Preparation method for wide-temperature catalyst used for preferential oxidation of co in a hydrogen-rich atmosphere, and product and applications
US-2019105638-A1 · Apr 11, 2019 · US
US10879538B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10879538-B2 |
| Application number | US-201916262197-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 30, 2019 |
| Priority date | Feb 7, 2018 |
| Publication date | Dec 29, 2020 |
| Grant date | Dec 29, 2020 |
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An oxygen evolution catalyst includes a core and a shell covering the surface of the core. The core includes ruthenium oxide or metal ruthenium in at least a surface portion. The shell includes titania or a composite oxide of titanium and ruthenium. Such an oxygen evolution catalyst is obtained by (a) dispersing core particles each including ruthenium oxide or metal ruthenium in at least a surface portion in a solvent to obtain a dispersion, (b) adding a Ti source to the dispersion to produce precursor particles in which the surface of each core particle is covered with a titania precursor, and (c) collecting the precursor particles from the dispersion and heat-treating the precursor particles after drying.
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What is claimed is: 1. An oxygen evolution catalyst comprising: a core; and a shell covering and fixed to a surface of the core, wherein the core includes ruthenium oxide or metal ruthenium in at least a surface portion, and the shell includes titania or a composite oxide of titanium and ruthenium. 2. The oxygen evolution catalyst according to claim 1 , wherein a titania coverage is 0.05 ML or more and 5.0 ML or less, the titania coverage being the number of titania atomic layers on the assumption that all of titanium included in the shell has become titania and that the titania uniformly covers the surface of the core. 3. A water electrolyzer comprising an oxygen electrode in which the oxygen evolution catalyst according to claim 1 is contained therein. 4. A fuel cell comprising an anode in which the oxygen evolution catalyst according to claim 1 is added thereto.
Compounds thereof with non-metallic elements · CPC title
at least one noble metal or noble metal oxide and at least one non-noble metal oxide · CPC title
Metals or alloys (H01M4/92 takes precedence) · CPC title
Fuel cells · CPC title
Hydrogen production from non-carbon containing sources, e.g. by water electrolysis · CPC title
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