Slurry composition for catalyst and method for producing same, method for producing catalyst using this slurry composition for catalyst, and method for producing Cu-containing zeolite

Patent metadata

Field	Value
Publication number	US-10882033-B2
Application number	US-201816197404-A
Country	US
Kind code	B2
Filing date	Nov 21, 2018
Priority date	Nov 27, 2017
Publication date	Jan 5, 2021
Grant date	Jan 5, 2021

Abstract

A slurry composition for a catalyst and a method for producing the same, a catalyst and a method for producing the same using the slurry composition for a catalyst. The method omits many heretofore required treatment steps and reduces catalyst production cost. The method comprising the steps of providing a slurry composition for a catalyst, comprising at least an aluminosilicate, Cu, and water, and having a solid concentration of 0.1% by mass to 90% by mass, wherein a component for a catalyst has composition represented by Al2O3·xSiO2·yT2O·zCuO (wherein T is a quaternary ammonium cation, and x, y and z are numbers that satisfy 10≤x≤40, 0.1≤y<2.0, and 0.1≤z<2.0, respectively) in terms of molar ratio based on an oxide; coating at least one side of a support with this slurry composition; and heat-treating at 350° C. or higher.

First claim

What is claimed is:

1. A slurry composition for a catalyst,
comprising at least an uncalcined Cu-containing aluminosilicate, an organic structure directing agent including a quarternary ammonium cation, and water, and
having a solid concentration of 0.1% by mass to 90% by mass,
wherein the slurry composition contains a component for the catalyst, said component having a composition represented by Al 2 O 3 ·xSiO 2 ·yT 2 O·zCuO wherein T is a quaternary ammonium cation derived from the organic structure directing agent, and x, y and z are numbers that satisfy 10≤x≤40, 0.1≤y<2.0, and 0.1≤z<2.0, respectively, in terms of molar ratio based on an oxide.

2. The slurry composition for a catalyst according to claim 1 , further comprising 0.1 to 40% by mass of a binder.

3. The slurry composition for a catalyst according to claim 1 , wherein
the T is a quaternary ammonium cation represented by the general formula R 1 N(R 2 ) 3 wherein R 1 represents a linear, branched or cyclic hydrocarbon group having 1 or more and 12 or less carbon atoms, wherein the hydrocarbon group optionally contains a heteroatom and optionally contains a substituent, R 2 represents a linear or branched alkyl group having 1 or more and 4 or less carbon atoms, and a plurality of R 2 are the same as or different from each other.

4. The slurry composition for a catalyst according to claim 1 , wherein
the uncalcined Cu-containing aluminosilicate is NH 4 + form.

5. The slurry composition for a catalyst according to claim 1 , wherein
the uncalcined Cu-containing aluminosilicate is a zeolite having a CHA-type crystal structure.

6. A method for producing a slurry composition for a catalyst, comprising at least the steps of:
providing an uncalcined Cu-containing aluminosilicate, an organic structure directing agent, and water; and
preparing a slurry having a solid concentration of 0.1% by mass to 90% by mass by mixing at least the Cu-containing aluminosilicate, the organic structure directing agent containing a quaternary ammonium cation, and the water, wherein a component for the catalyst has a composition represented by Al 2 O 3 ·xSiO 2 ·yT 2 O·zCuO wherein T is a quaternary ammonium cation, and x, y and z are numbers that satisfy 10≤x≤40, 0.1≤y<2.0, and 0.1≤z<2.0, respectively, in terms of molar ratio based on an oxide.

7. The method for producing a slurry composition for a catalyst according to claim 6 , wherein
in the step of preparing a slurry, a slurry containing at least 0.1 to 89% by mass of the Cu-containing aluminosilicate, 0.1 to 40% by mass of a binder, and 10 to 90% by mass of the water is prepared.

8. The method for producing a slurry composition for a catalyst according to claim 6 , wherein
the T is a quaternary ammonium cation represented by the general formula R 1 N(R 2 ) 3 wherein R 1 represents a linear, branched or cyclic hydrocarbon group having 1 or more and 12 or less carbon atoms, wherein the hydrocarbon group optionally contains a heteroatom and optionally contains a substituent, R 2 represents a linear or branched alkyl group having 1 or more and 4 or less carbon atoms, and a plurality of R 2 are the same as or different from each other.

9. The method for producing a slurry composition for a catalyst according to claim 6 , wherein
the aluminosilicate is NH 4 + form.

10. The method for producing a slurry composition for a catalyst according to claim 6 , wherein
the aluminosilicate is a zeolite having a CHA-type crystal structure.

11. A method for producing a catalyst, comprising at least:
the step of providing a slurry composition for a catalyst according to claim 1 ;
a coating step of coating at least one side of a support with the slurry composition for a catalyst; and
a calcination step of heat-treating the slurry composition for a catalyst after the coating at 350° C. or higher to form a catalyst layer.

12. The method for producing a catalyst according to claim 11 , wherein in the coating step, the support is coated with the slurry composition in an amount of 0.1 to 500 g/L based on the solid content of a Cu-containing zeolite.

13. A method for producing a Cu-containing zeolite, comprising at least:
providing a starting material composition comprising at least a Si—Al—Cu element source comprising at least an uncalcined Cu-containing aluminosilicate which has a silica-alumina ratio of 2 or more and less than 15 and contains divalent Cu at a Cu/Al ratio of 0.1 or more and less than 1.0, a Si element source exclusive of those corresponding to the Si—Al—Cu element source, an organic structure directing agent which contains a quaternary ammonium cation and is substantially free from polyamine, and water; and
hydrothermally treating the starting material composition to synthesize a Cu-containing zeolite having composition represented by Al 2 O 3 ·xSiO 2 ·yT 2 O·zCuO wherein T is a quaternary ammonium cation, and x, y and z are numbers that satisfy 10≤x≤40, 0.1≤y<2.0, and 0.1≤z<2.0, respectively, in terms of molar ratio based on an oxide.

14. The method for producing a Cu-containing zeolite according to claim 13 , wherein
an uncalcined Cu-containing zeolite is obtained without a calcination step of performing heat treatment at 350° C. or higher in the hydrothermal treatment step or later.

15. The method for producing a Cu-containing zeolite according to claim 13 , wherein
the Cu-containing aluminosilicate comprises at least one selected from the group consisting of an amorphous aluminosilicate, and an aluminosilicate having a GIS structure, a FAU structure, a CHA structure, an LTL structure, a PHI structure, a MER structure, or an ERI structure as a crystal structure.

16. The method for producing a Cu-containing zeolite according to claim 13 , wherein
the Si element source is at least one selected from the group consisting of precipitated silica, colloidal silica, fumed silica, silica gel, sodium silicate, and alkoxysilane.

17. The method for producing a Cu-containing zeolite according to claim 13 , wherein
the starting material composition further comprises a seed crystal of a CHA-type zeolite, and
in the hydrothermal treatment step, the starting material composition is hydrothermally treated to synthesize a Cu-containing CHA-type zeolite.

Assignees

• N E Chemcat Corp

Inventors

• Takagi Yukio
• Saito Kiyohiko
• Banno Yasuyuki
• Nagata Makoto

Classifications

• Y02A50/20

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• Y02T10/12

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• B01J35/56

  Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths · CPC title

• B01J37/10

  in the presence of water, e.g. steam · CPC title

• F01N2330/30

  Honeycomb supports characterised by their structural details · CPC title