Resin blend

Patent metadata

Field	Value
Publication number	US-10882989-B2
Application number	US-201414904930-A
Country	US
Kind code	B2
Filing date	Jul 15, 2014
Priority date	Jul 15, 2013
Publication date	Jan 5, 2021
Grant date	Jan 5, 2021

Abstract

Provided are a resin blend, a copolymer, a pellet, a method of manufacturing a resin molded article using the same, and a resin molded article. The exemplary resin blend may provide a protective film for a polarizing plate having an excellent adhesive strength to a polarizer. In addition, when the resin blend is used, additional primer coating on the protective film for a polarizing plate may be omitted, and an excellent adhesive strength to the polarizer may be exhibited, thereby reducing production time and cost and increasing productivity.

First claim

The invention claimed is:

1. A resin blend, comprising:
a first resin; and
a second resin of an acryl polymer having a difference in a surface energy, melt viscosity or solubility parameter from the first resin,
wherein the first resin is a polymer of a first monomer blend consisting of 85 to 98 parts by weight of an alkyl(meth)acrylate having an alkyl group having 1 to 14 carbon atoms; 1 to 5 parts by weight of the monomer of Formula 1; and 3 to 10 parts by weight of the monomer of Formula 2, based on 100 parts by weight of the first monomer blend,
wherein the second resin is a polymer of a second monomer blend consisting of 70 to 95 parts by weight of an alkyl(meth)acrylate having an alkyl group having 1 to 14 carbon atoms; and 5 to 30 parts by weight of the monomer of Formula 1, wherein the monomer of Formula 1 is a styrene substituted by at least one substituent, based on 100 parts by weight of the second monomer blend,
wherein the second resin is hydrophobic compared to the first resin,
wherein the second resin has a difference in melt viscosity form the first resin of 0.1 to 3000 pa*s at a shear rate of 100 to 1000 s −1 and a processing temperature of the resin blend,
wherein the second resin is included at 0.1 to 20 parts by weight with respect to 100 parts by weight of the first resin,
wherein the second resin has a difference in surface energy of 0.1 to 35 mN/m at 25° C. from the first resin,
wherein the second resin has a difference in melt viscosity of 0.1 to 3,000 Pa·s from the first resin at a shear rate of 100 to 1,000 s −1 and a processing temperature of the resin blend,
wherein the second resin has a difference in solubility parameter from the solubility parameter from the first resin of 0.001 to 10.0 (J/cm 3 ) 1/2 at 25° C., and
wherein the second resin has a polydispersity index of 1 to 2.5 and a weight average molecular weight of 5,000 to 200,000:

where R 1 is hydrogen or an alkyl group having 1 to 4 carbon atoms,
Ar is phenyl, and
R 2 is hydrogen or —X—R 6 in which —X— is —O— or —OC(O), and R 6 is an alkyl group having 1 to 4 carbon atoms,
wherein in the second resin the styrene substituted by at least one substituent is the monomer of Formula 1 in which R 2 is —X—R 6 ,

where Y is oxygen or NR 10 , and R 10 is hydrogen, an alkyl group having 1 to 12 carbon atoms or a cycloalkyl group having 3 to 8 carbon atoms.

2. The resin blend according to claim 1 , wherein, in the first resin, the monomer of Formula 1 is styrene or α-methyl styrene, and the monomer of Formula 2 is cyclohexyl maleimide or maleic acid anhydride.

3. The resin blend according to claim 1 , wherein R 1 is hydrogen or an alkyl-group having 1 to 4 carbon atoms,
Ar is phenyl, and
R 2 is hydrogen or —X—R 6 in which —X— is —O— or —OC(O), and —R 6 is a methyl group or an ethyl group.

4. The resin blend according to claim 1 , wherein, in the second resin, the monomer of Formula 1 is an unsubstituted styrene and a styrene substituted by at least one substituent selected from the group consisting of methyl, methoxy, ethoxy and acetoxy.

Assignees

• Lg Chemical Ltd

Inventors

• Lee Jong Won
• Lee Han Na
• Ryu Jin Young
• Kim Woo Sung
• Choi Eun Joo
• Choi Hyeon

Classifications

• C08F212/22

  Oxygen · CPC title

• C08F220/14

  Methyl esters {, e.g. methyl (meth)acrylate} · CPC title

• C08L33/12 Primary

  Homopolymers or copolymers of methyl methacrylate · CPC title

• C08L25/06

  Polystyrene · CPC title

• C08L33/08 Primary

  Homopolymers or copolymers of acrylic acid esters · CPC title