Process and apparatus for separating ethylene

Patent metadata

Field	Value
Publication number	US-10889535-B2
Application number	US-201716613752-A
Country	US
Kind code	B2
Filing date	Nov 21, 2017
Priority date	Jun 8, 2017
Publication date	Jan 12, 2021
Grant date	Jan 12, 2021

Abstract

The present invention provides an ethylene separation process comprising an first and second deethanizer columns and an acetylene converter, thereby providing an ethylene stream having a purity of 99 wt % or more to the middle of an ethylene separation column. The present invention increases the production amount of ethylene and also reduces energy consumption by passing the feed through a preliminary ethylene separation process, without having to change existing facilities in which an acetylene converter is provided downstream of the deethanizer column.

First claim

What is claimed is:

1. A process for separating ethylene from a feed stream comprising an initial C2 stream comprising acetylene, ethane and ethylene and a C3 stream comprising propylene, the process comprising the steps of:
feeding the feed stream comprising the initial C2 stream and the C3 stream into a first deethanizer column to discharge a first C2 stream from a top of the first deethanizer column and the C3 stream from a bottom of the first deethanizer column;
feeding a portion of the first C2 stream discharged from the top of the first deethanizer column into a second deethanizer column and discharging a second C2 stream from a top of the second deethanizer column;
introducing a downstream discharge of the second deethanizer column into the first deethanizer column again to reflux the first deethanizer column;
supplying the second C2 stream into a first acetylene converter to convert acetylene contained in the second C2 stream into ethylene and discharging a first ethylene stream from the first acetylene converter;
supplying a remaining portion of the first C2 stream discharged from the top of the first deethanizer column to a second acetylene converter to convert acetylene contained in the remaining portion of the first C2 stream into ethylene and discharging a second ethylene stream from the second acetylene converter; and
feeding the first ethylene stream and the second ethylene stream into an ethylene separation column to obtain ethylene.

2. The process according to claim 1 , wherein the first ethylene stream is fed to a middle of the ethylene separation column and the second ethylene stream is fed to a bottom of the ethylene separation column.

3. The ethylene separation process according to claim 1 , wherein the first C2 stream discharged from the top of the first deethanizer column has an ethylene purity of 65 wt % to 85 wt %.

4. The process according to claim 1 , wherein an ethylene purity of the second C2 stream discharged from the second deethanizer column is 96 wt % to 99 wt %, and wherein an ethylene purity of the first ethylene stream after passing through the first acetylene converter is 97 wt % or more.

5. The process according to claim 1 , wherein the second ethylene stream after passing through the second acetylene converter has an ethylene purity of 65 wt % to 85 wt %.

6. The process according to claim 1 , wherein the second deethanizer column has a number of stages between 30 and 100.

7. The ethylene separation process according to claim 1 , wherein the ethylene separation column has a number of stages between 150 and 200, wherein the first ethylene stream is fed to the ethylene separation column from stage 50 to stage 110 of the ethylene separation column, and wherein the second ethylene stream is fed to the ethylene separation column at a state that is 30 to 100 lower than the first ethylene stream.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Tae Woo
• Lee Sung Kyu
• Shin Joon Ho
• Choo Yeonuk

Classifications

• C07C7/005 Primary

  Processes comprising at least two steps in series · CPC title

• C07C7/04

  by distillation · CPC title

• C07C5/08 Primary

  of carbon-to-carbon triple bonds · CPC title

• C07C11/04

  Ethene · CPC title

• C07C7/167

  for removal of compounds containing a triple carbon-to-carbon bond · CPC title