Tire object provided with an elastomer layer made of a thermoplastic elastomer in the form of an (A-b-(a-methylstyrene-co-B))n-b-C block copolymer

Patent metadata

Field	Value
Publication number	US-10889146-B2
Application number	US-201615556169-A
Country	US
Kind code	B2
Filing date	Mar 8, 2016
Priority date	Mar 9, 2015
Publication date	Jan 12, 2021
Grant date	Jan 12, 2021

Abstract

A pneumatic object is provided with an elastomer layer which is gastight to inflation gases, said elastomer layer comprising, as predominant elastomer, a thermoplastic elastomer in the form of a block copolymer which comprises: (a) an elastomeric block comprising at least units derived from isobutylene, and having a glass transition temperature of less than or equal to −20° C., and (b) one or more thermoplastic blocks, the thermoplastic block(s) each comprising at least one first block consisting of units derived from at least one polymerizable monomer and at least one second block, said second block(s) being a random copolymer consisting of units derived from α-methylstyrene and of units derived from β-pinene. A process for rendering a pneumatic object gastight to inflation gases is also disclosed.

First claim

The invention claimed is:

1. A pneumatic object provided with an elastomer layer which is gastight to inflation gases, said elastomer layer comprising, as predominant elastomer, a thermoplastic elastomer in the form of a block copolymer which comprises:
(a) an elastomeric block comprising at least units derived from isobutylene, and having a glass transition temperature of less than or equal to −20° C., and
(b) one or more thermoplastic blocks, the one or more thermoplastic blocks each comprising at least one first block consisting of units derived from at least one polymerizable monomer and at least one second block, said at least one second block being a random copolymer consisting of units derived from α-methylstyrene and of units derived from β-pinene,
wherein a content of units derived from β-pinene ranges from 0.5 to 25 mol % relative to the number of moles of units of the block copolymer.

2. The pneumatic object according to claim 1 , wherein the block copolymer has a structure in which the elastomeric block is connected at one of its ends to a thermoplastic block.

3. The pneumatic object according to claim 1 , wherein the block copolymer has a linear structure in which the elastomeric block is connected at each of its ends to a thermoplastic block.

4. The pneumatic object according to claim 1 , wherein the block copolymer has a star-branched structure, the elastomeric block being central and being connected to 3 to 12 branches, each branch consisting of a thermoplastic block.

5. The pneumatic object according to claim 1 , wherein the at least one polymerizable monomer is selected from styrene monomers.

6. The pneumatic object according to claim 5 , wherein the at least one polymerizable monomer is styrene.

7. The pneumatic object according to claim 1 , wherein the block copolymer has a weight-average molecular weight ranging from 30 to 300 kg/mol.

8. The pneumatic object according to claim 7 , wherein the block copolymer has a weight-average molecular weight ranging from 120 to 250 kg/mol.

9. The pneumatic object according to claim 1 , wherein the content of units derived from β-pinene ranges from 0.8 to 5 mol % relative to the number of moles of units of the block copolymer.

10. The pneumatic object according to claim 1 , wherein the one or more thermoplastic blocks represent from 5 to 30% by weight relative to the total weight of the block copolymer.

11. The pneumatic object according to claim 10 , wherein the one or more thermoplastic blocks represent from 10 to 20% by weight relative to the total weight of the block copolymer.

12. The pneumatic object according to claim 1 , wherein the elastomeric block has a glass transition temperature of less than or equal to −40° C.

13. The pneumatic object according to claim 12 , wherein the elastomeric block has a glass transition temperature of less than or equal to −50° C.

14. The pneumatic object according to claim 1 , wherein the elastomeric block comprises from 0.5 to 6% by weight of units derived from one or more conjugated dienes relative to the total weight of the elastomeric block.

15. The pneumatic object according to claim 14 , wherein the elastomeric block comprises from 1.5 to 5% by weight of units derived from one or more conjugated dienes relative to the total weight of the elastomeric block.

16. The pneumatic object according to claim 15 , wherein the one or more conjugated dienes are selected from the group consisting of isoprene, 1,3-butadiene, 1-methylbutadiene, 2-methylbutadiene, 2,3-dimethyl-1,3-butadiene, 2,4-dimethyl-1,3-butadiene, 1,3-pentadiene, 2-methyl-1,3-pentadiene, 3-methyl-1,3-pentadiene, 4-methyl-1,3-pentadiene, 2,3-dimethyl-1,3-pentadiene, 1,3-hexadiene, 2-methyl-1,3-hexadiene, 3-methyl-1,3-hexadiene, 4-methyl-1,3-hexadiene, 5-methyl-1,3-hexadiene, 2,3-dimethyl-1,3-hexadiene, 2,4-dimethyl-1,3-hexadiene, 2,5-dimethyl-1,3-hexadiene, 2-neopentylbutadiene, 1,3-cyclopentadiene, 1,3-cyclohexadiene, 1-vinyl-1,3-cyclohexadiene, and mixtures thereof.

17. The pneumatic object according to claim 1 , wherein the elastomer layer which is gastight to inflation gases further comprises an extending oil.

18. The pneumatic object according to claim 17 , wherein the extending oil is selected from the group consisting of polyolefinic oils, paraffinic oils, naphthenic oils, aromatic oils, mineral oils and mixtures thereof.

19. The pneumatic object according to claim 18 , wherein the extending oil is selected from olefinic oils.

20. The pneumatic object according to claim 19 , wherein the extending oil is a polyisobutylene oil.

21. The pneumatic object according to claim 17 , wherein the extending oil has a number-average molar mass ranging from 350 to 4000 g/mol.

22. The pneumatic object according to claim 21 , wherein the extending oil has a number-average molar mass ranging from 400 to 3000 g/mol.

23. The pneumatic object according to claim 17 , wherein the extending oil has a content of greater than 5 phr.

24. The pneumatic object according to claim 23 , wherein the extending oil has a content between 5 and 100 phr.

25. The pneumatic object according to claim 1 , wherein the elastomer layer has a thickness of greater than or equal to 0.05 mm.

26. The pneumatic object according to claim 25 , wherein the elastomer layer has a thickness ranging from 0.1 to 10 mm.

27. The pneumatic object according to claim 26 , wherein the elastomer layer has a thickness ranging from 0.1 to 2 mm.

28. The pneumatic object according to claim 1 , wherein the elastomer layer is arranged on the inner wall of the pneumatic object.

29. The pneumatic object according to claim 1 , wherein the pneumatic object is a pneumatic tire.

30. A process for rendering a pneumatic object gastight to inflation gases comprising the step of:
incorporating the elastomer layer which is gastight to inflation gases into the pneumatic object according to claim 1 during the manufacture of the pneumatic object or after the manufacture of the pneumatic object.

31. The process according to claim 30 , wherein the elastomer layer is arranged on the inner wall of the pneumatic object.

32. The process according to claim 30 , wherein the pneumatic object is a pneumatic tire.

33. The process according to claim 32 , wherein the incorporating step includes depositing the elastomer layer on a tire-building drum before covering said elastomer layer a remainder of the structure of the pneumatic tire.

Assignees

• Michelin & Cie

Inventors

• Greiveldinger Marc
• Custodero Emmanuel

Classifications

• C08L53/00

  Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers · CPC title

• B60C5/14

  with impervious liner or coating on the inner wall of the tyre · CPC title

• B60C1/0008 Primary

  Compositions of the inner liner · CPC title

• C08F297/00

  Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer · CPC title

• C08L2201/14

  Gas barrier composition · CPC title