Composition for forming a heating element and method of preparing the composition

Patent metadata

Field	Value
Publication number	US-10893578-B2
Application number	US-201816145753-A
Country	US
Kind code	B2
Filing date	Sep 28, 2018
Priority date	Oct 11, 2017
Publication date	Jan 12, 2021
Grant date	Jan 12, 2021

Abstract

A composition for forming a heating element; a dried and sintered product thereof; and a method of preparing the composition for forming a heating element, the composition including a matrix particle, a composite filler, and a solvent, wherein the composite filler includes a core and a coating layer disposed on the core, the core includes a nanosheet filler, and the composition has a pH in a range of about 5 to about 9.

First claim

What is claimed is:

1. A composition for forming a heating element, comprising:
a matrix particle and an ionically charged coating layer disposed on a surface of the matrix particle;
a composite filler; and
a solvent,
wherein the composite filler comprises a core and a coating layer disposed on the core,
the core comprises a nanosheet filler, and
the composition has a pH in a range of about 5 to about 9, and
wherein the coating layer disposed on the core has a bilayer structure comprising a first polymer layer disposed on the nanosheet filler and a second polymer layer disposed on the first polymer layer.

2. The composition of claim 1 , wherein the coating layer disposed on the core is a polymer layer comprising one or more polymers.

3. The composition of claim 1 , wherein the coating layer disposed on the core comprises a polymer having a positive charge or a negative charge.

4. The composition of claim 1 , wherein the coating layer disposed on the core comprises an amphiphilic polymer.

5. The composition of claim 1 , wherein the coating layer disposed on the core comprises polyethyleneimine, polyethylene oxide-block-polypropylene oxide-block-polyethylene oxide, polyvinylamine, polyethylene oxide-block-polyacrylic acid, polyethylene oxide-block-polymethacrylic acid, polyethylene oxide-block-polyethyleneimine, polyethylene oxide-block-polyaspartic acid, polydimethylaminoethyl methacrylate-block-polydihydropropyl methacrylate, polyacrylic acid-block-polyacrylamide, polyacrylic acid-block-polyhydroxyethyl acrylate, polyethyleneamine, polyethylene oxide, polyethylene glycol, polyethylene sulfone, or a combination thereof.

6. The composition of claim 1 , wherein the coating layer disposed on the core comprises a first polymer and a second polymer, and a weight ratio of the first polymer to the second polymer is in a range of about 10:90 to about 90:10.

7. The composition of claim 1 , wherein an amount of a polymer present in the coating layer disposed on the core is in a range of about 10 parts by weight to about 500 parts by weight, based on 100 parts by weight of the nanosheet filler.

8. The composition of claim 1 , wherein the nanosheet filler comprises an oxide, a boride, a carbide, a chalcogenide, or a combination thereof.

9. The composition of claim 1 , wherein the nanosheet filler comprises RuO 2 , MnO 2 , ReO 2 , VO 2 , OsO 2 , TaO 2 , IrO 2 , NbO 2 , WO 2 , GaO 2 , MoO 2 , InO 2 , CrO 2 , RhO 2 , Ta 3 B 4 , Nb 3 B 4 , TaB, NbB, V 3 B 4 , Dy 2 C, Ho 2 C, AuTe 2 , PdTe 2 , PtTe 2 , YTe 3 , CuTe 2 , NiTe 2 , IrTe 2 , PrTe 3 , NdTe 3 , SmTe 3 , GdTe 3 , TbTe 3 , DyTe 3 , HoTe 3 , ErTe 3 , CeTe 3 , LaTe 3 , TiSe 2 , TiTe 2 , ZrTe 2 , HfTe 2 , TaSe 2 , TaTe 2 , TiS 2 , NbS 2 , TaS 2 , Hf 3 Te 2 , VSe 2 , VTe 2 , NbTe 2 , LaTe 2 , CeTe 2 , or a combination thereof.

10. The composition of claim 1 , wherein the nanosheet filler has a thickness in a range of about 1 nanometer to about 1,000 nanometers and a length in a range of about 0.1 micrometers to about 500 micrometers.

11. The composition of claim 1 , wherein the nanosheet filler is present in an amount of about 20 volume percent or less, based on a total volume of the matrix particle and the nanosheet filler.

12. The composition of claim 1 , wherein the nanosheet filler has an electrical conductivity of about 1000 siemens per meter or greater.

13. The composition of claim 1 , wherein dispersibility of the composite filler is independent of the pH of the composition.

