Elastic diene terpolymer and preparation method thereof
US-2016289359-A1 · Oct 6, 2016 · US
US10889708B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10889708-B2 |
| Application number | US-201716324070-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 10, 2017 |
| Priority date | Aug 11, 2016 |
| Publication date | Jan 12, 2021 |
| Grant date | Jan 12, 2021 |
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Caps and closures comprising high density polyethylene, polyolefin elastomer and polypropylene wherein the amount of high density polyethylene is more than 50% by weight of the total amount of high density polyethylene, polyolefin elastomer and polypropylene and wherein the total amount of high density polyethylene, polyolefin elastomer and polypropylene is 100% by weight.
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The invention claimed is: 1. Caps and closures comprising: a high density polyethylene, a polyolefin elastomer, and a polypropylene wherein the amount of high density polyethylene is more than 50% by weight of the total amount of the high density polyethylene, the polyolefin elastomer and the polypropylene, wherein the total amount of high density polyethylene, polyolefin elastomer and polypropylene is 100% by weight, and wherein the polyolefin elastomer is an ethylene-alpha olefin copolymer derived from two monomers consisting of ethylene and an alpha olefin containing 4-10 carbon atoms. 2. The caps and closures according to claim 1 , comprising the high density polyethylene in a range between ≥52% by weight and ≤100% by weight. 3. The caps and closures according to claim 1 , comprising the polypropylene in a range between >0.1% by weight and ≤40% by weight. 4. The caps and closures according to claim 1 , comprising the polyolefin elastomer in a range between >0.1% by weight and ≤40% by weight. 5. The caps and closures according to claim 1 , comprising the high density polyethylene in a range between >50% by weight and <100% by weight and the polypropylene in a range between >0.1% by weight and ≤40% by weight and the polyolefin elastomer in a range between >0.1% by weight and ≤40% by weight. 6. The caps and closures according to claim 1 , comprising the high density polyethylene in a range between >55% by weight and <100% by weight and the polypropylene in a range between ≥5% by weight and ≤35% by weight and the polyolefin elastomer in a range between ≥2% by weight and ≤20% by weight. 7. The caps and closures according to claim 1 , comprising the high density polyethylene in a range between ≥55% by weight and <80% by weight and the polypropylene in a range between ≥10% by weight and ≤30% by weight and the polyolefin elastomer in a range between ≥5% by weight and ≤20% by weight. 8. The caps and closures according to claim 1 , wherein an MFI of the high density polyethylene ranges between ≥0.1 and ≤30 g/10 min (measured according to ISO 1133 at 190 degrees Celsius and 2.16 kg) and/or a density of the high density polyethylene ranges between ≥950 and ≤958 kg/m 3 (measured according to ISO 1183). 9. The caps and closures according to claim 1 , wherein an MFI of the high density polyethylene ranges between ≥0.6 and ≤15 g/10 min (measured according to ISO 1133 at 190 degrees Celsius and 2.16 kg) and/or a density of the high density polyethylene ranges between >950 and <955 kg/m 3 (measured according to ISO 1183). 10. The caps and closures according to claim 1 , wherein an MFI of polypropylene ranges between 0.3 and 100 g/10 min (measured according to ISO1133 at 230 degrees Celsius and 2.16 kg) and/or a density of polypropylene ranges between ≥900 and ≤920 kg/m 3 (measured according to ISO 1183). 11. The caps and closures according to claim 1 , wherein an MFI of the polypropylene ranges between 0.3 and 10 g/10 min (MFI is determined according to ISO 1133 at 230 degrees Celsius and 2.16 kg) and/or a density of the polypropylene ranges between >902 and <906 kg/m 3 (measured according to ISO 1183). 12. The caps and closures according to claim 1 , wherein an MFI of the polyolefin elastomer ranges between ≥0.5 and ≤30 g/10 min (measured according to ASTM D1238 at 190 degrees Celsius and 2.16 kg) and/or a density of the polyolefin elastomer ranges between ≥857 and ≤880 kg/m 3 (measured according to ASTM D1505). 13. The caps and closures according to claim 1 , wherein the ethylene-alpha olefin copolymer is ethylene-octene copolymer. 14. The caps and closures according to claim 1 , wherein the polypropylene is impact polypropylene. 15. The caps and closures according to claim 1 , wherein an amount of high density polyethylene is higher than an amount of the polypropylene and wherein this is based on the wt % of the high density polyethylene and the wt % of the polypropylene and/or the amount of the polypropylene is higher than the amount of the polyolefin elastomer and wherein this is based on the wt % of the polypropylene and the wt % of the polyolefin elastomer. 16. The caps and closures according to claim 1 , wherein an MFI of the polyolefin elastomer ranges between ≥0.6 and ≤10 g/10 min (measured according to ASTM D1238 at 190 degrees Celsius and 2.16 kg) and/or a density of the polyolefin elastomer ranges between ≥865 and ≤870 kg/m 3 (measured according to ASTM D1505). 17. The caps and closures according to claim 1 , wherein an MFI of the polyolefin elastomer ranges between ≥0.6 and ≤10 g/10 min (measured according to ASTM D1238 at 190 degrees Celsius and 2.16 kg) and a density of the polyolefin elastomer ranges between ≥865 and ≤870 kg/m 3 (measured according to ASTM D1505). 18. The caps and closures according to claim 1 , comprising the high density polyethylene in a range between ≥55% by weight and ≤70% by weight; the polypropylene in a range between >5% by weight and <35% by weight; and the polyolefin elastomer in a range between ≥2% by weight and ≤20% by weight. 19. The caps and closures according to claim 18 , comprising the polypropylene in a range between >10% by weight and <30% by weight; and the polyolefin elastomer in a range between ≥5% by weight and ≤20% by weight. 20. Caps and closures comprising: a high density polyethylene in a range between >55% by weight and <80% by weight, a polyolefin elastomer in a range between ≥5% by weight and ≤20% by weight, and a polypropylene in a range between ≥10% by weight and ≤30% by weight, each based on the total amount of the high density polyethylene, the polyolefin elastomer and the polypropylene, wherein the total amount of high density polyethylene, polyolefin elastomer and polypropylene is 100% by weight, and wherein the polyolefin elastomer is ethylene-octene copolymer.
Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper (clamping or other pressure-applying devices for securing or retaining closure members B65D45/00) · CPC title
Polyethylene · CPC title
Low density, i.e. < 0.91 g/cm3 · CPC title
Propene · CPC title
at least partially crystalline copolymers of propene with other olefins · CPC title
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