioxide between 2:1 and 4:1.

9. A process for producing ethanol comprising:
(i) treating a feedstock to obtain a fermentable carbohydrate;
(ii) fermenting said fermentable carbohydrate to produce ethanol;
(iii) feeding a portion of the treated feedstock not converted to ethanol to an anaerobic digester;
(iv) collecting biogas from said anaerobic digester;
(v) converting one or more components of said collected biogas to ethanol, said converting comprising fermenting a gas substrate comprising one or more components obtained or derived from the collected biogas, said one or more components selected from carbon monoxide, carbon dioxide, and hydrogen; and
(vii) using an aqueous stream comprising ethanol produced in step (v) within the process such that ethanol produced in step (v) is copresent with fermentable carbohydrate for at least part of a step of fermenting said fermentable carbohydrate to produce ethanol.

10. The process according to claim 9 , wherein converting one or more components of said collected biogas to ethanol comprises:
reforming a gas to produce syngas, wherein said gas comprises methane from said collected biogas, and wherein said gas substrate comprises one or more components of the syngas.

11. The process according to claim 9 , wherein converting one or more components of said collected biogas to ethanol comprises:
subjecting a gas to a steam reforming process to produce syngas, wherein said gas comprises said collected biogas and carbon dioxide produced from fermenting said fermentable carbohydrate, wherein said gas substrate comprises one or more components of the syngas.

12. The process according to claim 9 , comprising collecting carbon dioxide produced from fermenting said fermentable carbohydrate, wherein said gas substrate comprises said collected carbon dioxide.

13. The process according to claim 12 , comprising:
(a) converting fossil methane to carbon monoxide and hydrogen by reforming;
(b) converting at least a portion of said carbon monoxide by a water-gas shift reaction to carbon dioxide, thereby producing a stream comprising carbon dioxide and hydrogen; and
(c) separating at least a portion of the hydrogen from the stream of step (b) from non-hydrogen components to produce a stream enriched in hydrogen and a stream comprising carbon dioxide;
wherein said gas substrate comprises hydrogen from said stream enriched in hydrogen.

14. The process according to claim 9 , comprising:
(a) converting fossil methane to carbon monoxide and hydrogen by reforming;
(b) converting at least a portion of said carbon monoxide by a water-gas shift reaction to carbon dioxide, thereby producing a stream comprising carbon dioxide and hydrogen; and
(c) separating at least a portion of said hydrogen from the stream of step (b) from non-hydrogen components to produce a stream enriched in hydrogen and a stream comprising carbon dioxide;
wherein said gas substrate comprises hydrogen from the stream enriched in hydrogen.

15. The process according to claim 9 , comprising recovering ethanol produced in step (v) and ethanol derived from the fermentable carbohydrate.

16. The process according to claim 9 , wherein said portion of treated feedstock not converted to ethanol and fed to anaerobic digestion comprises still bottoms.

17. The process according to claim 9 , wherein said gas substrate comprises hydrogen and carbon dioxide in amounts sufficient to provide a molar ratio of hydrogen to carbon dioxide between 2:1 and 4:1.

18. The process according to claim 9 , wherein said gas substrate is syngas produced by reforming said collected biogas.

19. The process according to claim 9 , wherein said gas substrate comprises syngas produced by reforming said collected biogas, hydrogen derived from fossil methane, carbon dioxide collected from carbohydrate fermentation, or any combination thereof.

Assignees

• Iogen Corp

Inventors

• Foody Patrick J

Classifications

• Y02E50/10

  Biofuels, e.g. bio-diesel · CPC title

• C12P5/00

  Preparation of hydrocarbons {or halogenated hydrocarbons} · CPC title

• B01D3/001

  Processes specially adapted for distillation or rectification of fermented solutions · CPC title

• Y02P30/00

  Technologies relating to oil refining and petrochemical industry · CPC title

• Y02E50/30

  Fuel from waste, e.g. synthetic alcohol or diesel · CPC title