Permanent magnet, motor, and generator

Patent metadata

Field	Value
Publication number	US-10892091-B2
Application number	US-201715413598-A
Country	US
Kind code	B2
Filing date	Jan 24, 2017
Priority date	Mar 23, 2015
Publication date	Jan 12, 2021
Grant date	Jan 12, 2021

Abstract

A method of manufacturing a permanent magnet comprises a solution heat treatment. The solution heat treatment includes: performing a heat treatment at a temperature T ST ; placing a cooling member including a first layer and a second layer on the first layer between the heater and the treatment object so that the first layer faces the treatment object; and transferring the treatment object together with the cooling member to the outside of a heating chamber, and cooling the treatment object until a temperature of the treatment object becomes a temperature lower than a temperature T ST −200° C. In the step of cooling the treatment object, a cooling rate until the temperature of the treatment object becomes the temperature T ST −200° C. is 5° C./s or more.

First claim

What is claimed is:

1. A method of manufacturing a permanent magnet, comprising:
press-forming alloy powder in a magnetic field to fabricate a compression molded body, wherein a total weight of the compression molded body is not less than 200 g nor more than 2000 g;
sintering the compression molded body to fabricate a sintered body;
performing a solution heat treatment on the sintered body; and
performing an aging heat treatment on sintered body after the solution heat treatment,
wherein the solution heat treatment includes:
performing a heat treatment on a treatment object having the sintered body at a temperature T ST of 1100 to 1200° C. inside a heating chamber having a heater;
transferring a cooling member into the heating chamber after the heat treatment and placing the cooling member between the heater and the treatment object, the cooling member including a first layer and a second layer on the first layer, the first layer having a first thermal emissivity of 0.5 or more, the second layer having a second thermal emissivity lower of less than 0.5, the first layer containing carbon, a metal carbide, a metal oxide, or a refractory brick, the second layer containing copper, molybdenum, tungsten, titanium, or stainless steel, and the first layer being faced with the treatment object; and
transferring the treatment object together with the cooling member to the outside of the heating chamber, and cooling the treatment object until a temperature of the treatment object becomes a temperature lower than a temperature T ST −200° C.,

wherein in cooling the treatment object, a cooling rate until the temperature of the treatment object becomes the temperature T ST −200° C. is 5° C./s or more, wherein the cooling rate is achieved by a combination of absorbing, by the first layer, heat emitted by the treatment object and reflecting, by the second layer, heat emitted from the heater, and
wherein the permanent magnet is expressed by a composition formula:
R p Fe q M r Cu t Co 100-p-q-r-t ,

where R represents at least one element selected from the group consisting of rare earth elements, M represents at least one element selected from the group consisting of Zr, Ti, and Hf, p is a number satisfying 10.5≤p≤12.5 atomic percent, q is a number satisfying 27≤q≤40 atomic percent, r is a number satisfying 0.88≤r≤4.5 atomic percent, and t is a number satisfying 4.5≤t≤10.7 atomic percent.

2. The method according to claim 1 ,
wherein 50 atomic percent or more of the element R in the composition formula is Sm, and
wherein 50 atomic percent or more of the element M in the composition formula is Zr.

3. The method according to claim 1 ,
wherein the permanent magnet includes a metallic structure having a main phase having a Th 2 Zn 17 crystal phase and a grain boundary phase provided between crystal grains constituting the main phase, and
wherein the main phase has a cell phase having the Th 2 Zn 17 crystal phase and a Cu rich phase having a CaCu 5 crystal phase.

4. The method according to claim 1 ,
wherein the permanent magnet includes a metallic structure, 90 vol % or more of the metallic structure being the Th 2 Zn 17 crystal phase and the CaCu 5 crystal phase, and
wherein less than 5 vol % of the crystal grains is composed of crystal grains having a diameter of 300 nm or more and consisting of the Th 2 Zn 17 crystal phases.

Assignees

• Toshiba Kk

Inventors

• Sanada Naoyuki
• Sakurada Shinya
• Horiuchi Yosuke
• Hagiwara Masaya
• Endo Masaki
• Terada Takahiro
• Chikaoka Hideo

Classifications

• H02K1/02

  characterised by the magnetic material · CPC title

• H01F41/0253

  for manufacturing permanent magnets · CPC title

• H01F7/02

  Permanent magnets {[PM]} · CPC title

• H01F1/08

  pressed, sintered, or bound together · CPC title

• H01F1/053 Primary

  containing rare earth metals · CPC title