Systems and methods for organic semiconductor devices with sputtered contact layers

Patent metadata

Field	Value
Publication number	US-10879479-B2
Application number	US-201716081390-A
Country	US
Kind code	B2
Filing date	Mar 3, 2017
Priority date	Mar 4, 2016
Publication date	Dec 29, 2020
Grant date	Dec 29, 2020

Abstract

Systems and methods for organic semiconductor devices with sputtered contact layers are provided. In one embodiment, an organic semiconductor device comprises: a first contact layer (140) comprising a first sputter-deposited transparent conducting oxide; an electron transport layer (130) interfacing with the first contact layer; a second contact layer (110) comprising a second sputter-deposited transparent conducting oxide; a hole transport layer interfacing with the second contact layer; and an organic semiconductor active layer (120) having a first side facing the electron transport layer and an opposing second side facing the hole transport layer; wherein either the electron transport layer or the hole transport layer comprises a buffering transport layer.

First claim

What is claimed is:

1. An organic semiconductor device, the device comprising:
a first contact layer comprising a first sputter-deposited transparent conducting oxide;
an electron transport layer interfacing with the first contact layer;
a second contact layer comprising a second sputter-deposited transparent conducting oxide;
a hole transport layer interfacing with the second contact layer;
an organic semiconductor active layer having a first side facing the electron transport layer and an opposing second side facing the hole transport layer; and
a plurality of scribes that extend into the electron transport layer, the hole transport layer, and the organic semiconductor active layer;
wherein either the electron transport layer or the hole transport layer comprises a buffering transport layer;
wherein either the first sputter-deposited transparent conducting oxide or the second sputter-deposited transparent conducting oxide extends into the plurality of scribes and is configured to electrically connect the first contact layer on a first side of each of the plurality of scribes to the second contact layer on a second side of each of the plurality of scribes.

2. The device of claim 1 , wherein the buffering transport layer comprises a transparent polymer material, a semi-transparent polymer material, a transparent oxide material or semi-transparent oxide material.

3. The device of claim 1 , wherein the organic semiconductor active layer comprises either an organic bulk heterojunction structure or a bilayer structure.

4. The device of claim 1 , wherein the organic semiconductor active layer comprises an organic bulk heterojunction absorber layer.

5. The device of claim 1 , wherein the organic semiconductor active layer comprises an organic emissive electroluminescent layer.

6. The device of claim 1 , wherein the first sputter-deposited transparent conducting oxide and the second sputter-deposited transparent conducting oxide both comprise sputter-deposited indium zinc oxide (IZO).

7. The device of claim 1 , wherein at least one of the first sputter-deposited transparent conducting oxide or the second sputter-deposited transparent conducting oxide comprise at least one of:
sputtered indium zinc oxide (IZO);
sputtered indium tin oxide (ITO);
sputtered aluminum doped zinc oxide (AZO); or
sputtered gallium doped zinc oxide (GZO).

8. The device of claim 1 , further comprising a substrate layer adjacent to either the first contact layer or the second contact layer.

9. An organic semiconductor device, the device comprising:
a substrate;
one or more backside device layers adjacent to the substrate;
an organic semiconductor active layer having an interface with the one or more backside device layers;
a buffering transport layer applied over the organic semiconductor active layer;
a plurality of scribes that extend into the buffering transport layer, the organic semiconductor active layer and the one or more backside device layers; and
a sputter-deposited transparent material contact layer applied over the buffering transport layer and into the plurality of scribes, wherein the sputter-deposited transparent material contact layer defines a front contact layer on a first side of each of the plurality of scribes and is configured to electrically connect the front contact layer to a back contact layer within the one or more backside device layers on a second side of each of the plurality of scribes.

10. The device of claim 9 , wherein the sputtered transparent material contact layer comprises a sputter-deposited transparent conducting oxide.

11. The device of claim 10 , wherein the sputter-deposited transparent conducting oxide comprises a sputtered indium zinc oxide (IZO).

12. The device of claim 9 , wherein the buffering transport layer comprises at least one of, a transparent polymer material, a semi-transparent polymer material, a transparent oxide material or semi-transparent oxide material.

13. The device of claim 9 , wherein the organic semiconductor active layer comprises either an organic bulk heterojunction structure or a bilayer structure.

14. A device comprising in order:
a front contact layer comprising a sputter-deposited transparent conducting oxide;
a buffering transport layer;
an organic semiconductor active layer; and
a plurality of scribes that extend into the buffering transport layer and the organic semiconductor active layer;
wherein the sputter-deposited transparent conducting oxide is applied over the buffering transport layer and into the plurality of scribes, wherein the sputter-deposited transparent conducting oxide is configured to electrically connect the front contact layer on a first side of each of the plurality of scribes to a back contact layer on a second side of each of the plurality of scribes.

Assignees

• Solarwindow Tech Inc
• Alliance Sustainable Energy

Inventors

• Hammond Scott R
• Van Hest Marinus Franciscus Antonius Maria

Classifications

• H10K39/12

  Electrical configurations of PV cells, e.g. series connections or parallel connections · CPC title

• H10K30/82

  Transparent electrodes, e.g. indium tin oxide [ITO] electrodes · CPC title

• H10K71/60 Primary

  Forming conductive regions or layers, e.g. electrodes · CPC title

• Y02E10/549

  Organic PV cells · CPC title

• H01L51/5012

  Electricity · mapped topic