Lubricity additive for fuel with a low sulphur content

Patent metadata

Field	Value
Publication number	US-10889774-B2
Application number	US-201615756608-A
Country	US
Kind code	B2
Filing date	Sep 2, 2016
Priority date	Sep 3, 2015
Publication date	Jan 12, 2021
Grant date	Jan 12, 2021

Abstract

The invention relates to a lubricity additive for fuel, particularly for diesel fuel, directly obtained from the acidification of a soapstock produced by a method for refining at least one vegetable and/or animal oil. The lubricity additive according to the invention is more specifically used for fuels that have a low sulfur content, for example, lower than 500 ppm (by weight).

First claim

The invention claimed is:

1. A method of using one or more acid oils, directly derived from acidification of at least one soapstock, the method comprising adding the one or more acid oils to an internal combustion engine fuel as a lubricity additive in a content of less than or equal to 1000 ppm by weight, thus obtaining an internal combustion engine fuel composition,
wherein the soapstock is obtained by a process of refining at least one oil selected from a vegetable and/or animal oil,
the lubricity additive has a content of triglycerides of greater than or equal to 5% by weight.

2. The method according to claim 1 , wherein the lubricity additive has a content of free fatty acids of greater than or equal to 5% by weight.

3. The method according to claim 1 , wherein the lubricity additive has a content of fatty acids containing more than two unsaturations of less than or equal to 40% by weight.

4. The method according to claim 1 , wherein the lubricity additive has a content of C 18 : 1 and C 18 :2 fatty acids of greater than or equal to 40% by weight.

5. The method according to claim 1 , wherein the lubricity additive has a pour point of less than or equal to −3° C.

6. The method according to claim 1 , wherein the lubricity additive is directly derived from a process of acidifying at least one soapstock obtained by a process of refining at least one vegetable oil.

7. The method according to claim 1 , wherein the lubricity additive is directly obtained by an acidification process comprising:
a) a step of extracting fatty acids present in at least one soapstock derived from the refining of one or more oils selected from a vegetable oil and/or an animal oil, this extraction step being carried out in an acid medium under conditions effective for forming an aqueous phase and an organic phase comprising said fatty acids,
b) a separation step during which said previously formed organic phase is separated and recovered.

8. The method according to claim 7 , wherein the soapstock treated in step a) is obtained by a process of refining a vegetable and/or animal oil comprising:
a1) a step of saponifying a vegetable or animal oil or a mixture of vegetable and/or animal oils under conditions effective for saponifying the free fatty acids present in the oil or the mixture of oils and for forming a soapstock,
a2) a step of separating the oil or the mixture of oils and the soapstock formed during step a1).

9. The method according to claim 1 , wherein the internal combustion engine fuel composition has a sulphur content of less than 500 ppm.

Assignees

• Total Marketing Services

Inventors

• Ben Sahel Hakim
• Langlois Olivier
• Herou Julien
• Germanaud Laurent

Classifications

• C10L10/08 Primary

  for improving lubricity; for reducing wear · CPC title

• C10L1/1802 Primary

  natural products, e.g. waxes, extracts, fatty oils · CPC title

• Y02T50/678

  Aviation using fuels of non-fossil origin · CPC title

• C10L1/1881

  carboxylic group attached to an aliphatic carbon atom · CPC title

• C10L1/18

  containing oxygen · CPC title