14. The composition of claim 1 , wherein the matrix particle comprises a glass frit.

15. The composition of claim 14 , wherein the glass frit comprises silicon oxide, lithium oxide, nickel oxide, cobalt oxide, boron oxide, potassium oxide, aluminum oxide, titanium oxide, manganese oxide, copper oxide, zirconium oxide, phosphorus oxide, zinc oxide, bismuth oxide, lead oxide, sodium oxide, or a combination thereof.

16. The composition of claim 15 , wherein the glass frit comprises an additive and a silicon oxide, and
the additive comprises Li, Ni, Co, B, K, Al, Ti, Mn, Cu, Zr, P, Zn, Bi, Pb, Na, or a combination thereof.

17. The composition of claim 14 , wherein the glass frit comprises a zinc oxide-silicon oxide glass frit, a zinc oxide-boron oxide-silicon oxide glass frit, a zinc oxide-boron oxide-silicon oxide-aluminum oxide glass frit, a bismuth oxide-silicon oxide glass frit, a bismuth oxide-boron oxide-silicon oxide glass frit, a bismuth oxide-boron oxide-silicon oxide-aluminum oxide glass frit, a bismuth oxide-zinc oxide-boron oxide-silicon oxide glass frit, a bismuth oxide-zinc oxide-boron oxide-silicon oxide-aluminum oxide glass frit, or a combination thereof.

18. The composition of claim 1 , wherein the matrix particle has a particle diameter in a range of about 1 micrometer to about 50 micrometers.

19. The composition of claim 1 , wherein the ionically charged coating layer disposed on the surface of the matrix particle comprises a hydrolysate of an organosilane, an amphiphilic polymer, or a combination thereof.

20. The composition of claim 19 , wherein the organosilane comprises N-2-(aminoethyl)-3-aminopropylmethyldimethoxysilane, N-2-(aminoethyl)-3-aminopropyltrimethoxysilane, 3-aminopropyltrimethoxy silane, 3-aminopropyltri ethoxysilane, N-phenyl-3-aminopropyltrimethoxysilane, or a combination thereof.

21. The composition of claim 1 , further comprising:
a dispersion stabilizer, an oxidation stabilizer, a weather stabilizer, an antistatic agent, a dye, a pigment, a coupling agent, or a combination thereof.

22. The composition of claim 21 , wherein the dispersion stabilizer comprises tetrabutyl ammonium hydroxide, tetramethyl ammonium hydroxide, or a combination thereof.

23. The composition of claim 1 , further comprising:
a binder,
wherein the binder comprises a cellulose polymer, an acrylic polymer, a styrene polymer, a polyvinyl resin, a methacrylic acid ester polymer, a styrene-acrylic acid ester copolymer, a polystyrene, a polyvinyl butyral, a polyvinyl alcohol, a polyethylene oxide, a polyacrylonitrile, a polypropylene carbonate, a polymethyl methacrylate, an ammonium acrylate polymer, an arabic gum, a gelatin, an alkyd resin, a butyral resin, a saturated polyester resin, a natural rubber, a silicone rubber, a fluorosilicone, a fluoroelastomer, a synthetic rubber, a copolymer thereof, or a combination thereof.

24. A method of preparing a composition for forming a heating element, the method comprising:
preparing a first solution having a pH in a range of about 11 or greater comprising a composite filler and a solvent;
adding an acid to the first solution to prepare a second solution having a pH in a range of about 5 to about 9; and
adding a matrix particle and a binder to the second solution and mixing the matrix particle and the binder with the second solution to prepare the composition for forming the heating element,
wherein the composite filler comprises a core and a coating layer disposed on the core, and
the core comprises a nanosheet,
the coating layer disposed on the core has a bilayer structure comprising a first polymer layer disposed on the nanosheet filler and a second polymer layer disposed on the first polymer layer, and
the composition further comprises an ionically charged coating layer disposed on a surface of the matrix particle.

25. The method of claim 24 , wherein the preparing of the first solution comprises adding one or more polymers to an alkaline

Assignees

• Samsung Electronics Co Ltd

Inventors

• Koh Haengdeog
• Kim Hajin
• Bae Minjong
• Kim Doyoon
• Kim Seyun
• Kim Jinhong
• Mizusaki Soichiro
• Lee Changsoo

Classifications

• H05B2214/04

  Heating means manufactured by using nanotechnology · CPC title

• H05B2203/013

  Heaters using resistive films or coatings · CPC title

• H05B3/20

  Heating elements having extended surface area substantially in a two-dimensional [2D] plane, e.g. plate-heater (H05B3/62, H05B3/68, H05B3/78, H05B3/84 take precedence) · CPC title

• H05B3/14 Primary

  the material being non-metallic · CPC title

• H01B1/14 Primary

  Conductive material dispersed in non-conductive inorganic material · CPC title