Fractionation of biomass-based material

Patent metadata

Field	Value
Publication number	US-10876071-B2
Application number	US-201916511237-A
Country	US
Kind code	B2
Filing date	Jul 15, 2019
Priority date	Jul 13, 2018
Publication date	Dec 29, 2020
Grant date	Dec 29, 2020

Abstract

A process is disclosed for fractionating biomass-based material. The process includes evaporating an evaporable part of biomass-based material in a short path evaporator, SPE, to produce a depitched lights fraction in liquid form, and a heavier pitch fraction. The depitched lights fraction may contain depitched tall oil in liquid form, and the heavier pitch fraction may contain tall oil pitch, TOP.

First claim

The invention claimed is:

1. A process for fractionating biomass-based material, wherein the process comprises:
evaporating biomass-based material in a thin film evaporator thereby producing a thin film evaporator overhead vapour fraction containing at least organic acids and neutral organic components, and a thin film evaporator residue fraction;
evaporating said thin film evaporator residue fraction in a short path evaporator thereby producing a depitched lights fraction in liquid form, and a heavier pitch fraction; and
distilling, in a distillation column, the thin film evaporator overhead vapour fraction, and the depitched lights fraction in liquid form, thereby producing a lighter organic acid and neutral organic components fraction, a first heavier organic acid and neutral organic components fraction in liquid form, and a second heavier organic acid and neutral organic components fraction in gaseous form;
wherein the thin film evaporator overhead vapour fraction contains at least rosin acid and fatty acid.

2. A process according to claim 1 , wherein the process comprises:
obtaining as products said heavier pitch fraction, lighter organic acid and neutral organic components fraction, first heavier organic acid and neutral organic components fraction, and second heavier organic acid and neutral organic components fraction.

3. A process according to claim 2 , wherein the thin film evaporator overhead vapour fraction is subjected to phase separation before the distillation in the distillation column, to remove liquid from the thin film evaporator overhead vapour fraction.

4. A process according to claim 2 , wherein the process comprises:
dehydrating biomass-based material to remove water, light organic acids, light neutral organic components and evaporable organic and inorganic impurities, to produce dehydrated biomass-based material, and/or dehydrating crude tall oil to remove turpentine and water, to produce dehydrated crude tall oil;
wherein the dehydration is performed by evaporating at a temperature of 50-240° C. and at a pressure of 3-10 kPa.

5. A process according to claim 4 , wherein the inorganic impurities include light sulphur compounds.

6. A process according to claim 2 , wherein the process comprises:
treatment of at least one of said fractions by purification to remove impurities.

7. A process according to claim 1 , wherein the biomass-based material is crude tall oil, and the depitched lights fraction in liquid form includes a depitched tall oil fraction in liquid form, and the heavier pitch fraction includes a tall oil pitch fraction,
wherein crude tall oil is evaporated in the thin film evaporator to produce the thin film evaporator overhead vapour fraction containing at least rosin acid and fatty acid, and a crude tall oil fraction containing thin film evaporator residue;
wherein said depitched tall oil fraction in liquid form, and said tall oil pitch fraction are obtained by evaporating said crude tall oil fraction in said short path evaporator;
wherein the thin film evaporator overhead vapour fraction and the depitched tall oil fraction are distilled in the distillation column to produce a crude fatty acid fraction, a tall oil rosin fraction in liquid form, and a tall oil rosin fraction in gaseous form; and
obtaining as products said tall oil pitch fraction, said crude fatty acid fraction and said tall oil rosin fraction.

8. A process according to claim 7 , comprising:
subjecting the depitched lights fraction and/or the depitched tall oil fraction to distilling in the distillation column directly after the evaporation in the short path evaporator.

9. A process according to claim 7 , wherein the lighter organic acid and neutral organic components fraction and/or the crude fatty acid fraction comprises at least one of:
about 3 wt-% to 8 wt-% rosin acid, or about 5 wt-% rosin acid.

10. A process according to claim 7 , comprising:
recovering said heavier pitch fraction and/or said tall oil pitch fraction at a short path evaporator bottoms temperature of at least one of 240° C. to 320° C., or 260° C. to 300° C., or 270° C. to 290° C.

11. A process according to claim 7 , wherein the process comprises:
redistilling, in a redistillation column, the first heavier organic acid and neutral organic components fraction and/or the tall oil rosin fraction in liquid form, to produce a further purified rosin fraction and a bottoms rosin fraction,
wherein the redistillation is performed below a depitching temperature, and at the pressure of the distillation column or lower.

12. A process according to claim 7 , wherein the process comprises:
distilling, in a light heads column, at least part of the crude fatty acid fraction and/or lighter organic acid and neutral organic components fraction, to produce a light heads fraction as a heads column distillate, and a further crude fatty acid fraction and/or a further lighter organic acid and neutral organic components fraction as a heads column bottom fraction;
distilling, in a fatty acid column, said further crude fatty acid fraction and/or a further lighter organic acid and neutral organic components fraction to produce a fatty acid fraction obtained as a fatty acid column distillate, and bottom oil obtained as a fatty acid column bottom fraction; and
recovering the light heads fraction, the fatty acid fraction, and bottom oil;
wherein the operating pressure of the light heads column is the same or slightly higher compared to the distillation column operating pressure, and

wherein the fatty acid column operating pressure is the same or slightly higher compared to the distillation column operating pressure.

13. A process according to claim 1 , wherein the thin film evaporator is a wiped film evaporator or a falling film evaporator.

14. A process according to claim 1 , wherein the distillation column is a packed column, a random packing column, structured packing column or tray column.

15. A process according to claim 1 , comprising:
performing evaporation in the short path evaporator at a pressure of at least one of 1400 Pa or less, or at 100 Pa to 1000 Pa, or at 200 Pa to 700 Pa, or at 250 Pa to 400 Pa.

16. A process as claimed in claim 1 , wherein the process comprises:
dehydrating crude tall oil to remove turpentine and water, to produce dehydrated crude tall oil; wherein the dehydrated crude tall oil is evaporated in the thin film evaporator to produce the thin film evaporator overhead vapour fraction containing at least rosin acid and fatty acid, and a crude tall oil fraction comprising thin film evaporator residue;
wherein the produced crude tall oil fraction is evaporated in the short path evaporator to produce a depitched tall oil fraction comprising depitched tall oil in liquid form, and a tall oil pitch fraction;
wherein the produced thin film evaporator overhead vapour fraction and depitched tall oil fraction are distilled in the distillation column to produce a crude fatty acid fraction comprising crude fatty acid, a fraction comprising tall oil rosin in liquid form, and a fraction comprising tall oil rosin in gaseous form;
wherein the process comprises
recovering said tall oil pitch fraction, said crude fatty acid fraction and said tall oil rosin fraction;
redistilling, in a redistillation column, the tall oil rosin fraction comprising tall oil rosin in liquid form, to produce a further purified tall oil rosin fraction and a bottoms rosin fraction;
distilling, in a light heads column, at least part of the crude fatty acid fraction comprising crude fatty acid, to produce a light heads fractio

Assignees

• Neste Oyj

Inventors

• Nevanlinna Ville
• Vikman Kim

Classifications

• C10G7/04

  Dewatering · CPC title

• C10G3/40

  Thermal non-catalytic treatment · CPC title

• C11B3/12

  by distillation · CPC title

• C11B13/005 Primary

  of residues of the fabrication of wood-cellulose (in particular tall-oil) · CPC title

• C10G7/02 Primary

  Stabilising gasoline by removing gases by fractioning · CPC title