Product, composition and application thereof, and automobile tire inner liner, tube and curing bladder

Patent metadata

Field	Value
Publication number	US-10894881-B2
Application number	US-201716331470-A
Country	US
Kind code	B2
Filing date	Sep 7, 2017
Priority date	Sep 7, 2016
Publication date	Jan 19, 2021
Grant date	Jan 19, 2021

Abstract

Butyl rubber, a preparation method therefor, and an application thereof, and a composition and rubber product containing the butyl rubber. The butyl rubber comprises a structural unit derived from isobutylene, a structural unit derived from conjugated diene, and a structural unit selectively derived from aryl olefin represented by formula I, at least a part of the conjugated diene being isoprene. Also provided are an automobile tire inner liner, tube and curing bladder made of the butyl rubber. The butyl rubber has good processability and compounding properties, die swell ratio and integrated mechanical properties, and particularly high tear strength. The butyl rubber can effectively reduce power consumption in the processing and compounding process, and the prepared product has good dimensional stability and application performance.

First claim

The invention claimed is:

1. A butyl rubber, comprising a structural unit derived from isobutylene, a structural unit derived from conjugated diene, and optionally a structural unit derived from aryl olefin,
wherein, at least a part of the conjugated diene is isoprene, and the aryl olefin is a compound of Formula I,

in Formula I, R 1 is an aryl group of C 6 -C 20 ;
wherein, in the butyl rubber, a part of the structural unit derived from conjugated diene serves as a grafting site so that a part of the molecular chain of the butyl rubber is a grafted chain, and a remaining part of the molecular chain of the butyl rubber is a linear chain; and
wherein a peak molecular weight of the butyl rubber is 0.9 million to 2.6 million, and a content of the butyl rubber of which Log (MW) is greater than or equal to 6 is 30 to 80% by weight wherein MW is molecular weight.

2. The butyl rubber according to claim 1 , wherein the main chain of the grafted chain comprises the structural unit derived from conjugated diene and the structural unit derived from aryl olefin, and
a branch of the grafted chain comprises the structural unit derived from isobutylene and the structural unit derived from isoprene.

3. The butyl rubber according to claim 1 , wherein the linear chain comprises the structural unit derived from isobutylene and the structural unit derived from isoprene.

4. The butyl rubber according to claim 1 , wherein, based on a total amount of the butyl rubber, a content of the structural unit derived from conjugated diene is from 0.5 to 2.5 mol %, and a content of the structural unit derived from aryl olefin is from 0.01 to 3 mol %.

5. The butyl rubber according to claim 1 , wherein a Mooney viscosity ML (1+8) 125° C. of the butyl rubber is 30 to 70.

6. The butyl rubber according to claim 1 , wherein the content of the butyl rubber of which Log (MW) is greater than or equal to 6 is 35 to 75% by weight.

7. The butyl rubber according to claim 1 , wherein the peak molecular weight of the butyl rubber is 0.95 million to 2.3 million. more preferably 1 . 1 million to 1 . 9 million.

8. The butyl rubber according to claim 1 , wherein a molecular weight of the butyl rubber exhibits a bimodal distribution, and a Log (MW) value of a high molecular weight shoulder peak is between 6 and 7.5.

9. The butyl rubber according to claim 1 , wherein the butyl rubber is prepared by a method comprising a step of contacting isobutylene and isoprene with at least one grafting agent in at least one diluent in the presence of at least one Lewis acid and at least one compound capable of providing protons under cationic polymerization conditions,
wherein the at least one Lewis acid is a compound of Formula III,
AlR 5 n X 1 (3-n)   (Formula III)

in Formula III, R 5 are the same or different and each represents an alkyl group of C 1 -C 8 ; X 1 are the same or different and each represents a halogen; n is 1, 2 or 3; and
the at least one compound capable of providing protons is protonic acid.

10. The butyl rubber according to claim 9 , wherein, based on a total amount of isobutylene and isoprene, a content of the isobutylene is 85 to 99% by weight, and a content of isoprene is 1 to 15% by weight.

11. The butyl rubber according to claim 9 , wherein an amount of the at least one grafting agent is 0.01 to 3% by weight of isobutylene.

12. The butyl rubber according to claim 9 , wherein the at least one grafting agent comprises polymerizable structural unit with cationically polymerizable group and the optional aryl olefin structural unit derived from the compound of Formula I.

13. The butyl rubber according to claim 12 , wherein, in the at least one grafting agent, a content of the polymerizable structural unit is 1 to 15 mol %; and/or
a weight-average molecular weight of the at least one grafting agent is 10,000 to 300,000; and a molecular weight distribution index is 1 to 2.5.

14. The butyl rubber according to claim 9 , wherein a molar ratio of the at least one Lewis acid to isobutylene is 1:500 to 1:5,000; and/or
a molar ratio of the at least one compound capable of providing protons to the at least one Lewis acid is from 0.01:1 to 1:1; and/or
the at least one diluent is selected from alkanes and halogenated alkanes.

15. The butyl rubber according to claim 9 , wherein the contacting step is carried out at a temperature ranging from −120° C. to −50° C.

16. A halogenated butyl rubber, comprising a rubber matrix and a halogen element bonded to the rubber matrix, wherein the rubber matrix is the butyl rubber of claim 1 .

17. The halogenated butyl rubber according to claim 16 , wherein the halogen element is a chlorine element and/or a bromine element.

18. The halogenated butyl rubber according to claim 16 , wherein, based on a total amount of the halogenated butyl rubber, a content of the halogen element is in a range of 0.2 to 2 mol %.

19. A composition, comprising the butyl rubber according to claim 1 , a vulcanizing agent, and optionally at least one additive agent, wherein the at least one additive agent is a vulcanization accelerator or carbon black.

20. An automobile tire inner liner, formed by the halogenated butyl rubber according to claim 16 .

21. An automobile tire inner tube, formed by the butyl rubber according to claim 1 .

22. A curing bladder, formed by the butyl rubber according to claim 1 .

23. A composition, comprising the halogenated butyl rubber according to claim 16 , a vulcanizing agent, and optionally at least one additive agent, wherein the at least one additive agent is a vulcanization accelerator or carbon black.

Assignees

• China Petroleum & Chem Corp
• Beijing Res Inst Chemical Ind China Petroleum & Chemical Corp

Inventors

• Qiu Yingxin
• Gong Huiqin
• Zhang Lei
• Meng Weijuan
• Zhou Xinqin
• Wang Lei

Classifications

• C08L51/00

  Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds (for ABS polymers C08L55/02); Compositions of derivatives of such polymers · CPC title

• B60C1/0008

  Compositions of the inner liner · CPC title

• C08K5/0025

  Crosslinking or vulcanising agents; including accelerators · CPC title

• C08F2500/21

  Rubbery or elastomeric properties · CPC title

• C08L51/04

  grafted on to rubbers · CPC title