Process for producing microfibrillated cellulose and a product thereof

Patent metadata

Field	Value
Publication number	US-10883226-B2
Application number	US-201616074562-A
Country	US
Kind code	B2
Filing date	Dec 22, 2016
Priority date	Feb 3, 2016
Publication date	Jan 5, 2021
Grant date	Jan 5, 2021

Abstract

The present invention relates to a method of producing microfibrillated cellu-lose (MFC) comprising (i) providing cellulosic material, (ii) drying the cellulosic material so that specific surface area (SSA), when measured with BET-method, is at most 10 m2/g, and (iii) subjecting the dried cellulosic material to mechanical treatment. The present invention additionally relates to microfibril-lated cellulose produced with the method of the present invention.

First claim

The invention claimed is:

1. A method of producing microfibrillated cellulose (MFC) comprising:
(i) providing a cellulosic material, which is microcrystalline cellulose,
(ii) drying the cellulosic material by spray drying, flash drying, fluid bed drying or rotary drum drying, wherein the drying time is less than 5 minutes, until a specific surface area (SSA), when measured with Brunauer-Emmett-Teller (BET)-method, of the cellulosic material is at most 10 m 2 /g, and a size of the dried cellulosic material is less than 50 μm, and
(iii) subjecting the dried cellulosic material to mechanical treatment, which refines the cellulosic material to microfibrillated cellulose.

2. The method according to claim 1 , wherein the cellulosic material is dried by bringing it in contact with heated gas.

3. The method according to claim 2 , wherein the heated gas is air, an inert gas, or steam.

4. The method according to claim 1 , wherein drying time is from 1 s to 60 s.

5. The method of claim 4 , wherein the drying time is 5-30s.

6. The method according to claim 1 , wherein the drying is spray drying and inlet temperature in the spray drying is from 200° C. to 450° C., and outlet temperature from 50° C. to 150° C.

7. The method according to claim 1 , wherein water content of the dried cellulosic material is from 1 wt. % to 20 wt. %.

8. The method of claim 7 wherein water content of the dried cellulosic material is from 2 wt. % to 15 wt. %.

9. The method according to claim 1 , wherein the dried cellulosic material is fed to the mechanical treatment at a feed consistency of from 1 wt. % to 70 wt. % in dry solids content.

10. The method according to claim 1 , wherein the mechanical treatment is selected from fibrillation in a grinder, comminutor, extruder, rotor-stator mixer or grinder, rotor-rotor mixer or grinder, high-shear rate grinder, dispersionizers, homogenizer, fluidizer or ultrasonic disintegrator.

11. The method according to claim 1 , wherein the mechanical treatment is conducted by a homogenizer or a fluidizer.

12. The method according to claim 11 , wherein pressure in the homogenizer or in the fluidizer is from 200 bar to 2100 bar.

13. The method according to claim 11 , wherein the dried cellulosic material is passed through the homogenizer or fluidizer from 1 to 5 pass(es).

14. The method according to claim 1 , wherein the inlet temperature in the spray drying is from 250° C. to 400° C., and outlet temperature from 60° C. to 120.

Assignees

• Kemira Oyj

Inventors

• Vanhatalo Kari
• Lundin Tom
• Lillandt Marcus

Classifications

• D21B1/04

  by dividing raw materials into small particles, e.g. fibres (breaking-up or cutting wood or the like by dry methods B27L; mechanical separation of fibres from plant material D01B1/00; hackling or heckling machines D01B5/00) · CPC title

• C08L1/02

  Cellulose; Modified cellulose · CPC title

• D21B1/06 Primary

  by dry methods · CPC title

• C08B15/02

  Oxycellulose; Hydrocellulose; {Cellulosehydrate, e.g. microcrystalline cellulose} · CPC title

• D21H11/18 Primary

  Highly hydrated, swollen or fibrillatable fibres · CPC title