Method for welding polyamide and poly(meth)acrylate plastics

Patent metadata

Field	Value
Publication number	US-10894366-B2
Application number	US-201815933906-A
Country	US
Kind code	B2
Filing date	Mar 23, 2018
Priority date	Oct 16, 2015
Publication date	Jan 19, 2021
Grant date	Jan 19, 2021

Abstract

The invention relates to a method for welding a polyamide plastic and a poly(meth)acrylate—particularly a polymethyl methacrylate—plastic using a primer, said primer containing at least one copolymer synthesised from at least one styrene or styrene derivative and at least one maleic anhydride or maleic anhydride derivative. The invention also relates to correspondingly welded products.

First claim

What is claimed is:

1. A method for welding polyamide plastics and poly(meth)acrylate plastics, comprising:
providing a polyamide plastic substrate having a surface defining a joining zone on a portion of that surface,
providing a poly(meth)acrylate plastic substrate having a surface defining a joining zone on a portion of that surface,
applying a primer onto the joining zone surface of at least one of the polyamide plastic substrate and the poly(meth)acrylate plastic substrate,
positioning the polyamide plastic substrate joining zone adjacent the poly(meth)acrylate substrate joining zone so that the primer is disposed between the joining zones, and
welding the polyamide plastic substrate joining zone to the poly(meth)acrylate substrate joining zone,
wherein the primer contains at least one copolymer synthesized from at least one styrene or styrene derivative and at least one maleic anhydride or maleic anhydride derivative.

2. The welding method according to claim 1 , wherein the polyamide plastic is selected from the group consisting of polyamide 6, polyamide 6.6, polyamide 6.10, polyamide 6.12, polyamide 10.10, polyamide 11, polyamide 12, polyamide 10.12, polyphthalamides, optically transparent polyamides and mixtures based on said polyamides.

3. The welding method according to claim 1 , wherein the poly(meth)acrylate plastic is made up of 50 to 100 wt. % methyl methacrylate, the poly(meth)acrylate plastic has molar mass (weight average Mw) of more than 50000 g/mol, and/or the poly(meth)acrylate plastic is a poly(methylmethacrylate) plastic.

4. The welding method according to claim 1 , wherein the at least one copolymer has a molar ratio of styrene to maleic anhydride of from 1:0.01 to 1:2.

5. The welding method according to claim 1 , wherein the at least one copolymer comprises a monomer selected from the group consisting of acrylates and methacrylates.

6. The welding method according to claim 1 , wherein the at least one copolymer has a maleic anhydride content of 0.1-50 wt. %, based on the copolymer.

7. The welding method according to claim 1 , wherein the at least one copolymer of the primer has a glass transition temperature Tg of more than 30° C.

8. The welding method according to claim 1 , wherein the at least one copolymer has a weight-average molecular weight Mw in the range of from 5000-2000000 g/mol.

9. The welding method according to claim 1 , wherein the primer contains, in addition to the at least one copolymer, at least one further polymer that is compatible with at least one of the polyamide plastic or the poly(meth)acrylate plastic to be welded.

10. The welding method according to claim 1 , wherein the primer contains 10-90 wt. % of organic solvent, based on the total weight of the primer.

11. The welding method according to claim 10 , wherein the organic solvent has a vapor pressure at 20° C. of from 1 to 600 hPa, and the organic solvent is selected from the group consisting of tetrahydrofuran, methyl isobutyl ketone (MIBK), cyclohexanone and mixtures thereof.

12. An object produced according to the welding method according to claim 1 .

13. The welding method according to claim 1 , wherein the step of welding comprises hot gas welding, hot plate welding, ultrasonic welding, high frequency welding, friction welding, laser welding, infrared welding, thermal contact welding, thermal pulse welding, microwave welding, induction welding or a combination thereof.

14. The welding method according to claim 1 , wherein the step of welding comprises ultrasonic welding, friction welding, infrared welding or a combination thereof.

15. The welding method according to claim 1 , wherein the welded polyamide plastic substrate joining zone and the poly(meth)acrylate substrate joining zone form a weld seam.

16. The welding method according to claim 1 , wherein the polyamide plastic substrate is welded to the poly(meth)acrylate substrate only in their respective joining zones.

17. The welding method according to claim 1 , wherein the step of welding comprises heating the polyamide plastic substrate and the poly(meth)acrylate plastic substrate only in their respective joining zones.

18. The welding method according to claim 1 , wherein the primer is an aqueous dispersion or emulsion.

Assignees

• Henkel Ag & Co Kgaa

Inventors

• Walter Pablo
• Friedrich Norman
• Gonzalez Lina
• Luetzen Hendrik
• Haertig Thomas

Classifications

• C08J5/121 Primary

  by heating · CPC title

• C08J7/043

  Improving the adhesiveness of the coatings per se, e.g. forming primers (adhesives in the form of films or foils characterised by the primer layers between the polymer carriers and the adhesives C09J7/50) · CPC title

• B29C65/02 Primary

  by heating, with or without pressure · CPC title

• B29C66/02

  Preparation of the material, in the area to be joined, prior to joining or welding (B29C66/32 takes precedence) · CPC title

• B29C66/731

  characterised by the intensive physical properties of the material of the parts to be joined · CPC title