Method for granulating urea

Patent metadata

Field	Value
Publication number	US-10894764-B2
Application number	US-201816494710-A
Country	US
Kind code	B2
Filing date	Mar 6, 2018
Priority date	Mar 17, 2017
Publication date	Jan 19, 2021
Grant date	Jan 19, 2021

Abstract

Precipitation of an ammonium salt is prevented while suppressing an increase in water content of the aqueous urea solution which is to be supplied to a urea granulation step, when recovering and using urea and NH3 in a gas which contains urea dust and NH3 and which arises from a urea granulation step.

First claim

What is claimed is:

1. A method for continuously granulating urea, comprising
a granulation step of producing granular solid urea from a feed aqueous urea solution by using air, and discharging air containing urea dust and ammonia,
a recovery step of recovering urea dust and ammonia from air containing urea dust and ammonia discharged from the granulation step, by use of an aqueous solution containing an acid, so as to obtain an aqueous recovered-urea solution which is an aqueous solution containing urea and an ammonium salt;
an ammonium salt concentration adjustment step of mixing the aqueous recovered-urea solution which is obtained from the recovery step with an aqueous urea solution having a lower ammonium salt concentration as compared to that of the aqueous recovered-urea solution, so as to adjust the ammonium salt concentration of the aqueous recovered-urea solution;
a concentration step of concentrating the aqueous recovered-urea solution which is obtained from the ammonium salt concentration adjustment step by vaporizing water which is contained in the aqueous recovered-urea solution which is obtained from the ammonium salt concentration adjustment step, so as to obtain a concentrated aqueous recovered-urea solution; and
a mix step of mixing the concentrated aqueous recovered-urea solution with the feed aqueous urea solution before the feed aqueous urea solution is fed to the granulation step,
wherein the ammonium salt concentration of the concentrated aqueous recovered-urea solution is 7 mass % or less.

2. The method according to claim 1 , wherein, in the ammonium salt concentration adjustment step, a part of the feed aqueous urea solution, before or after the concentrated aqueous recovered-urea solution is mixed with it, is used as said aqueous urea solution having a lower ammonium salt concentration.

3. The method according to claim 1 , further comprising, before the concentration step, a neutralization step of adding an alkali to the aqueous recovered-urea solution which is obtained from the recovery step to neutralize a residue of the acid in the aqueous recovered-urea solution, the neutralization step is conducted after the recovery step.

4. The method according to claim 1 , further comprising a control step of controlling the ammonium salt concentration of the concentrated aqueous recovered-urea solution by manipulating the flow rate of said aqueous urea solution having a lower ammonium salt concentration which is to be mixed with the aqueous recovered-urea solution in the ammonium salt concentration adjustment step, based on the present value of the ammonium salt concentration of the concentrated aqueous recovered-urea solution.

5. The method according to claim 4 , wherein, in the control step, the present value of the ammonium salt concentration of the concentrated aqueous recovered-urea solution is obtained based on the temperature and pressure of the water vaporization in the concentration step and the temperature and density of the concentrated aqueous recovered-urea solution.

6. The method according to claim 1 , wherein the acid is at least one acid selected from the group consisting of sulfuric acid, nitric acid and phosphoric acid.

7. The method according to claim 1 , further comprising a step of supplying the water, which is vaporized in the concentration step, to the recovery step.

8. The method according to claim 1 , wherein the acid comprises sulfuric acid.

Assignees

• Toyo Engineering Corp

Inventors

• Nakamura Shuhei
• Sugiura Akiko
• Sasaki Keigo

Classifications

• C07C273/16 Primary

  Separation; Purification · CPC title

• C07C275/00

  Derivatives of urea, i.e. compounds containing any of the groups [IMAGE cpc-sch-C07C-0967.gif], the nitrogen atoms not being part of nitro or nitroso groups · CPC title

• B01J2/00

  Processes or devices for granulating materials {, e.g. fertilisers} in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic · CPC title