Photochromic film

Patent metadata

Field	Value
Publication number	US-10877301-B2
Application number	US-201815954008-A
Country	US
Kind code	B2
Filing date	Apr 16, 2018
Priority date	Apr 16, 2018
Publication date	Dec 29, 2020
Grant date	Dec 29, 2020

Abstract

An optical device that is disposed to manage light transmittance therethrough includes a multi-layer photochromic sheet that is composed of a first layer, a second layer, and a photochromic layer interposed therebetween. The photochromic layer is composed of a mixture of dichroic dye and photo-isomerizable material that are disposed in a liquid crystal host, and the first and second layers are each fabricated from a clear polymer.

First claim

What is claimed is:

1. An optical device disposed to manage light transmittance therethrough, comprising:
a multi-layer photochromic sheet composed of a first layer, a second layer, and a photochromic layer interposed therebetween;
wherein the first and second layers are fabricated from a clear polymer material;
wherein the photochromic layer is composed of a dichroic dye and a photo-isomerizable material that are disposed in a liquid crystal host;
wherein the photo-isomerizable material is in a relaxed, trans, low-energy state when exposed to lightwaves that are less than a threshold intensity level, and
wherein the dichroic dye and the photo-isomerizable materials disposed in the liquid crystal host are disposed in a homeotropic alignment when exposed to lightwaves that are less than the threshold intensity level.

2. The optical device of claim 1 , wherein the photo-isomerizable material comprises an azobenzene moiety.

3. The optical device of claim 1 , wherein the photochromic layer is composed of a mixture of the dichroic dye and the photo-isomerizable material that are suspended in the liquid crystal host.

4. The optical device of claim 1 , wherein the photo-isomerizable material comprises a film that is disposed on inner surfaces of both the first and second layers.

5. The optical device of claim 1 , further comprising a transparent adhesive layer disposed on an outer surface of the first layer and interposed between the outer surface of the first layer of the optical device and an adjacent glass pane.

6. The optical device of claim 1 , wherein the first layer is configured as a micro-prismatic array, the micro-prismatic array including a plurality of linearly-disposed microprisms arranged in parallel with each other; wherein each of the linearly-disposed microprisms has a right-triangular cross-section including a first leg and a second leg that are defined in a second plane that is perpendicular to a first plane defined by the first layer;
wherein each of the first legs of the linearly-disposed microprisms defines a first subplane, and wherein each of the second legs of the linearly-disposed microprisms defines a second subplane, and wherein the photo-isomerizable material is disposed on the first subplane associated with the first leg.

7. The optical device of claim 1 , wherein the photo-isomerizable material is in an excited, cis, high-energy state when exposed to lightwaves that are greater than a threshold intensity level.

8. The optical device of claim 7 , wherein the dichroic dye and the photo-isomerizable materials disposed in the liquid crystal host are disposed in a non-homeotropic alignment when exposed to lightwaves that are greater than the threshold intensity level.

9. An optical device disposed on a windscreen, comprising:
a multi-layer photochromic sheet composed of a first layer, a second layer, and a photochromic layer interposed therebetween;
wherein the photochromic layer includes a dichroic dye and a photo-isomerizable material that are disposed in a liquid crystal host; and
wherein the optical device is disposed on the windscreen to manage light transmittance therethrough;
wherein the photo-isomerizable material is in an excited, cis, high-energy state when exposed to lightwaves that are greater than a threshold intensity, and wherein the dichroic dye and the photo-isomerizable materials disposed in the liquid crystal host are disposed in a non-homeotropic alignment when exposed to lightwaves that are greater than a threshold intensity level.

10. The optical device of claim 9 , wherein the photo-isomerizable material comprises an azobenzene moiety.

11. The optical device of claim 9 , wherein the photochromic layer is composed of a mixture of the dichroic dye and the photo-isomerizable material that are suspended in the liquid crystal host.

12. The optical device of claim 9 , wherein the photo-isomerizable material comprises a film that is disposed on inner surfaces of both the first and second layers.

13. The optical device of claim 9 , further comprising a transparent adhesive layer disposed on an outer surface of the first layer and interposed between the outer surface of the first layer of the optical device and an adjacent glass pane.

14. The optical device of claim 9 , wherein the first layer is configured as a micro-prismatic array, the micro-prismatic array including a plurality of linearly-disposed microprisms arranged in parallel with each other, and wherein the photo-isomerizable material is disposed on a subplane of each of the linearly-disposed microprisms.

15. The optical device of claim 14 , wherein each of the linearly-disposed microprisms has a right-triangular cross-section including a first leg and a second leg that are defined in a second plane that is perpendicular to a first plane defined by the first layer;
wherein each of the first legs of the linearly-disposed microprisms defines a first subplane, and wherein each of the second legs of the linearly-disposed microprisms defines a second subplane, and wherein the photo-isomerizable material is disposed on the first subplane associated with the first leg.

16. The optical device of claim 9 , wherein the photo-isomerizable material is in a relaxed, trans, low-energy state when exposed to lightwaves that are less than a threshold intensity level, and wherein the dichroic dye and the photo-isomerizable materials disposed in the liquid crystal host are disposed in a homeotropic alignment when exposed to lightwaves that are less than a threshold intensity level.

17. An optical device disposed to manage light transmittance therethrough, comprising:
a multi-layer photochromic sheet composed of a first layer, a second layer, and a photochromic layer interposed therebetween;
a first electrode disposed on an inner surface of the first layer;
a second electrode disposed on an inner surface of the second layer; and
a light sensor disposed to monitor incident light and operably connected to an electric power source;
wherein the photochromic layer is composed of a dichroic dye and a photo-isomerizable material that are disposed in a liquid crystal host;
wherein the light sensor is disposed to electrically connect the electric power source to the first and second electrodes in response to a detection of incident light that is greater than a threshold magnitude;
wherein transmittance of the photochromic layer decreases in response to the electrical connection of the electric power source to the first and second electrodes;
wherein the photo-isomerizable material is in a relaxed, trans, low-energy state when exposed to lightwaves that are less than a threshold intensity level, and
wherein the dichroic dye and the photo-isomerizable materials disposed in the liquid crystal host are disposed in a homeotropic alignment when exposed to lightwaves that are less than the threshold intensity level; and
wherein the photo-isomerizable material is in an excited, cis, high-energy state when exposed to lightwaves that are greater than a threshold intensity, and wherein the dichroic dye and the photo-isomerizable materials disposed in the liquid crystal host are disposed in a non-homeotropic alignment when exposed to lightwaves that are greater than a threshold intensity level.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Chang Kai-Han

Classifications

• B60J3/04 Primary

  adjustable in transparency · CPC title

• C09K2219/13

  used in the technical field of thermotropic switches · CPC title

• G02F2202/28

  Adhesive materials or arrangements · CPC title

• G02F2202/14

  photochromic · CPC title

• C09K19/00

  Liquid crystal materials · CPC title