Tow prepreg, composite material-reinforced pressure vessel, and method of producing composite material-reinforced pressure vessel

Patent metadata

Field	Value
Publication number	US-10889695-B2
Application number	US-201815986963-A
Country	US
Kind code	B2
Filing date	May 23, 2018
Priority date	Dec 10, 2015
Publication date	Jan 12, 2021
Grant date	Jan 12, 2021

Abstract

Provided are a tow prepreg comprising a reinforcing fiber bundle impregnated with a matrix resin composition, wherein the matrix resin composition contains a component (A) (an epoxy resin), a component (B) (dicyandiamide), a component (C) (a curing accelerator), and a component (D) (a core-shell type rubber particle), and a content of the component (D) with respect to 100 parts by mass of the component (A) is from 20 to 70 parts by mass, a viscosity is from 3 Pa·s to 80 Pa·s at 30° C., and a minimum viscosity to be obtained when a viscosity is measured by raising a temperature from room temperature to 130° C. at a rate of temperature rise of 2.0° C./min is from 0.04 Pa·s to 1 Pa·s, which exhibits excellent drape property and tackiness and less stickiness and can be unwound at a high speed; and a composite material-reinforced pressure vessel having fewer voids in a reinforcing layer which is obtainable by using the tow prepreg, a high burst pressure, and an excellent appearance due to appropriate resin flow.

First claim

The invention claimed is:

1. A tow prepreg comprising a reinforcing fiber bundle impregnated with a matrix resin composition, wherein
the matrix resin composition contains a component (A), a component (B), a component (C), and a component (D), wherein
the component (A) is an epoxy resin, the component (B) is dicyandiamide, the component (C) is a curing accelerator, and the component (D) is a core-shell rubber particle and
a content of the component (D) with respect to 100 parts by mass of the component (A) is from 22.7 to 70 parts by mass,
a viscosity of the matrix resin composition is from 3 Pas to 80 Pa·s at 30° C., and
a minimum viscosity to be obtained when a viscosity of the matrix resin composition is measured by raising a temperature from room temperature to 130° C. at a rate of temperature rise of 2.0° C./min is from 0.04 Pa·s to 1 Pa·s.

2. The tow prepreg according to claim 1 , wherein the component (A) contains a component (A1-1) and a component (A2), wherein
the component (A1-1) is a bifunctional epoxy resin which is liquid at 25° C. and has one or more aromatic ring in the molecule and
the component (A2) is a bifunctional epoxy resin which has a viscosity of 15 Pa·s or less at 25° C. and does not have an aromatic ring in the molecule.

3. The tow prepreg according to claim 2 , wherein the component (A2) is a component (A2-1), wherein
the component (A2-1) is a bifunctional epoxy resin which has a viscosity of 15 Pa·s or less at 25° C. and does not have an aromatic ring in the molecule but has one or more alicyclic structure in the molecule.

4. The tow prepreg according to claim 3 , wherein a content of the component (A2-1) in the component (A) is from 2 to 80 parts by mass with respect to 100 parts by mass of the component (A).

5. The tow prepreg according to claim 1 , wherein the matrix resin composition has a curing completion time of shorter than 360 minutes at 100° C. when the curing completion time is measured using a curelastometer.

6. The tow prepreg according to claim 1 , wherein a total content of the component (B) and the component (C) with respect to 100 parts by mass of the component (A) is from 2 to 12 parts by mass.

7. The tow prepreg according to claim 1 , wherein a content of the component (C) with respect to 100 parts by mass of the component (A) is from 0.1 to 10 parts by mass.

8. The tow prepreg according to claim 1 , wherein the component (C) is a urea derivative or an imidazole derivative.

9. The tow prepreg according to claim 1 , wherein the reinforcing fiber bundle is a carbon fiber bundle.

10. A composite material-reinforced pressure vessel comprising:
a metal liner or a resin liner; and
a reinforcing layer disposed so as to cover a part or the whole of a surface of the metal liner or the resin liner, wherein
the reinforcing layer is a cured product of the tow prepreg according to claim 1 .

11. A method of producing a composite material-reinforced pressure vessel, the method comprising:
winding the tow prepreg according to claim 1 onto a rotating metal liner or resin liner to fabricate a pressure vessel intermediate body; and
heating the pressure vessel intermediate body to cure the matrix resin composition contained in the tow prepreg.

12. The tow prepreg according to claim 1 , wherein a content of the component (D) with respect to 100 parts by mass of the component (A) is from 30 to 45 parts by mass.

13. A method of producing a composite material-reinforced pressure vessel, the method comprising:
preparing a matrix resin composition which contains a component (A), a component (B), a component (C), and a component (D), wherein the component (A) is an epoxy resin, the component (B) is dicyandiamide, the component (C) is a curing accelerator, and the component (D) is a core-shell rubber particle and a content of the component (D) with respect to 100 parts by mass of the component (A) is from 22.7 to 70 parts by mass and has a viscosity of from 3 Pa·s to 80 Pa·s at 30° C. and a minimum viscosity of from 0.04 Pa·s to 1 Pa·s to be obtained when a viscosity of the matrix resin composition is measured by raising a temperature from room temperature to 130° C. at a rate of temperature rise of 2.0° C./min;
impregnating a reinforcing fiber bundle with the matrix resin composition to fabricate a resin-impregnated reinforcing fiber bundle;
winding the resin-impregnated reinforcing fiber bundle onto a rotating metal liner or resin liner to fabricate a pressure vessel intermediate body; and
heating the pressure vessel intermediate body to cure the matrix resin composition contained in the resin-impregnated reinforcing fiber bundle.

14. The method according to claim 13 , wherein a content of the component (D) with respect to 100 parts by mass of the component (A) is from 30 to 45 parts by mass.

Assignees

• Mitsubishi Chem Corp

Inventors

• Okamoto Satoshi
• Harada Yukihiro

Classifications

• Y02E60/32

  Hydrogen storage · CPC title

• F17C1/02 Primary

  involving reinforcing arrangements {(F17C1/14, F17C1/16 take precedence)} · CPC title

• C08J5/249

  characterised by the additives used in the prepolymer mixture · CPC title

• C08J5/243 Primary

  using carbon fibres · CPC title

• B29C70/32

  on a rotating mould, former or core · CPC title