Method of producing lignin with reduced amount of odorous substances

Patent metadata

Field	Value
Publication number	US-10882879-B2
Application number	US-201716311357-A
Country	US
Kind code	B2
Filing date	Jun 19, 2017
Priority date	Jun 22, 2016
Publication date	Jan 5, 2021
Grant date	Jan 5, 2021

Abstract

The present invention relates to a method of producing lignin with reduced amount of odorous substances comprising the steps of: i) providing a solid phase lignin containing starting material to be contacted with a water solution comprising alcohol; ii) dissolving at least guaiacol and etylguaiacol content from the lignin into the water solution, and iii) draining off the water solution with its content of guaiacol and etylguaiacol; iv) obtaining a lignin material with a reduced content guaiacol and etylguaiacol. The alcohol is preferably a C1-C4 alcohol, preferably ethanol. The invention also relates to a lignin product with reduced odour obtained and/or obtainable by the method and to the use of the obtained lignin as a component in polymer blends, an additive or filler in building materials, as binding agent in adhesives, and/or for the production of a carbon fibre, especially in indoor applications.

First claim

The invention claimed is:

1. A method for treatment of lignin to reduce odor from the lignin, wherein:
the lignin is maintained in solid phase and treated such that the chemical structure and bonding thereof substantially remain, and
the method comprises
providing a solid phase lignin containing starting material to be contacted with a water solution comprising alcohol;
dissolving at least guaiacol and etylguaiacol content from the lignin into the water solution;
draining off the water solution with its content of guaiacol and etylguaiacol; and
obtaining a lignin material with a reduced content of guaiacol and etylguaiacol.

2. The method according to claim 1 , wherein the lignin containing starting material has dry matter content above 50% (w/w), and a lignin content of this dry matter content exceeding 50% (w/w).

3. The method according to claim 1 , wherein the lignin containing starting material is mixed with water and alcohol in any order of mixing, and the resulting mixture is allowed to mature during a residence time of at least 5 minutes before draining off the water solution.

4. The method according to claim 1 , wherein the lignin containing starting material is a filter cake subjected to a displacement wash using the water solution comprising alcohol.

5. The method according to claim 1 , wherein the content of alcohol in the water solution is in the range of 0.1-50% by weight based on the lignin dry weight.

6. The method according to claim 5 , wherein the content of alcohol in the water solution is in the range of 0.5-10% by weight based on the lignin dry weight.

7. The method according to claim 6 , wherein the content of alcohol in the water solution is below 5% by weight based on the lignin dry weight.

8. The method according to claim 5 , wherein the alcohol content any of ethanol, methanol, propanol or butanol.

9. A method according to claim 1 for treatment of lignin to reduce odor from the lignin, comprising:
providing a solid phase lignin containing starting material to be contacted with a water solution comprising alcohol;
dissolving at least guaiacol and etylguaiacol content from the lignin into the water solution;
draining off the water solution with its content of guaiacol and etylguaiacol; and
obtaining a lignin material with a reduced content of guaiacol and etylguaiacol,
wherein the lignin containing starting material is obtained from a process comprising the steps of:
a. precipitating lignin by acidifying black liquor obtained from an alkaline chemical pulping process;
b. dewatering and/or filtrating the obtained lignin to provide a first filter cake;
c. re-suspending the lignin;
d. adjusting the pH of the obtained suspension in step c) to a pH lower than 6;
e. dewatering and/or filtrating the acidic suspension from step d) to provide a second filter cake; and
f. washing and dewatering the second filter cake so as to obtain the lignin containing starting material.

10. The method according to claim 1 , wherein
the water solution is an alcohol containing liquid phase solution, and
said alcohol containing liquid phase solution comprises carboxylic acid.

11. The method according to claim 1 , wherein the water solution is an alcohol containing liquid phase solution, and wherein the method further comprises utilizing the alcohol containing liquid phase solution to obtain lignin from black liquor in an alkaline chemical pulping process.

12. The method according to claim 1 , wherein the water solution is an alcohol containing liquid phase solution, and the alcohol containing liquid phase solution comprises an acid which is not carboxylic acid.

13. A lignin product obtained and/or obtainable by the method according to claim 1 .

14. The lignin product according to claim 13 , wherein the concentration of guaiacol and etylguaiacol in the obtained lignin product is at least 50% less than in the lignin containing starting material, the concentration being calculated from a peak area of a respective peak in a chromatogram.

15. A polymer blend comprising the lignin material according to claim 13 .

16. An additive comprising the lignin product according to claim 13 .

17. A filler for a building material or construction material comprising the lignin product according to claim 13 .

18. A binding agent for adhesive, the binding agent comprising the lignin product according to claim 13 .

19. A carbon fiber comprising the lignin product according to claim 13 .

Assignees

• Valmet Oy

Inventors

• Tomani Per
• Alvarado Fernando
• Sedin Maria

Classifications

• C07G1/00 Primary

  Low-molecular-weight derivatives of lignin (high-molecular-weight derivatives of lignin {C08H6/00}) · CPC title

• C08L97/005

  Lignin · CPC title

• D21C11/00

  Regeneration of pulp liquors {or effluent waste waters} · CPC title

• C09J197/005

  Lignin · CPC title

• B01D11/00 Primary

  Solvent extraction · CPC title