Electrochemical reaction device

Patent metadata

Field	Value
Publication number	US-10883180-B2
Application number	US-201815915390-A
Country	US
Kind code	B2
Filing date	Mar 8, 2018
Priority date	Sep 20, 2017
Publication date	Jan 5, 2021
Grant date	Jan 5, 2021

Abstract

An electrochemical reaction device, comprises: an anode to oxidize a first substance; a first flow path facing on the anode and through which a liquid containing the first substance flows; a cathode to reduce a second substance; a second flow path facing on the cathode and through which a gas containing the second substance flows; a porous separator provided between the anode and the cathode; and a power supply connected to the anode and the cathode. A thickness of the porous separator is 1 μm or more and 500 μm or less. An average fine pore size of the porous separator is larger than 0.008 μm and smaller than 0.45 μm. A porosity of the porous separator is higher than 0.5.

First claim

What is claimed is:

1. An electrochemical reaction device, comprising:
an anode to oxidize a first substance;
a first flow path facing the anode and through which a liquid containing the first substance flows;
a cathode to reduce a second substance;
a second flow path facing the cathode and through which a gas containing the second substance flows; and
a porous separator provided between the anode and the cathode,
wherein a thickness of the porous separator is 1 μm or more and 500 μm or less,
an average fine pore size of the porous separator is larger than 0.008 μm and smaller than 0.45 μm, and
a porosity of the porous separator is higher than 0.5,
wherein the cathode includes:
a porous conductive layer having a first surface and a second surface; and
a reduction catalyst layer having a third surface on the first surface and containing a reduction catalyst configured to reduce the second substance,
wherein an area of the second surface is larger than an area of the third surface,
wherein the second flow path faces the second surface,
wherein the porous conductive layer has water repellency, and
wherein the porous separator is hydrophilic.

2. The device according to claim 1 , wherein a coefficient of permeability of the porous separator is 1.7×10 −20 m 2 or more and 1.7×10 −16 m 2 or less.

3. The device according to claim 1 , wherein the porosity is 0.7 or more.

4. The device according to claim 1 , wherein the liquid contains water, and
the gas contains carbon dioxide.

5. The device according to claim 1 , wherein the porous separator contains polytetrafluoroethylene.

6. The device according to claim 1 , wherein the porous separator contains hydrophilic polytetrafluoroethylene.

7. The device according to claim 1 , wherein the porous separator has a first face facing the anode and a second face facing the cathode,
a pressure gradient ∇P between the first and second faces is represented by
a formula: ∇P=−μ×Q×180(1−ε 3 )/d m 2 ×ε 3 ×A,
the μ represents a coefficient of viscosity of the liquid passing through the porous separator,
the Q represents a volume flow rate of the liquid passing through the porous separator,
the ε represents a porosity of the porous separator,
the d m represents an average fine pore size of the porous separator,
the A represents a sectional area of the porous separator, and
the ∇P is larger than 1 kPa/m and smaller than 2000 kPa/m.

8. The device according to claim 7 , wherein the ∇P is 2 kPa/m or more and 200 kPa/m or less.

9. The device according to claim 1 , wherein a product of the thickness and the average fine pore size 0.1 μm 2 or more and 6 μm 2 or less.

10. The device according to claim 9 , wherein the average fine pore size is 0.1 μm or more.

11. The device according to claim 9 , wherein the thickness is 100 μm or less.

12. The device according to claim 1 , further comprising:
a first flow path layer having an inlet and an outlet; and
a second flow path layer provided between the first flow path layer and the cathode and having a first region and a second region, the first region being apart from the first flow path layer, the second region being bent so as to protrude toward the first flow path layer from the first region, the second region having a first opening communicating with the inlet and a second opening communicating with the outlet,
wherein the cathode and the second region define the second flow path therebetween.

13. An electrochemical reaction device, comprising:
a first anode to oxidize a first substance;
a first flow path facing the first anode and through which a liquid containing the first substance flows;
a first cathode to reduce a second substance;
a second flow path facing the first cathode and through which a gas containing the second substance flows; and
a first porous separator provided between the first anode and the first cathode,
a second anode to oxidize the first substance;
a third flow path facing the second anode and through which the liquid flows;
a second cathode to reduce the second substance;
a fourth flow path facing the second cathode and through which the gas flows;
a second porous separator provided between the second anode and the second cathode;
a first flow path layer having an inlet and an outlet;
a second flow path layer provided between the first cathode and the first flow path layer and having a first region and a second region, the first region being apart from the first flow path layer, the second region being bent so as to protrude toward the first flow path layer from the first region, the second region having a first opening communicating with the inlet and a second opening communicating with the outlet, and the first region having a third opening through the second flow path layer; and
a third flow path layer provided between the first anode and the second cathode and having a third region and a fourth region, the third region being apart from the first anode, and the fourth region being bent so as to protrude toward the first anode from the third region, the third region having a fourth opening through the third flow path layer, and the fourth region having a fifth opening through the third flow path layer,
wherein:
the third region and the second cathode define the first flow path therebetween;
the first cathode and the second region define the second flow path therebetween;
a thickness of the first porous separator is 1 μm or more and 500 μm or less;
a average fine pore size of the first porous separator is larger than 0.008 μm and smaller than 0.45 μm;
a porosity of the first porous separator is higher than 0.5.

14. An electrochemical reaction device, comprising:
an anode to oxidize a first substance;
a first flow path facing the anode and through which a liquid containing the first substance flows;
a cathode to reduce a second substance;
a second flow path facing the cathode and through which a gas containing the second substance flows;
a first flow path layer having an inlet and an outlet;
a second flow path layer provided between the first flow path layer and the cathode and having a first region and a second region, the first region being apart from the first flow path layer, the second region being bent so as to protrude toward the first flow path layer from the first region, the second region having a first opening communicating with the inlet and a second opening communicating with the outlet; and
a porous separator provided between the anode and the cathode,
wherein the cathode and the second region define the second flow path therebetween,
wherein a thickness of the porous separator is 1 μm or more and 500 μm or less,
an average fine pore size of the porous separator is larger than 0.008 μm and smaller than 0.45 μm, and
a porosity of the porous separator is higher than 0.5.

15. The device according to claim 14 ,
wherein the cathode includes:
a porous conductive layer having a first surface and a second surface; and
a reduction catalyst layer having a third surface on the first surface and containing a reduction catalyst configured to reduce the second substance, and

wherein the second flow path faces the second surface, and
wherein an area of the second surface is larger than an area of the third surface.

Assignees

• Toshiba Kk

Inventors

• Ono Akihiko
• Hongo Takuya
• Yamagiwa Masakazu
• Kudo Yuki
• Mikoshiba Satoshi
• Yoshinaga Norihiro
• Kanai Yuta
• Tamura Jun

Classifications

• H01M50/426

  Fluorocarbon polymers · CPC title

• H01M50/491

  Porosity · CPC title

• H01M50/489

  Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties · CPC title

• C25B11/02

  characterised by shape or form · CPC title

• C25B1/04 Primary

  by electrolysis of water · CPC title