Method for producing alkyl cellulose

Patent metadata

Field	Value
Publication number	US-10881124-B2
Application number	US-201514965149-A
Country	US
Kind code	B2
Filing date	Dec 10, 2015
Priority date	Dec 11, 2014
Publication date	Jan 5, 2021
Grant date	Jan 5, 2021

Abstract

Provided is a method for producing an alkyl cellulose having a high viscosity and not having an excessively high gel strength. More specifically, there is provided a method for producing an alkyl cellulose comprising the steps of: mixing a cellulose pulp with a first alkali metal hydroxide solution with stirring to obtain alkali cellulose; reacting the alkali cellulose with an alkylating agent to obtain a first reaction mixture; blending a second alkali metal hydroxide solution with the first reaction mixture with stirring, without further blending of the alkylating agent, to obtain a second reaction mixture; and purifying the second reaction mixture to obtain an alkyl cellulose. There is also provided an alkyl cellulose being produced by the above method and having a degree of substitution of alkyl group of 27 to 33% by weight.

First claim

The invention claimed is:

1. A method for producing an alkyl cellulose, comprising the steps of:
mixing a cellulose pulp with a first alkali metal hydroxide solution with stirring to obtain an alkali cellulose;
reacting the alkali cellulose with an alkylating agent to obtain a first reaction mixture including a first alkyl cellulose that is substituted with an alkyl group;
blending a second alkali metal hydroxide solution with the first reaction mixture with stirring to obtain a second reaction mixture including a second alkyl cellulose, wherein the blending of the second alkali metal hydroxide solution with the first reaction mixture is performed without adding additional alkylating agent; and
purifying the second reaction mixture to obtain the second alkyl cellulose,
wherein a ratio of a weight of a first alkali metal hydroxide in the first alkali metal hydroxide solution to a total weight of the first alkali metal hydroxide and a second alkali metal hydroxide in the second alkali metal hydroxide solution is 50 to 86%.

2. The method for producing an alkyl cellulose according to claim 1 , wherein a molar ratio (second alkali metal hydroxide/cellulose) of the second alkali metal hydroxide in the second alkali metal hydroxide solution to cellulose in the cellulose pulp is 0.65 to 2.0.

3. The method for producing an alkyl cellulose according to claim 2 , wherein a blending rate of the second alkali metal hydroxide is 0.5 to 9.6 [mol/mol·hr] where the blending rate is a molar amount of the second alkali metal hydroxide blended with the first reaction mixture per unit time and per mol of cellulose in the cellulose pulp.

4. The method for producing an alkyl cellulose according to claim 1 , wherein a blending rate of the second alkali metal hydroxide is 0.5 to 9.6 [mol/mol·hr] where the blending rate is a molar amount of the second alkali metal hydroxide blended with the first reaction mixture per unit time and per mol of cellulose in the cellulose pulp.

5. The method for producing an alkyl cellulose according to claim 1 , wherein, in the step of blending a second alkali metal hydroxide solution with the first reaction mixture, a temperature in a reactor is 65 to 90° C. at start of the blending.

6. The method for producing an alkyl cellulose according to claim 1 , wherein, in the step of blending a second alkali metal hydroxide solution with the first reaction mixture, the second alkali metal hydroxide solution is blended while a temperature in the reactor is increased at a constant rate from start of the blending to completion thereof.

7. The method for producing an alkyl cellulose according to claim 6 , wherein the temperature increase rate is 3.0 to 50° C./hr.

8. The method for producing an alkyl cellulose according to claim 1 , wherein a molar ratio (first alkali metal hydroxide/cellulose) of the first alkali metal hydroxide in the first alkali metal hydroxide solution to cellulose in the cellulose pulp is 2.0 to 4.0.

9. The method for producing an alkyl cellulose according to claim 1 , wherein the first alkyl cellulose in the first reaction mixture has a degree of substitution (DS) of the alkyl group of 0.75 to 1.68.

10. An alkyl cellulose having a viscosity at 20° C. of a 1% by weight aqueous solution of the alkyl cellulose of 2,550 to 9,450 mPa·s as measured by a Brookfield viscometer, and having a storage elastic modulus G′(65° C.) at 65° C. of a 1.5% by weight aqueous solution thereof of 2,000 to 4,500 Pa.

11. The alkyl cellulose according to claim 10 , wherein a 1.5% by weight aqueous solution of the alkyl cellulose has a gelation temperature of 40 to 55° C.

12. The alkyl cellulose according to claim 11 , having a degree of substitution (DS) of alkyl group of 1.61 to 2.03.

13. The alkyl cellulose according to claim 10 , having a degree of substitution (DS) of alkyl group of 1.61 to 2.03.

Assignees

• Shinetsu Chemical Co
• Se Tylose Gmbh & Co Kg

Inventors

• Kitamura Akira
• Yamamoto Atsushi
• Narita Mitsuo
• Nebel Heiko
• Schultz Andreas

Classifications

• C08L1/28 Primary

  Alkyl ethers · CPC title

• C08B1/08

  Alkali cellulose · CPC title

• A23V2300/24

  Heat, thermal treatment · CPC title

• C08B11/02

  Alkyl or cycloalkyl ethers · CPC title

• A23D7/003

  Compositions other than spreads (characterised by ingredients other than fatty acid triglycerides A23D7/0053) · CPC title