Electrochemical sensor and method of using same

Patent metadata

Field	Value
Publication number	US-10876990-B2
Application number	US-201916415403-A
Country	US
Kind code	B2
Filing date	May 17, 2019
Priority date	Jan 28, 2014
Publication date	Dec 29, 2020
Grant date	Dec 29, 2020

Abstract

Methods for analyzing a fluid sample can include providing a sensor comprising a non-conductive housing and having a first face and an electrode array mounted in the first face. The method can include disposing the first face of the housing into a fluid sample to be analyzed, selecting a mode of operation, and initiating sensor operation. Modes of operation can include electrochemical operation and conductivity analysis, and can be selected via positioning a switch. The method can include receiving information from the sensor regarding at least one parameter of the fluid. Such parameters can include a concentration of a target constituent in the fluid sample, combined concentrations of different species within the fluid sample, and/or information indicative of the conductivity of the fluid sample.

First claim

The invention claimed is:

1. A non-transitory computer-readable medium containing executable instructions for determining a value of a predetermined parameter of a fluid sample via a sensor that includes:
a non-conductive housing having a first face,
an operational amplifier,
an electrode array mounted in the first face of the non-conductive housing and comprising a first electrode, a fourth electrode, a second electrode disposed between the first electrode and the fourth electrode, and a third electrode disposed between the second electrode and the fourth electrode, the third electrode being coupled to an input of the operational amplifier; and
a first switch coupled to an output of the operational amplifier; and
the non-transitory computer-readable medium comprising instructions for causing a programmable processor to:
receive a command initiating a mode of operation;
position the first switch in either a first position or a second position based on the received command; wherein
in the first position, the switch couples the output of the operational amplifier to the fourth electrode; and
in the second position, the switch couples the output of the operational amplifier to the third electrode;

apply an electrical potential to the fluid sample via the first electrode;
maintain a substantially constant electrical potential within the fluid sample via at least one of the second electrode and the third electrode;
receive an electrical current flowing through the fluid sample at the fourth electrode;
receive current information providing an indication of the magnitude of the current flowing through the fluid sample;
perform a calculation using the applied electrical potential and received current information to determine the value of the predetermined parameter of the fluid sample.

2. The non-transitory computer-readable medium of claim 1 , further comprising instructions for causing the programmable processor to receive fluid sample temperature information from a temperature sensor; and wherein performing the calculation comprises using the fluid sample temperature information to determine the value of the predetermined parameter of the fluid sample.

3. The non-transitory computer-readable medium of claim 1 , wherein the desired parameter of the fluid sample is one in the group consisting of: the conductivity of the fluid sample, the concentration of a target constituent in the fluid sample, and the combined concentration of ionized and soluble species in the fluid sample.

4. The non-transitory computer-readable medium of claim 1 , wherein receiving current information comprises receiving a signal indicative of a voltage drop across a known resistor.

5. The non-transitory computer-readable medium of claim 4 , wherein applying the electrical potential to the fluid sample comprises applying an alternating current potential.

6. The non-transitory computer-readable medium of claim 5 , wherein performing the calculation comprises calculating the conductivity of the fluid sample.

7. The non-transitory computer-readable medium of claim 5 , wherein applying the alternating current potential to the fluid sample comprises controlling at least a second switch coupled to a direct current voltage source to produce a substantially square wave to apply to the fluid sample.

8. The non-transitory computer-readable medium of claim 7 , wherein:
the received signal indicative of the voltage drop across the known resistor comprises two values, each value corresponding to a voltage drop in a different direction across the known resistor; and
performing the calculation comprises calculating the difference between the two values in the received signal.

9. The non-transitory computer-readable medium of claim 1 , wherein the programmable processor is configured to receive a command to determine a desired parameter of the fluid sample; and wherein
the applied electrical potential is dependent upon the received command.

10. The non-transitory computer-readable medium of claim 9 , wherein the received command is selected from a list of predefined commands.

11. The non-transitory computer-readable medium of claim 10 , wherein the received command comprises determining the concentration of a target constituent in the fluid sample; and wherein
the applied electrical potential relative to the substantially constant electrical potential at the at least one of the second electrode and the electrode comprises a predetermined redox potential of the target constituent.

12. The non-transitory computer-readable medium of claim 11 , wherein the target constituent comprises one of the group consisting of: peroxides, peracids, and hypochlorite.

13. The non-transitory computer-readable medium of claim 4 , wherein applying the electrical potential to the fluid sample comprises applying a direct current potential.

14. A non-transitory computer-readable medium containing executable instructions for determining a value of a predetermined parameter of a fluid sample, the medium comprising instructions for causing a programmable processor to:
receive a command initiating a mode of operation of a sensor, the sensor comprising:
an operational amplifier;
a first electrode, a second electrode, a third electrode and a fourth electrode; wherein
the second electrode is disposed between the first electrode and the fourth electrode, and
the third electrode is disposed between the second electrode and the fourth electrode and is coupled to an input of the operational amplifier; and
a switch;

position the switch based on the received command in either a first position or a second position; wherein
in the first position, the switch couples an output of the operational amplifier to the forth electrode; and
in the second position, the switch couples the output of the operational amplifier to the third electrode; and wherein

the switch is positioned in the first position in the event of a first mode of operation being received via the received command; and
the switch is positioned in the second position in the event of a second mode of operation being received via the received command.

15. The non-transitory computer-readable medium of claim 14 , wherein the first mode of operation comprises a conductivity mode of operation.

16. The non-transitory computer-readable medium of claim 15 , wherein receiving the command initiating the mode of operation of the sensor comprising receiving a selection of the first mode of operation, and wherein the medium further comprises instructions for causing the programmable processor to:
initiate a conductivity analysis of the fluid sample; and
generate information comprising:
information indicative of the conductivity of the fluid sample; and/or
information indicative of the combined concentration of ionized and soluble species in the fluid sample.

17. The non-transitory computer-readable medium of claim 14 , wherein the second mode of operation comprises an electrochemical mode of operation.

18. The non-transitory computer-readable medium of claim 17 , wherein receiving the command initiating the mode of operation of the sensor comprises receiving a selection of the second mode of operation, and wherein the medium further comprises instructions for causing the programmable processor to:
initiate an electrochemical analysis of the fluid sample; and
receive a selection of a target constituent of the fluid sample; and
provide an electrical potential to the fluid sample to effect an electrochemical reaction of the target constituent in the fl

Assignees

• Ecolab Usa Inc

Inventors

• Banks Rodney H

Classifications

• G16C99/00 Primary

  Subject matter not provided for in other groups of this subclass · CPC title

• G01N33/18

  Water · CPC title

• A61L2/28

  Devices for testing the effectiveness or completeness of sterilisation or disinfection, e.g. indicators which change colour · CPC title

• C01B15/00

  Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides · CPC title

• G01N25/00

  Investigating or analyzing materials by the use of thermal means (G01N3/00 - G01N23/00 take precedence) · CPC title