Aqueous coating composition and process of making the same

Patent metadata

Field	Value
Publication number	US-10894889-B2
Application number	US-201415533666-A
Country	US
Kind code	B2
Filing date	Dec 19, 2014
Priority date	Dec 19, 2014
Publication date	Jan 19, 2021
Grant date	Jan 19, 2021

Abstract

An aqueous coating composition includes, based on the total weight of the aqueous coating composition, (a) an aqueous polymer dispersion present in an amount of from 15% to 33% by solids weight, wherein the polymer includes at least 95% by solids weight of an acrylic emulsion copolymer based on the solids weight of the polymer; (b) anionic colloidal silica present in an amount of from 1% to 13% by solids weight; (c) a solvent present in an amount of from 0.5% to 9% by weight, wherein the solvent has at least one hydroxyl group and a dielectric constant at 25° C. of from 7 to 10.3; (d) a monoamine compound present in an amount of from 0.2% to 1.5% by weight, wherein the monoamine compound is selected from an alkyl monoamine, a beta-hydroxyl monoamine containing up to 2 hydroxyl groups, or mixtures thereof; and (e) water.

First claim

What is claimed is:

1. An aqueous coating composition comprising, based on the total weight of the aqueous coating composition,
(a) an aqueous polymer dispersion present in an amount of from 15% to 33% by solids weight, wherein the polymer comprises at least 95% by solids weight of an acrylic emulsion copolymer based on the solids weight of the polymer;
(b) anionic colloidal silica present in an amount of from 1% to 13% by solids weight;
(c) a solvent present in an amount of from 0.5% to 9% by weight, wherein the solvent has at least one hydroxyl group and a dielectric constant at 25° C. of from 7 to 10.3, and is at least one of diethylene glycol monobutyl ether, ethylene glycol monobutyl ether, ethylene glycol monohexyl ether, triethylene glycol monobutyl ether, dipropylene glycol n-butyl ether, propylene glycol n-butyl ether, dipropylene glycol n-propyl ether, propylene glycol n-propyl ether, or diethylene glycol monomethyl ether;
(d) a monoamine compound present in an amount of from 0.2% to 1.5% by weight, wherein the monoamine compound is selected from an alkyl monoamine, a beta-hydroxyl monoamine containing up to 2 hydroxyl groups, or mixtures thereof; and
(e) water;
wherein the aqueous coating composition is substantially free of silane coupling agents.

2. The aqueous coating composition of claim 1 , wherein the monoamine compound is a primary monoamine.

3. The aqueous coating composition of claim 1 , wherein the monoamine compound is selected from n-butylamine, 2-amino-2-methyl-1-propanol, or mixtures thereof.

4. The aqueous coating composition of claim 1 , wherein the monoamine compound is present in an amount of from 0.5% to 1.2% by weight, based on the total weight of the aqueous coating composition.

5. The aqueous coating composition of claim 1 , wherein the anionic colloidal silica has a pH value >8.5.

6. The aqueous coating composition of claim 1 , wherein silica particles in the anionic colloidal silica have a specific surface area of from 20 to 800 m 2 /g.

7. The aqueous coating composition of claim 1 , wherein the anionic colloidal silica is present in an amount of from 1.5% to 11% by solids weight, based on the total weight of the aqueous coating composition.

8. The aqueous coating composition of claim 1 , wherein the solvent is present in an amount of from 1% to 7% by weight based on the total weight of the aqueous coating composition.

9. The aqueous coating composition of claim 1 , wherein the acrylic emulsion copolymer has a glass transition temperature of from 0° C. to 40° C.

10. The aqueous coating composition of claim 1 , being substantially free of microfillers.

11. An aqueous coating composition comprising, based on the total weight of the aqueous coating composition,
(a) an aqueous polymer dispersion present in an amount of from 18% to 31% by solids weight, wherein the polymer comprises at least 95% by solids weight of an acrylic emulsion copolymer based on the solids weight of the polymer;
(b) anionic colloidal silica present in an amount of from 1.5% to 11% by solids weight, wherein silica particles in the anionic colloidal silica have a specific surface area of from 80 to 500 m 2 /g;
(c) a solvent present in an amount of from 1% to 4% by weight, wherein the solvent has at least one hydroxyl group and a dielectric constant at 25° C. of from 7 to 10.3, and is at least one of diethylene glycol monobutyl ether, ethylene glycol monobutyl ether, ethylene glycol monohexyl ether, triethylene glycol monobutyl ether, dipropylene glycol n-butyl ether, propylene glycol n-butyl ether, dipropylene glycol n-propyl ether, propylene glycol n-propyl ether, or diethylene glycol monomethyl ether;
(d) a monoamine compound present in an amount of from 0.7% to 1% by weight, wherein the monoamine is selected from an alkyl monoamine, a beta-hydroxyl monoamine containing up to 2 hydroxyl groups, or mixtures thereof; and
(e) water;
wherein the aqueous coating composition is substantially free of silane coupling agents.

12. A process of preparing the aqueous coating composition of claim 1 , comprising: admixing
(a) the aqueous polymer dispersion,
(b) the anionic colloidal silica,
(c) the solvent,
(d) the monoamine compound, and
(e) water.

13. A method of imparting both low gloss and high clarity to a substrate comprising:
forming the aqueous coating composition of claim 1 ,
applying the aqueous coating composition to a substrate, and
drying the applied coating composition to form a coating; wherein the coating has a gloss level of 20 or less on a 60° Gardner Gloss scale and a clarity value of 40% or higher.

Assignees

• Dow Global Technologies Llc

Inventors

• Xu Yawei
• Shen Biao
• Yang Xiaohong

Classifications

• B27K3/12

  Impregnating by coating the surface of the wood with an impregnating paste · CPC title

• C09D133/00

  Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers · CPC title

• C09D7/63

  organic · CPC title

• C09D133/14

  of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen · CPC title

• C08K3/36

  Silica · CPC title